Catalysts, catalytic materials having catalysts present on supports and catalytic methods are provided. The catalysts, catalytic material and methods are useful in a variety of catalytic reactions, for example, the oxidative coupling of methane.

Disclosed is a catalyst for producing an olefin, the catalyst having an excellent conversion and excellent selectivity, and a method for preparing the catalyst. The catalyst for producing an olefin, according to the present invention, includes: a support including alumina and an auxiliary support component; a main catalyst including an active metal oxide supported on the support; and a co-catalyst including an oxide of an alkali metal and a Group 6B transition metal.

A process for the vapour phase chemical dehydration of ethanol in a reactor in the presence of a supported hetero-polyacid catalyst, said process comprising a step of contacting the ethanol with the heteropolyacid catalyst, wherein the heteropoly acid catalyst comprises a partially neutralised silicotungstic acid salt, wherein the partially neutralised silicotungstic acid salt has from 30% to 70% of the hydrogen atoms replaced with cations selected from the group consisting of alkali metal cations, alkaline earth metal cations, transition metal cations, ammonium cations, and mixtures thereof; but with the proviso that the alkali metal cation is not lithium; and wherein, after attaining steady-state performance of the catalyst, said process is operated continuously with the same supported heteropolyacid catalyst for at least 150 hours, without any regeneration of the catalyst.

The present invention provides a process for the preparation of ethene by vapour phase chemical dehydration of a feed comprising ethanol and optionally water and/or ethoxyethane, said process comprising contacting a dried supported heteropoly acid catalyst in a reactor with the feed-stream having feed temperature of at least 200° C.; wherein the pressure inside the reactor is at least 0.80 MPa but less than 1.80 MPa; and before the supported heteropolyacid catalyst is contacted with the feed-stream having a feed temperature of at least 200° C., the process is initiated by: (i) drying a supported heteropolyacid catalyst in a reactor under a stream of inert gas having a feed temperature of from above 100° C. to 200° C.; and (ii) contacting the dried supported heteropolyacid catalyst with an ethanol-containing vapour stream having a feed temperature of from above 100° C. to 160° C.

An organic reductant, in particular an organo silicon reductant suitable for activating supported catalysts of the type MO.sub.nE.sub.m, wherein E is S and/or Se, in particular MO.sub.n, wherein M is W, Mo or Re, is described as well as its use in metathesis reactions. The reduced catalysts are able to metathesize olefins at low temperatures and are therefore also suitable for metathesis of functionalized olefins.

According to various aspects and exemplary embodiments of the present disclosure, ultra-small catalyst particles having extremely high reactivity may be synthesized in single-atom or single-molecule state. When the ultra-small-sized single-atom or single-molecule catalyst is used, the use of metal raw materials can be minimized and, at the same time, catalytic activity may be maximized through maximized reactivity of the single-atom or single-molecule catalyst.

Disclosed are a catalyst for oxidative coupling reaction of methane, a method for preparing the same, and a method for oxidative coupling reaction of methane using the same. The catalyst includes a mixed metal oxide, which is a mixed oxide of metals including sodium (Na), tungsten (W), manganese (Mn), barium (Ba) and titanium (Ti). It is possible to obtain paraffins, such as ethane and propane, and olefins, such as ethylene and propylene, with high efficiency through the method for oxidative coupling reaction of methane using the catalyst.

Systems and processes herein improve the conversion of propylene to ethylene via metathesis. On a mass basis, embodiments herein may be used to convert greater than 40% propylene, on a mass basis, to ethylene, such as 43% to 75%, on a mass basis. In one aspect, processes for the conversion of propylene to ethylene herein may include introducing a propylene feed stream to a metathesis reactor, and contacting the propylene with a metathesis catalyst in the metathesis reactor to convert the propylene to ethylene and 2-butene. An effluent from the metathesis reactor may be recovered, the effluent including ethylene, 2-butene, and unconverted propylene. The effluent may then be separated in a fractionation system to recover an ethylene fraction, a propylene fraction, a c4 fraction, and a C5+ fraction. The propylene fraction and the C4 fraction may then be fed to the metathesis reactor to produce additional ethylene.

A oxygen transfer agent useful for the oxidative dehydrogenation of saturated hydrocarbons includes at least one mixed oxide derived from manganese or compounds thereof, as well as a promoter, such as tungsten and/or phosphorus. The oxygen transfer agent may also include an alkali metal or compounds thereof, boron or compounds thereof, an oxide of an alkaline earth metal, and an oxide containing one or more of one or more of manganese, lithium, boron, and magnesium. A reactor is at least partially filled with the oxygen transfer agent in the form of a fixed or circulating bed and provides an unsaturated hydrocarbon product, such as ethylene and/or propylene. The oxygen transfer agent may be regenerated using oxygen.

The present invention provides a catalyst comprising a transition metal, an inorganic support, a zeolite, and a layered double hydroxide. Using of the catalyst according to the present invention in an olefin production process exhibits high activity and high selectivity with decreased deactivation rate, therefore longer reaction cycle can be performed and catalyst life is prolonged.