C07C63/15

Diels-Alder ring-opening process

The invention is directed to a process for the ring-opening of a cycloadduct obtainable from a reaction of a furanic compound and a diene, said process comprising contacting the cycloadduct with an acidic mixture comprising sulfuric acid and an activating agent to obtain a ring-opened product. The present invention is particularly directed a continuous process.

Diels-Alder ring-opening process

The invention is directed to a process for the ring-opening of a cycloadduct obtainable from a reaction of a furanic compound and a diene, said process comprising contacting the cycloadduct with an acidic mixture comprising sulfuric acid and an activating agent to obtain a ring-opened product. The present invention is particularly directed a continuous process.

PROCESS FOR EXTRACTING AROMATIC DICARBOXYLIC ACIDS FROM THEIR METAL SALTS

The present invention relates to a process for extracting aromatic dicarboxylic acids from an outlet stream of a basic depolymerization of polycondensates containing metal carboxylates of the aromatic dicarboxylic acid to be extracted, wherein a mineral or organic acid is added to this outlet stream, the pKs value of which acid being greater than or equal to that of the aromatic dicarboxylic acid, on which the polycondensate is based.

PROCESS FOR EXTRACTING AROMATIC DICARBOXYLIC ACIDS FROM THEIR METAL SALTS

The present invention relates to a process for extracting aromatic dicarboxylic acids from an outlet stream of a basic depolymerization of polycondensates containing metal carboxylates of the aromatic dicarboxylic acid to be extracted, wherein a mineral or organic acid is added to this outlet stream, the pKs value of which acid being greater than or equal to that of the aromatic dicarboxylic acid, on which the polycondensate is based.

PRODUCTION OF XYLENE DERIVATIVES
20180370984 · 2018-12-27 ·

The present invention relates to the production of xylene derivatives from furfural and its derivatives. The invention describes new routes for converting furfural and its derivatives into xylene derivatives including novel intermediates.

USING PRESSURIZED WET GAS LINES TO AVOID FOULING IN PURIFIED TEREPHTHALIC ACID (PTA) FILTERS AND LINES

Processes for recovering a purified aromatic carboxylic acid include contacting a crude aromatic carboxylic acid with hydrogen in the presence of a catalyst in a hydrogenation reactor to form a purified aromatic carboxylic acid; crystallizing the purified aromatic carboxylic acid to form a solid/liquid mixture comprising purified aromatic carboxylic acid solids; filtering the solid/liquid mixture in a rotary pressure filter apparatus to remove a liquid filtrate, washing the solid/liquid mixture in the rotary pressure apparatus with a wash fluid to form a washed solid/liquid mixture, and drying the washed solid/liquid mixture in the rotary pressure apparatus with an inert gas to form a filter cake comprising purified aromatic carboxylic acid solids and a wet gas stream; withdrawing the wet gas stream from the rotary pressure filter apparatus while maintaining the wet gas stream at a pressure above ambient; and recovering the purified aromatic carboxylic acid solids from the filter cake.

USING PRESSURIZED WET GAS LINES TO AVOID FOULING IN PURIFIED TEREPHTHALIC ACID (PTA) FILTERS AND LINES

Processes for recovering a purified aromatic carboxylic acid include contacting a crude aromatic carboxylic acid with hydrogen in the presence of a catalyst in a hydrogenation reactor to form a purified aromatic carboxylic acid; crystallizing the purified aromatic carboxylic acid to form a solid/liquid mixture comprising purified aromatic carboxylic acid solids; filtering the solid/liquid mixture in a rotary pressure filter apparatus to remove a liquid filtrate, washing the solid/liquid mixture in the rotary pressure apparatus with a wash fluid to form a washed solid/liquid mixture, and drying the washed solid/liquid mixture in the rotary pressure apparatus with an inert gas to form a filter cake comprising purified aromatic carboxylic acid solids and a wet gas stream; withdrawing the wet gas stream from the rotary pressure filter apparatus while maintaining the wet gas stream at a pressure above ambient; and recovering the purified aromatic carboxylic acid solids from the filter cake.

Liquid phase oxidation of aromatic feedstocks with manganate recycling to produce carboxylic acids

Systems and methods for liquid-phase oxidation of an aromatic feedstock containing at least one oxidizable aromatic compound may incorporate an oxidation reactor, a separation apparatus in fluidic communication with the oxidation reactor, a solids treatment unit, and a product recovery unit in fluidic communication with the separation apparatus. The oxidation reactor may conduct liquid-phase oxidation of the oxidizable aromatic compound in the aromatic feedstock in the presence of a manganate salt to form a slurry containing liquid product and solid manganese dioxide. The separation apparatus may accept the slurry from the oxidation reactor and separate the liquid component from the solid component. The solids treatment unit accepts the solid component from the separation apparatus, treats the solid component with a basic liquid to oxidize the manganese dioxide in the solid component and form a regenerated manganate salt, which may be recycled back to the oxidation reactor.

Monomer for hardmask composition, hardmask composition including said monomer, and method for forming pattern using said hardmask composition

Disclosed are a monomer represented by the following Chemical Formula 1 for a hardmask composition, a hardmask composition including the monomer, and a method of forming patterns using the same. ##STR00001##
In the above Chemical Formula 1, A, A, L, L, X and n are the same as defined in the specification.

Monomer for hardmask composition, hardmask composition including said monomer, and method for forming pattern using said hardmask composition

Disclosed are a monomer represented by the following Chemical Formula 1 for a hardmask composition, a hardmask composition including the monomer, and a method of forming patterns using the same. ##STR00001##
In the above Chemical Formula 1, A, A, L, L, X and n are the same as defined in the specification.