A biaxially-oriented film comprising a polyethylene having (A) a melt flow index of 1.0 g/10 min or more, (B) a density of 0.90 g/cm3 to less than 0.940 g/cm.sup.3, (C) a g′.sub.LCB of greater than 0.8, (D) ratio of comonomer content at Mz to comonomer content at Mw is greater than 1.0, (E) ratio of comonomer content at Mn to comonomer content at Mw is greater than 1.0, and (F) a ratio of the g′.sub.LCB to the g′.sub.zave is greater than 1.0, and where the film has a 1% secant in the transverse direction of 70,000 psi or more and Dart Drop of 350 g/mil or more.

A biaxially-oriented film comprising a polyethylene having (A) a melt flow index of 1.0 g/10 min or more, (B) a density of 0.90 g/cm3 to less than 0.940 g/cm.sup.3, (C) a g′.sub.LCB of greater than 0.8, (D) ratio of comonomer content at Mz to comonomer content at Mw is greater than 1.0, (E) ratio of comonomer content at Mn to comonomer content at Mw is greater than 1.0, and (F) a ratio of the g′.sub.LCB to the g′.sub.zave is greater than 1.0, and where the film has a 1% secant in the transverse direction of 70,000 psi or more and Dart Drop of 350 g/mil or more.

A bimodal polymer composition comprising a lower molecular weight homopolymer and a higher molecular weight copolymer wherein the bimodal polymer composition has a density of from about 0.930 gram per cubic centimeter (g/cc) to about 0.970 g/cc, a ratio of high load melt index:melt index of from about 10 to about 150 and an Environmental Stress Crack Resistance (ESCR) of from about 25 hours to about 300 hours when measured in accordance with ASTM D1693 or ASTM D2561. A chromium-catalyzed polymer composition comprising (i) a lower molecular weight homopolymer and (ii) a higher molecular weight copolymer, wherein the bimodal polymer composition has an Environmental Stress Crack Resistance (ESCR) of from about 25 hours to about 300 hours when measured in accordance with ASTM D1693 or ASTM D2561.

A bimodal polymer composition comprising a lower molecular weight homopolymer and a higher molecular weight copolymer wherein the bimodal polymer composition has a density of from about 0.930 gram per cubic centimeter (g/cc) to about 0.970 g/cc, a ratio of high load melt index:melt index of from about 10 to about 150 and an Environmental Stress Crack Resistance (ESCR) of from about 25 hours to about 300 hours when measured in accordance with ASTM D1693 or ASTM D2561. A chromium-catalyzed polymer composition comprising (i) a lower molecular weight homopolymer and (ii) a higher molecular weight copolymer, wherein the bimodal polymer composition has an Environmental Stress Crack Resistance (ESCR) of from about 25 hours to about 300 hours when measured in accordance with ASTM D1693 or ASTM D2561.

Provided is a collection of polymeric beads, wherein the beads comprise (i) 75 to 99% by weight, based on the weight of the bead, polymerized units of monofunctional vinyl monomer, and (ii) 1 to 25% by weight, based on the weight of the bead, polymerized units of multifunctional vinyl monomer; wherein, within each bead, the average concentration of moles of polymerized units of multifunctional vinyl monomer per cubic micrometer is MVAV; wherein, within each bead, T1000 is a sequence of 1,000 unique connected polymerized monomer units; wherein, within each T1000, MVSEQ is the weight percent polymerized units of multifunctional vinyl monomer, based on the weight of T1000; wherein MVRATIO=MVSEQ/MVAV; and wherein 90% or more of the beads by volume are uniform beads, wherein a uniform bead is a bead in which 90% or more of all T1000 sequences has MVRATIO of 1.5 or less.

Provided is a collection of polymeric beads, wherein the beads comprise (i) 75 to 99% by weight, based on the weight of the bead, polymerized units of monofunctional vinyl monomer, and (ii) 1 to 25% by weight, based on the weight of the bead, polymerized units of multifunctional vinyl monomer; wherein, within each bead, the average concentration of moles of polymerized units of multifunctional vinyl monomer per cubic micrometer is MVAV; wherein, within each bead, T1000 is a sequence of 1,000 unique connected polymerized monomer units; wherein, within each T1000, MVSEQ is the weight percent polymerized units of multifunctional vinyl monomer, based on the weight of T1000; wherein MVRATIO=MVSEQ/MVAV; and wherein 90% or more of the beads by volume are uniform beads, wherein a uniform bead is a bead in which 90% or more of all T1000 sequences has MVRATIO of 1.5 or less.

The present disclosure relates to an ethylene/1-hexene copolymer having excellent flexibility and processability and useful for manufacturing high-pressure heating pipes, PE-RT pipes or large-diameter pipes.

The present disclosure relates to an ethylene/1-hexene copolymer having excellent flexibility and processability and useful for manufacturing high-pressure heating pipes, PE-RT pipes or large-diameter pipes.

An interpolymer product comprising: a first ethylene interpolymer comprising ethylene and an α-olefin having a weight-average molecular weight (M.sub.w) of greater than 250,000 and a density of less than 0.930 g/cm.sup.3, and a second ethylene interpolymer comprising ethylene and an α-olefin wherein the second ethylene interpolymer comprises a M.sub.w of less than 70,000 and a density of greater than 0.930 g/cm.sup.3; and wherein the interpolymer product comprises an environmental stress crack resistance (ESCR), measured according to ASTM D1693, Condition B, 10% IGEPAL CO-630, of greater than 90 hours. The interpolymer product may be manufactured in a continuous solution polymerization process utilizing at least two reactors employing at least one single site catalyst formulation and at least one heterogeneous catalyst formulation.

An interpolymer product comprising: a first ethylene interpolymer comprising ethylene and an α-olefin having a weight-average molecular weight (M.sub.w) of greater than 250,000 and a density of less than 0.930 g/cm.sup.3, and a second ethylene interpolymer comprising ethylene and an α-olefin wherein the second ethylene interpolymer comprises a M.sub.w of less than 70,000 and a density of greater than 0.930 g/cm.sup.3; and wherein the interpolymer product comprises an environmental stress crack resistance (ESCR), measured according to ASTM D1693, Condition B, 10% IGEPAL CO-630, of greater than 90 hours. The interpolymer product may be manufactured in a continuous solution polymerization process utilizing at least two reactors employing at least one single site catalyst formulation and at least one heterogeneous catalyst formulation.