Multiple methods of synthesizing cannabigerol are presented. Combining olivetol with geraniol derivatives are provided. Cross-coupling methods of combing functionalized resorcinols are provided. Useful intermediates are formed during such cross-coupling steps.

Multiple methods of synthesizing cannabigerol are presented. Combining olivetol with geraniol derivatives are provided. Cross-coupling methods of combing functionalized resorcinols are provided. Useful intermediates are formed during such cross-coupling steps.

Multiple methods of synthesizing cannabigerol are presented. Combining olivetol with geraniol derivatives are provided. Cross-coupling methods of combing functionalized resorcinols are provided. Useful intermediates are formed during such cross-coupling steps.

Multiple methods of synthesizing cannabigerol are presented. Combining olivetol with geraniol derivatives are provided. Cross-coupling methods of combing functionalized resorcinols are provided. Useful intermediates are formed during such cross-coupling steps.

The present invention relates to an ambient ion based method of making free-standing 2D metal sheets made of bare NPs, at the air-liquid interface. An electro-hydrodynamic flow field was generated by electrospray deposition on the liquid surface, which in turn assisted the assembly of the NPs. The NP-NSs were made under ambient conditions at room temperature from metal salt precursors. The sheets can be made of different elements such as Pd, Au, and Ag. Synthesized 2D NP-NSs were used as efficient and reusable heterogeneous catalysts for CC bond formation reactions. These thin metal sheets may also be used as catalysts, sensors, gas adsorbing media, electrodes for electrochemical reactions, etc.

The present invention relates to an ambient ion based method of making free-standing 2D metal sheets made of bare NPs, at the air-liquid interface. An electro-hydrodynamic flow field was generated by electrospray deposition on the liquid surface, which in turn assisted the assembly of the NPs. The NP-NSs were made under ambient conditions at room temperature from metal salt precursors. The sheets can be made of different elements such as Pd, Au, and Ag. Synthesized 2D NP-NSs were used as efficient and reusable heterogeneous catalysts for CC bond formation reactions. These thin metal sheets may also be used as catalysts, sensors, gas adsorbing media, electrodes for electrochemical reactions, etc.

Multiple methods of synthesizing cannabigerol are presented. Combining olivetol with geraniol derivatives are provided. Cross-coupling methods of combing functionalized resorcinols are provided. Useful intermediates are formed during such cross-coupling steps.

Multiple methods of synthesizing cannabigerol are presented. Combining olivetol with geraniol derivatives are provided. Cross-coupling methods of combing functionalized resorcinols are provided. Useful intermediates are formed during such cross-coupling steps.

The subject invention pertains to a method of halogenating phenols, yielding a range of halogenated phenols with enantiomeric ratio of up to 99.5:0.5. In certain embodiments, the subject invention pertains to a method of asymmetric halogenation of bisphenol, yielding a range of chiral bisphenol ligands. The novel chiral bisphenols are potent privileged catalyst cores that can be applied to the preparation of ligands for various catalytic asymmetric reactions. The catalyst library can easily be accessed because late-stage modification of the scaffold can readily be executed through cross-coupling of the halogen handles on the bisphenols.

The subject invention pertains to a method of halogenating phenols, yielding a range of halogenated phenols with enantiomeric ratio of up to 99.5:0.5. In certain embodiments, the subject invention pertains to a method of asymmetric halogenation of bisphenol, yielding a range of chiral bisphenol ligands. The novel chiral bisphenols are potent privileged catalyst cores that can be applied to the preparation of ligands for various catalytic asymmetric reactions. The catalyst library can easily be accessed because late-stage modification of the scaffold can readily be executed through cross-coupling of the halogen handles on the bisphenols.