Patent classifications
C07C29/74
Process to recover 3-methyl-but-3-en-1-ol
The presently claimed invention relates to a process for the recovery of 3-methyl-3-buten- -ol from a stream comprising (Z)-3-methylpent-2-ene-1,5-diol, (E)-3-methylpent-2-ene-,5-diol and 3-methylenepentane-1,5-diol by treating the stream with isobutene and water.
Process to recover 3-methyl-but-3-en-1-ol
The presently claimed invention relates to a process for the recovery of 3-methyl-3-buten- -ol from a stream comprising (Z)-3-methylpent-2-ene-1,5-diol, (E)-3-methylpent-2-ene-,5-diol and 3-methylenepentane-1,5-diol by treating the stream with isobutene and water.
PROCESS FOR PREPARING ETHYLENE GLYCOL FROM A CARBOHYDRATE SOURCE
Ethylene glycol is prepared from a carbohydrate source in a process, wherein hydrogen, the carbohydrate source, a liquid diluent and a catalyst system are provided as reactants into a reaction zone; wherein the catalyst system comprises a tungsten compound and at least one hydrogenolysis metal selected from the noble metals Pd, Pt, Ru, Rh, Ir and combinations thereof; wherein the carbohydrate source is introduced into the reaction zone such that in the reaction zone the concentration of the carbohydrate source in the diluent is at least 4% wt, calculated as weight of carbohydrate source per weight of diluent; wherein the amount of the at least one hydrogenolysis metal selected from the noble metals Pd, Pt, Ru, Rh, Ir and combinations thereof ranges from 0.2 to 1.0% wt, calculated as the metal and based on the amount of carbohydrate source introduced into the reaction zone; wherein the molar ratio of tungsten to the at least one hydrogenolysis metal is in the range of 1 to 25; and wherein the carbohydrate source is reacted with hydrogen in the presence of the catalyst system to yield an ethylene glycol-containing product.
PROCESS FOR PREPARING ETHYLENE GLYCOL FROM A CARBOHYDRATE SOURCE
Ethylene glycol is prepared from a carbohydrate source in a process, wherein hydrogen, the carbohydrate source, a liquid diluent and a catalyst system are provided as reactants into a reaction zone; wherein the catalyst system comprises a tungsten compound and at least one hydrogenolysis metal selected from the noble metals Pd, Pt, Ru, Rh, Ir and combinations thereof; wherein the carbohydrate source is introduced into the reaction zone such that in the reaction zone the concentration of the carbohydrate source in the diluent is at least 4% wt, calculated as weight of carbohydrate source per weight of diluent; wherein the amount of the at least one hydrogenolysis metal selected from the noble metals Pd, Pt, Ru, Rh, Ir and combinations thereof ranges from 0.2 to 1.0% wt, calculated as the metal and based on the amount of carbohydrate source introduced into the reaction zone; wherein the molar ratio of tungsten to the at least one hydrogenolysis metal is in the range of 1 to 25; and wherein the carbohydrate source is reacted with hydrogen in the presence of the catalyst system to yield an ethylene glycol-containing product.
METHOD FOR PRODUCING HIGH-EFFICIENCY METHANOL CAPABLE OF REDUCING EMISSION OF CARBON DIOXIDE
A method for producing high-efficiency methanol capable of reducing emission of carbon dioxide. The method includes: a first step of preparing mixed gas by using steam and natural gas as raw materials and converting C.sub.2+ hydrocarbon contained in the natural gas into methane on a catalyst; a second step of preparing a synthesis gas including carbon monoxide, carbon dioxide, and hydrogen by reforming the mixed gas in a reformer filled with a reforming catalyst; and a third step of preparing methanol by using the synthesis gas as the raw material and reacting the synthesis gas.
METHOD FOR PRODUCING HIGH-EFFICIENCY METHANOL CAPABLE OF REDUCING EMISSION OF CARBON DIOXIDE
A method for producing high-efficiency methanol capable of reducing emission of carbon dioxide. The method includes: a first step of preparing mixed gas by using steam and natural gas as raw materials and converting C.sub.2+ hydrocarbon contained in the natural gas into methane on a catalyst; a second step of preparing a synthesis gas including carbon monoxide, carbon dioxide, and hydrogen by reforming the mixed gas in a reformer filled with a reforming catalyst; and a third step of preparing methanol by using the synthesis gas as the raw material and reacting the synthesis gas.
STRIPPING METHOD
The present invention relates to a stripping method capable of recovering, by an environmentally friendly method, a high-purity ester-based compound without concern over the oxidation of an ester-based compound from a mixture containing the ester-based compound. The stripping method has advantages of generating no wastewater, enabling equipment costs to be reduced by simplifying the process, removing concern over the oxidation of an ester-based compound during the process, and enabling the reuse of the components recovered in the process.
STRIPPING METHOD
The present invention relates to a stripping method capable of recovering, by an environmentally friendly method, a high-purity ester-based compound without concern over the oxidation of an ester-based compound from a mixture containing the ester-based compound. The stripping method has advantages of generating no wastewater, enabling equipment costs to be reduced by simplifying the process, removing concern over the oxidation of an ester-based compound during the process, and enabling the reuse of the components recovered in the process.
Continuous processes for the selective conversion of aldohexose-yielding carbohydrate to ethylene glycol using low concentrations of retro-aldol catalyst
Retro-aldol processes are disclosed that use very low concentrations of retro-aldol catalyst in combination with hydrogenation catalyst of certain activities, sizes and spatial dispersions to obtain the high selectivities to ethylene glycol.
Continuous processes for the selective conversion of aldohexose-yielding carbohydrate to ethylene glycol using low concentrations of retro-aldol catalyst
Retro-aldol processes are disclosed that use very low concentrations of retro-aldol catalyst in combination with hydrogenation catalyst of certain activities, sizes and spatial dispersions to obtain the high selectivities to ethylene glycol.