A method for producing a vinyl chloride type polymer is to produce the vinyl chloride type polymer by polymerizing a vinyl chloride monomer, or a mixture of a vinyl chloride monomer with a monomer copolymerizable with the vinyl chloride monomer in an aqueous medium by using a polymerization reactor. An aqueous solution of a copolymerized polyether having a weight-average molecular weight of 1,000 to 3,500 with a mole ratio of ethylene oxide to propylene oxide in the range of 10/90 to 60/40 is charged into the polymerization reactor with an amount of 0.005 to 0.050 part by weight as the copolymerized polyether relative to 100 parts by weight of the vinyl chloride monomer.

The present invention provides an antiviral substrate that is excellent in antiviral properties, is excellent in transparency or the like, and is capable of maintaining characteristics such as the transparency of a base material and the color of the surface of the base material. The present invention relates to an antiviral substrate in which a cured material of an electromagnetic curable resin containing a copper compound is scattered in the form of islands on a surface of a base material, and at least a part of the copper compound is exposed on a surface of the cured material of the electromagnetic curable resin.

A modified vinyl alcohol-based polymer includes a polyoxyalkylene unit, and an organic acid unit bonded to a polyvinyl alcohol chain, the polyoxyalkylene unit includes a moiety represented by the general formula (I), the moiety being bonded to the polyvinyl alcohol chain only via an ether bond and/or a carbon-carbon bond, wherein a ratio of a number of moles of monomer units bonded to the polyoxyalkylene unit to a total number of moles of the monomer units constituting the polyvinyl alcohol chain of the modified vinyl alcohol-based polymer is 0.01 mol % to 5 mol %, and a ratio of a number of moles of the organic acid unit to the total number of moles of the monomer units constituting the polyvinyl alcohol chain of the modified vinyl alcohol-based polymer is 0.1 mol % to 10 mol %.

A modified vinyl alcohol-based polymer includes a polyoxyalkylene unit, and an organic acid unit bonded to a polyvinyl alcohol chain, the polyoxyalkylene unit includes a moiety represented by the general formula (I), the moiety being bonded to the polyvinyl alcohol chain only via an ether bond and/or a carbon-carbon bond, wherein a ratio of a number of moles of monomer units bonded to the polyoxyalkylene unit to a total number of moles of the monomer units constituting the polyvinyl alcohol chain of the modified vinyl alcohol-based polymer is 0.01 mol % to 5 mol %, and a ratio of a number of moles of the organic acid unit to the total number of moles of the monomer units constituting the polyvinyl alcohol chain of the modified vinyl alcohol-based polymer is 0.1 mol % to 10 mol %.

A modified vinyl alcohol-based polymer includes a polyoxyalkylene unit, and an organic acid unit bonded to a polyvinyl alcohol chain, the polyoxyalkylene unit includes a moiety represented by the general formula (I), the moiety being bonded to the polyvinyl alcohol chain only via an ether bond and/or a carbon-carbon bond, wherein a ratio of a number of moles of monomer units bonded to the polyoxyalkylene unit to a total number of moles of the monomer units constituting the polyvinyl alcohol chain of the modified vinyl alcohol-based polymer is 0.01 mol % to 5 mol %, and a ratio of a number of moles of the organic acid unit to the total number of moles of the monomer units constituting the polyvinyl alcohol chain of the modified vinyl alcohol-based polymer is 0.1 mol % to 10 mol %.

A method for producing a modified polytetrafluoroethylene, the method including: polymerizing tetrafluoroethylene in an aqueous medium in which a polymer having units based on a fluorine-free monomer is present. The fluorine-free monomer is a monomer represented by formula (1): CH.sub.2═CR.sup.1-L-R.sup.2, where R.sup.1 is a hydrogen atom or an alkyl group, L is a single bond, —CO—O—*, —O—CO—* or —O—, * is a bonding position to R.sup.2, and R.sup.2 is an alkyl group. To the total amount of tetrafluoroethylene supplied to the polymerization, a proportion of the polymer is from 0.001 to 0.050 mass %.

A method for producing a modified polytetrafluoroethylene, the method including: polymerizing tetrafluoroethylene in an aqueous medium in which a polymer having units based on a fluorine-free monomer is present. The fluorine-free monomer is a monomer represented by formula (1): CH.sub.2═CR.sup.1-L-R.sup.2, where R.sup.1 is a hydrogen atom or an alkyl group, L is a single bond, —CO—O—*, —O—CO—* or —O—, * is a bonding position to R.sup.2, and R.sup.2 is an alkyl group. To the total amount of tetrafluoroethylene supplied to the polymerization, a proportion of the polymer is from 0.001 to 0.050 mass %.

The present invention is related to water-swellable polymer particles which contain a hydrophilic base polymer (B) and a hydrophobic polymer (P). It is also related to a process for producing the water-swellable polymer particles, an article containing the water-swellable polymer particles and the use of the water-swellable polymer particles.

The present disclosure relates to compositions comprising a copolymer derived from a vinyl aromatic monomer, a (meth)acrylate monomer, an acid monomer, and a copolymerizable surfactant and compositions comprising the same. The (meth)acrylate monomer can be selected from a monomer having a theoretical glass transition temperature (Tg) for its corresponding homopolymer of 0° C. or less or a hydrophobic (meth)acrylate monomer. In some embodiments, the copolymer is further derived from an organosilane. The copolymers can have a theoretical glass transition temperature (Tg) from −60° C. to 80° C. and a number average particle size of 250 nm or less. The compositions can be used to prepare compositions such as coatings that have improved water resistance, blush resistance, and/or resistance to hydrostatic pressures. Methods of making the copolymers are also provided.

The present disclosure relates to compositions comprising a copolymer derived from a vinyl aromatic monomer, a (meth)acrylate monomer, an acid monomer, and a copolymerizable surfactant and compositions comprising the same. The (meth)acrylate monomer can be selected from a monomer having a theoretical glass transition temperature (Tg) for its corresponding homopolymer of 0° C. or less or a hydrophobic (meth)acrylate monomer. In some embodiments, the copolymer is further derived from an organosilane. The copolymers can have a theoretical glass transition temperature (Tg) from −60° C. to 80° C. and a number average particle size of 250 nm or less. The compositions can be used to prepare compositions such as coatings that have improved water resistance, blush resistance, and/or resistance to hydrostatic pressures. Methods of making the copolymers are also provided.