A polymerization process includes contacting an ethylene feed containing ethylene monomers with a catalyst feed containing a hafnium-based or zirconium-based single-site catalyst in a solution so as to polymerize the ethylene monomers into long-chain branched high density polyethylene having on average a long-chain branch/polymer chain less than 10 and greater than 0.25. A polymerization composition includes ethylene; a hafnium-based or zirconium-based single-site catalyst; and a long-chain branched high density polyethylene polymerization product, where the long-chain branched high density polyethylene has on average a long-chain branch/polymer chain less than 10 and greater than 0.25; and where at least one of the ethylene, the catalyst, and the product is in solution.

A polymerization process includes contacting an ethylene feed containing ethylene monomers with a catalyst feed containing a hafnium-based or zirconium-based single-site catalyst in a solution so as to polymerize the ethylene monomers into long-chain branched high density polyethylene having on average a long-chain branch/polymer chain less than 10 and greater than 0.25. A polymerization composition includes ethylene; a hafnium-based or zirconium-based single-site catalyst; and a long-chain branched high density polyethylene polymerization product, where the long-chain branched high density polyethylene has on average a long-chain branch/polymer chain less than 10 and greater than 0.25; and where at least one of the ethylene, the catalyst, and the product is in solution.

A copolymer of ethylene and a 1,3-diene, containing more than 50 mol % of ethylene units and containing 1,2-cyclohexanediyl units is provided. The 1,3-diene is 1,3-butadiene or a mixture of 1,3-dienes containing 1,3-butadiene, and the copolymer consists of a main chain and one or more side chains.

A copolymer of ethylene and a 1,3-diene, containing more than 50 mol % of ethylene units and containing 1,2-cyclohexanediyl units is provided. The 1,3-diene is 1,3-butadiene or a mixture of 1,3-dienes containing 1,3-butadiene, and the copolymer consists of a main chain and one or more side chains.

This invention relates to a biaxially-oriented polyethylene film comprising polyethylene having: (A) a melt index, I.sub.2, of 1.0 g/10 min or greater; (B) a density of 0.925 g/cm.sup.3 to 0.945 g/cm.sup.3; (C) a g′.sub.vis of less than 0.8; (D) an Mz of 1,000,000 g/mol or more; (E) an Mw/Mn of 5 or more; (F) an Mw of 100,000 g/mol or more; (G) a ratio of the g′.sub.LCB to the g′.sub.Zave is greater than 1.0; and (H) a Strain Hardening Ratio of 4 or more, where the film has a 1% secant in the transverse direction of 60,000 psi or more, a Dart Drop of 250 g/mil or more, and a ratio of 1% secant MD/1% secant TD is 0.65 or more.

This invention relates to a biaxially-oriented polyethylene film comprising polyethylene having: (A) a melt index, I.sub.2, of 1.0 g/10 min or greater; (B) a density of 0.925 g/cm.sup.3 to 0.945 g/cm.sup.3; (C) a g′.sub.vis of less than 0.8; (D) an Mz of 1,000,000 g/mol or more; (E) an Mw/Mn of 5 or more; (F) an Mw of 100,000 g/mol or more; (G) a ratio of the g′.sub.LCB to the g′.sub.Zave is greater than 1.0; and (H) a Strain Hardening Ratio of 4 or more, where the film has a 1% secant in the transverse direction of 60,000 psi or more, a Dart Drop of 250 g/mil or more, and a ratio of 1% secant MD/1% secant TD is 0.65 or more.

The invention relates to a copolymer of ethylene and of a 1,3-diene of formula CH.sub.2═CR—CH═CH.sub.2, which copolymer bears an amine function, the symbol R representing a hydrocarbon chain having from 3 to 20 carbon atoms. Such a copolymer improves the compromise between the content of ethylene in the polymer, its crystallinity and the stiffness of a rubber composition containing it.

The invention relates to a copolymer of ethylene and of a 1,3-diene of formula CH.sub.2═CR—CH═CH.sub.2, which copolymer bears an amine function, the symbol R representing a hydrocarbon chain having from 3 to 20 carbon atoms. Such a copolymer improves the compromise between the content of ethylene in the polymer, its crystallinity and the stiffness of a rubber composition containing it.

Apparatuses and processes that produce multimodal polyolefins, and in particular, polyethylene resins, are disclosed herein. This is accomplished by using two reactors in series, where one of the reactors is a multi-zone circulating reactor that can circulate polyolefin particles through two polymerization zones optionally having two different flow regimes so that the final multimodal polyolefin has improved product properties and improved product homogeneity.

Apparatuses and processes that produce multimodal polyolefins, and in particular, polyethylene resins, are disclosed herein. This is accomplished by using two reactors in series, where one of the reactors is a multi-zone circulating reactor that can circulate polyolefin particles through two polymerization zones optionally having two different flow regimes so that the final multimodal polyolefin has improved product properties and improved product homogeneity.