A modified EVOH resin having a primary hydroxyl group in its side chain. In the modified EVOH resin, the proportion of an ethylene structural unit is 1 to 16.5 mol %, and the proportion of a structural unit containing the side-chain primary hydroxyl group is not less than 2.5 mol %.

There is provided a multilayer structure comprising at least a barrier resin layer (X) and an inorganic barrier layer (Y) with a thickness of 500 nm or less which is adjacent to the barrier resin layer (X), wherein the layer (X) is made of a resin composition (x) comprising an ethylene-vinyl alcohol copolymer (A) and a polyamide (B) in a mass ratio (A/B) of 55/45 to 98/2, and the ethylene-vinyl alcohol copolymer (A) has an ethylene content of 20 to 46 mol % and a saponification degree of 90 mol % or more. Thus, there can be provided a multilayer structure having excellent gas barrier properties and appearance even after being subjected to stretching process or retorting process followed by bending process, and a packaging material for retort therewith.

There is provided a multilayer structure comprising at least a barrier resin layer (X) and an inorganic barrier layer (Y) with a thickness of 500 nm or less which is adjacent to the barrier resin layer (X), wherein the layer (X) is made of a resin composition (x) comprising an ethylene-vinyl alcohol copolymer (A) and a polyamide (B) in a mass ratio (A/B) of 55/45 to 98/2, and the ethylene-vinyl alcohol copolymer (A) has an ethylene content of 20 to 46 mol % and a saponification degree of 90 mol % or more. Thus, there can be provided a multilayer structure having excellent gas barrier properties and appearance even after being subjected to stretching process or retorting process followed by bending process, and a packaging material for retort therewith.

A diverting agent of the present invention contains a polyvinyl alcohol-based resin, wherein when the diverting agent is added to a 0.48 mass % aqueous solution of guar gum to prepare a mixed solution having a concentration of 12 mass %, a dispersion liquid obtained by dispersing the mixed solution at 30° C. for 60 minutes is pressurized and dehydrated at a pressure of 1 MPa using a pressure dehydration device including a drainage part having a slit having a width of 2 mm, and a regression line represented by an equation (A): y=ax+b (in the equation (A), y is a cumulative dehydration amount (g), x is a square root of a time (minutes) elapsed from start of pressurization, a and b are a slope and an intercept of the regression line, respectively, and 0<x≤2) is calculated by a least squares method from a scatter diagram plotted on a graph in which the square root x of the time is plotted on a horizontal axis and the cumulative dehydration amount y is plotted on a vertical axis, a slope a of the equation (A) satisfies a condition (B): a≤80.

A diverting agent of the present invention contains a polyvinyl alcohol-based resin, wherein when the diverting agent is added to a 0.48 mass % aqueous solution of guar gum to prepare a mixed solution having a concentration of 12 mass %, a dispersion liquid obtained by dispersing the mixed solution at 30° C. for 60 minutes is pressurized and dehydrated at a pressure of 1 MPa using a pressure dehydration device including a drainage part having a slit having a width of 2 mm, and a regression line represented by an equation (A): y=ax+b (in the equation (A), y is a cumulative dehydration amount (g), x is a square root of a time (minutes) elapsed from start of pressurization, a and b are a slope and an intercept of the regression line, respectively, and 0<x≤2) is calculated by a least squares method from a scatter diagram plotted on a graph in which the square root x of the time is plotted on a horizontal axis and the cumulative dehydration amount y is plotted on a vertical axis, a slope a of the equation (A) satisfies a condition (B): a≤80.

The present invention relates to a method for producing a copolymer of ethylene and a polar group-containing olefin using as a catalyst a metal complex of group 10 elements having a structure represented by formula (C4) and (C5)

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(in the formula, “Men” represents a menthyl group and “Me” represents a methyl group). The method of the present invention makes it possible to produce a polar group-containing olefin polymer available for various applications, as being a high molecular weight body, which has been difficult to produce, and to produce the polymer in a molecular weight range such that the polymer has good moldability.

The present invention relates to a method for producing a copolymer of ethylene and a polar group-containing olefin using as a catalyst a metal complex of group 10 elements having a structure represented by formula (C4) and (C5)

##STR00001##

(in the formula, “Men” represents a menthyl group and “Me” represents a methyl group). The method of the present invention makes it possible to produce a polar group-containing olefin polymer available for various applications, as being a high molecular weight body, which has been difficult to produce, and to produce the polymer in a molecular weight range such that the polymer has good moldability.

The present invention relates to a method for producing a copolymer of ethylene and an allyl monomer that is represented by formula (1) and has a polar group, or a copolymer of ethylene, the allyl monomer that is represented by formula (1) and has a polar group, and another monomer. This production method is characterized by using a metal complex, which is represented by general formula (C1), as a polymerization catalyst and by having a silane compound, which is represented by general formula (2) and has a silicon-hydrogen bond, coexist with the metal complex. (In the formulae, the symbols are as defined in the description.) According to the present invention, a copolymer of an allyl monomer that has a polar group is able to be produced with high catalytic activity, said copolymer being capable of having various applications. ##STR00001##

The present invention relates to a method for producing a copolymer of ethylene and an allyl monomer that is represented by formula (1) and has a polar group, or a copolymer of ethylene, the allyl monomer that is represented by formula (1) and has a polar group, and another monomer. This production method is characterized by using a metal complex, which is represented by general formula (C1), as a polymerization catalyst and by having a silane compound, which is represented by general formula (2) and has a silicon-hydrogen bond, coexist with the metal complex. (In the formulae, the symbols are as defined in the description.) According to the present invention, a copolymer of an allyl monomer that has a polar group is able to be produced with high catalytic activity, said copolymer being capable of having various applications. ##STR00001##

The present invention relates to a method for producing a copolymer of ethylene and an allyl monomer that is represented by formula (1) and has a polar group, or a copolymer of ethylene, the allyl monomer that is represented by formula (1) and has a polar group, and another monomer. This production method is characterized by using a metal complex, which is represented by general formula (C1), as a polymerization catalyst and by having a silane compound, which is represented by general formula (2) and has a silicon-hydrogen bond, coexist with the metal complex. (In the formulae, the symbols are as defined in the description.) According to the present invention, a copolymer of an allyl monomer that has a polar group is able to be produced with high catalytic activity, said copolymer being capable of having various applications. ##STR00001##