Systems and methods are provided for conversion of oxygenate-containing feeds to a hydrocarbon effluent that includes a naphtha boiling range portion with an increased research octane number and/or increased octane rating. The conditions for converting the oxygenate-containing feed can correspond to conversion conditions for fluidized bed operation and/or moving bed operation, with a low acidity catalyst that also includes phosphorus to improve the hydrogen transfer rate relative to the expected hydrogen transfer rate for a low acidity catalyst. In addition to providing a naphtha fraction with an improved research octane number and/or octane rating, the amount of durene in the naphtha fraction can be reduced or minimized.

The present disclosure provides an aromatization catalyst, a preparation method, a regeneration method and an aromatization method thereof. The preparation method comprises steps of: mixing a zeolite molecular sieve with a binder to obtain a catalyst precursor; the catalyst precursor is successively subjected to an ion exchange modification and a first modification treatment, and then subjected to a hydrothermal treatment, and further subjected to active metal loading and a second modification treatment, to obtain the aromatization catalyst. The aromatization catalyst has good carbon deposition resistance and high aromatization activity, and enables an aromatization reaction to be completed under mild conditions, and has high aromatic selectivity, and the liquid yield is above 98.5%.

The present disclosure provides an aromatization catalyst, a preparation method, a regeneration method and an aromatization method thereof. The preparation method comprises steps of: mixing a zeolite molecular sieve with a binder to obtain a catalyst precursor; the catalyst precursor is successively subjected to an ion exchange modification and a first modification treatment, and then subjected to a hydrothermal treatment, and further subjected to active metal loading and a second modification treatment, to obtain the aromatization catalyst. The aromatization catalyst has good carbon deposition resistance and high aromatization activity, and enables an aromatization reaction to be completed under mild conditions, and has high aromatic selectivity, and the liquid yield is above 98.5%.

A bifunctional catalyst for conversion of oxygenates, said bifunctional catalyst comprising zeolite, alumina binder, Zn and P, wherein P is evenly distributed across the catalyst.

Process for the preparation of a catalyst and a catalyst comprising enhanced mesoporosity is provided herein. Thus, in one embodiment, provided is a particulate FCC catalyst comprising 2 to 50 wt % of one or more ultra stabilized high Si02/A1203 ratio large pore faujasite zeolite or a rare earth containing USY, 0 to 50 wt % of one or more rare-earth exchanged large pore faujasite zeolite, 0 to 30 wt % of small to medium pore size zeolites, 5 to 45 wt % quasi-crystalline boehmite 0 to 35 wt % microcrystalline boehmite, 0 to 25 wt % of a first silica, 2 to 30 wt % of a second silica, 0.1 to 10 wt % one or more rare earth components showiomg enhanced mesoporosity in the range of 6-40 nm, the numbering of the silica corresponding to their orders of introduction in the preparation process.

A bifunctional catalyst for example for conversion of oxygenates, said bifunctional catalyst comprising zeolite, alumina binder, Zn and P, wherein Zn is present at least partly as ZnAl.sub.2O.sub.4.

Systems and methods are provided for conversion of oxygenate-containing feeds to a hydrocarbon effluent that includes a naphtha boiling range portion with an increased research octane number and/or increased octane rating. The conditions for converting the oxygenate-containing feed can correspond to conversion conditions for fluidized bed operation and/or moving bed operation, with a low acidity catalyst that also includes phosphorus to improve the hydrogen transfer rate relative to the expected hydrogen transfer rate for a low acidity catalyst. In addition to providing a naphtha fraction with an improved research octane number and/or octane rating, the amount of durene in the naphtha fraction can be reduced or minimized.

Provided is a catalyst for synthesizing a polyethylene oxide polymer, comprising a crown ether as a first component, a quaternary phosphonium salt as a second component, and an alkali metal and/or an alkali metal compound as a third component. The catalyst can reduce the concentration of alkali metal ions in the product and is suitable for high-standard industrial fields. Also provided is a method for synthesizing a polyethylene oxide polymer, comprising carrying out a reaction of a compound containing active hydrogen and ethylene oxide in the presence of the catalyst. The method is simple to operate and environmentally friendly, improves the quality of the synthesized product, and is suitable for high-standard industrial production.

Disclosed is a method for preparing propylene glycol phenyl ether, comprising carrying out a polymerization reaction of phenol and a propylene oxide in the presence of a quaternary phosphonium salt compound as a catalyst. Preferably, the method comprises mixing phenol and a quaternary phosphonium salt compound, and then adding propylene oxide under oxygen-free conditions, wherein the phenol is polymerized with the propylene oxide to produce the propylene glycol phenyl ether. The propylene glycol phenyl ether thus prepared has few impurities and contains no metal ions, such as potassium and sodium, and does not require subsequent operations to remove metal ions and perform rectification separation, thereby reducing the costs and allowing same to be directly applied to high-standard industrial production.

Process for the preparation of a catalyst and a catalyst comprising the use of more than one silica source is provided herein. Thus, in one embodiment, the invention provides a particulate FCC catalyst comprising about 5 to about 60 wt % one or more zeolites, about 15 to about 35 wt % quasicrystalline boehmite (QCB), about 0 to about 35 wt % microcrystalline boehmite (MCB), greater than about 0 to about 15 wt % silica from sodium stabilized basic colloidal silica, greater than about 0 to about 30 wt % silica from acidic colloidal silica or polysilicic acid, and the balance clay and the process for making the same. This process results in attrition resistant catalysts with a good accessibility.