Radically polymerizable dental material, which contains at least one ABA or AB block copolymer, preferably at least one monofunctional, radically polymerizable monomer (a) and preferably at least one radically polymerizable urethane di(meth)acrylate telechel (b).

Low molecular weight polyalkyl acrylate polymers can be used as high viscosity base fluids. A corresponding method can be used for their preparation. Lubricant compositions may contain such low molecular weight polyalkyl acrylate polymers and the compositions may be used as automatic transmission fluids, manual transmission fluids, continuously variable transmission fluids, gear oil formulations, industrial gear oil formulations, axle fluid formulations, dual clutch transmission fluids, dedicated hybrid transmission fluids, or hydraulic oils.

A composition with improved storage viscosity is provided. The composition contains a (meth)acrylic-based copolymer (A′) and an epoxy compound (C). A molecule of the (meth)acrylic-based copolymer (A′) includes an XY diblock structure or an XYX triblock structure therein. A number of repeating units which are derived from a (meth)acrylic ester monomer having an alkoxysilyl group and are included in an X block is 1.0 or more on average; an amount of repeating units which are derived from a (meth)acrylic ester monomer having an alkoxysilyl group and are included in a Y block is 0% by weight to 3% by weight, with respect to a weight of all repeating units included in the Y block. A molecular weight distribution (Mw/Mn) of the (meth)acrylic-based copolymer (A′) is 1.8 or less.

A photoresponsive polymer includes a structural unit represented by the following general formula (1), the photoresponsive polymer being fluidized by light irradiation, and reversibly non-fluidized:

[Chemical formula 1]

R.sub.1—Z.sub.1═Z.sub.2—R.sub.2  General formula (1) in the formula, Z.sub.1 and Z.sub.2 each represent CH or N, and Z.sub.1≠Z.sub.2, R.sub.1 represents an aromatic hydrocarbon group having a substituent R.sub.a selected from the group consisting of an alkyl group, an alkoxy group, and a halogen atom at each of two ortho positions with respect to Z.sub.1, R.sub.2 represents an aromatic heterocyclic group with or without a substituent, and at least one of the R.sub.1 and the R.sub.2 is bonded to a group containing a structure derived from a polymerizable group.

A method of preparing PNVCL block polymers as the substrate for thermo-sensitive cultureware is provided. A hydrophobic polymer of poly n-butyl mathacrylate (PBMA) is obtained by atom transfer radical polymerization (ATRP) with typical haloalkane as an initiator. Further a thermo-sensitive block copolymer of poly n-vinyl caprolactam (PNVCL) is obtained by polymerization of N-vinyl caprolactam (NVCL) monomers using the hydrophobic PBMA polymer as a macroinitiator.

Articles having functional surfaces, for example antimicrobial functional surfaces, are prepared by methods comprising anodization. Organophosphorous compounds are deposited on a surface by methods comprising anodization, followed by attaching functional compounds, functional oligomers or functional polymers. Alternatively, functional organophosphorous compounds, functional oligomers or functional polymers are deposited on a surface by methods comprising anodization.

Provided herein are curable compositions for use in a high temperature lithography-based photopolymerization process, and telechelic block polymers and methods of using such polymers in curable compositions to produce medical devices such as orthodontic appliances comprising the polymeric compositions comprising the telechelic block polymers.

A material comprising: a support 10; and a brush layer 20 containing a brush-like polymer chain assemblage 21 formed of a plurality of polymer chains and a swelling liquid 22, in which a brush layer 20 is swollen with the swelling liquid 22, the brush layer 20 retaining on the surface a lubricating liquid 30, and the swelling liquid 22 contained in the brush layer 20 and the lubricating liquid 30 being phase-separated to form a liquid-liquid phase separation interface 40 in between and a sliding system using the material.

Provided herein are block copolymers comprising a hydrophilic polymer segment and a hydrophobic polymer segment, wherein the hydrophilic polymer segment comprises a polymer selected from the group consisting of: poly(ethylene oxide) (PEO), poly(methacrylate phosphatidyl choline) (MPC), and polyvinylpyrrolidone (PVP), wherein the hydrophobic polymer segment comprises

##STR00001##

wherein R′ is —H or —CH.sub.3, wherein R is —NR.sup.1R.sup.2, wherein R.sup.1 and R.sup.2 are alkyl groups, wherein R.sup.1 and R.sup.2 are the same or different, wherein R.sup.1 and R.sup.2 together have from 5 to 16 carbons, wherein R.sup.1 and R.sup.2 may optionally join to form a ring, wherein n is 1 to about 10, and wherein x is about 20 to about 200 in total. Also provided are pH-sensitive micelle compositions for therapeutic and diagnostic applications.

Provided is a polymer functioning as a leveling agent that imparts high smoothness to a coating film. Specifically, a polymer containing a polymer block (A1) of a polymerizable monomer (a1) having a functional group represented by —Si[OSi(R).sub.3].sub.n[R′].sub.3-n (n is an integer of 1 to 3, each R independently represents an alkyl group having 1 to 3 carbon atoms, and each R′ independently represents an alkyl group having 1 to 3 carbon atoms). Also provided are a coating composition, a resist composition, and an article containing the polymer.