A thermoformable film comprises a polyethylene composition. The polyethylene composition comprises a first polyethylene which is an ethylene copolymer having a weight average molecular weight of from 70,000 to 250,000 and a molecular weight distribution M.sub.w/M.sub.n of <2.3, a second polyethylene which is an ethylene copolymer or homopolymer having a weight average molecular weight of from 15,000 to 100,000 and a molecular weight distribution M.sub.w/M.sub.n of <2.3, and a third polyethylene which is an ethylene copolymer or homopolymer having a weight average molecular weight of from 70,000 to 250,000 and a molecular weight distribution M.sub.w/M.sub.n of >2.3, where the first polyethylene has more short chain branching than the second polyethylene or the third polyethylene. The polyethylene composition has a melt flow ratio (I.sub.21/I.sub.2) of ≤50 and an area Dimensional Thermoformability Index (aDTI) at 105° C. of less than 15.

A thermoformable film comprises a polyethylene composition. The polyethylene composition comprises a first polyethylene which is an ethylene copolymer having a weight average molecular weight of from 70,000 to 250,000 and a molecular weight distribution M.sub.w/M.sub.n of <2.3, a second polyethylene which is an ethylene copolymer or homopolymer having a weight average molecular weight of from 15,000 to 100,000 and a molecular weight distribution M.sub.w/M.sub.n of <2.3, and a third polyethylene which is an ethylene copolymer or homopolymer having a weight average molecular weight of from 70,000 to 250,000 and a molecular weight distribution M.sub.w/M.sub.n of >2.3, where the first polyethylene has more short chain branching than the second polyethylene or the third polyethylene. The polyethylene composition has a melt flow ratio (I.sub.21/I.sub.2) of ≤50 and an area Dimensional Thermoformability Index (aDTI) at 105° C. of less than 15.

This disclosure relates to ethylene interpolymer products comprising a Melt Flow-Intrinsic Viscosity Index value, MFIVI, of from ≥ 0.05 to ≤ 0.80; a first derivative of a melt flow distribution function, formula (I) at a loading of 4000 g, of from ≥ -1.85 to ≤-1.51; a sum of unsaturation, SUM.sup.U, from ≥ 0.047 to ≤ 0.100 unsaturations per 100 carbon atoms; and a residual catalytic metal of from ≥ 0.03 to ≤ 5 ppm of hafnium. Ethylene interpolymer products comprise at least two ethylene interpolymers. Ethylene interpolymer products are characterized by a melt index (I.sub.2) from 0.3 to 500 dg/minute, a density from 0.855 to 0.975 g/cc and from 0 to 25 mole percent of one or more a-olefins. Ethylene interpolymer products have polydispersity, M.sub.w/M.sub.n, from 1.7 to 25; and CDBI.sub.50 values from 1% to 98%. These ethylene interpolymer products have utility in flexible as well as rigid applications.

[00001]$\frac{dLog(1/I_n)}{dLog(loading)}$

This disclosure relates to ethylene interpolymer products comprising a Melt Flow-Intrinsic Viscosity Index value, MFIVI, of from ≥ 0.05 to ≤ 0.80; a first derivative of a melt flow distribution function, formula (I) at a loading of 4000 g, of from ≥ -1.85 to ≤-1.51; a sum of unsaturation, SUM.sup.U, from ≥ 0.047 to ≤ 0.100 unsaturations per 100 carbon atoms; and a residual catalytic metal of from ≥ 0.03 to ≤ 5 ppm of hafnium. Ethylene interpolymer products comprise at least two ethylene interpolymers. Ethylene interpolymer products are characterized by a melt index (I.sub.2) from 0.3 to 500 dg/minute, a density from 0.855 to 0.975 g/cc and from 0 to 25 mole percent of one or more a-olefins. Ethylene interpolymer products have polydispersity, M.sub.w/M.sub.n, from 1.7 to 25; and CDBI.sub.50 values from 1% to 98%. These ethylene interpolymer products have utility in flexible as well as rigid applications.

[00001]$\frac{dLog(1/I_n)}{dLog(loading)}$

This invention relates to a compound represented by the formula: T.sub.yLAMX.sub.n-2 wherein: A is a substituted or unsubstituted tetrahydro-as-indacenyl group bonded to M; L is substituted or unsubstituted monocyclic or polycyclic arenyl ligand or monocyclic or polycyclic heteroarenyl ligand bonded to M; M is a group 3, 4, 5, or 6 transition metal (preferably group 4); T is a bridging group bonded to L and A; y is 0 or 1, indicating the absence or presence of T; X is a leaving group, typically a univalent anionic ligand, or two Xs are joined and bound to the metal atom to form a metallocycle ring, or two Xs are joined to form a chelating ligand, a diene ligand, or an alkylidene; n is the oxidation state of M and is 3, 4, 5, or 6.

This invention relates to a compound represented by the formula: T.sub.yLAMX.sub.n-2 wherein: A is a substituted or unsubstituted tetrahydro-as-indacenyl group bonded to M; L is substituted or unsubstituted monocyclic or polycyclic arenyl ligand or monocyclic or polycyclic heteroarenyl ligand bonded to M; M is a group 3, 4, 5, or 6 transition metal (preferably group 4); T is a bridging group bonded to L and A; y is 0 or 1, indicating the absence or presence of T; X is a leaving group, typically a univalent anionic ligand, or two Xs are joined and bound to the metal atom to form a metallocycle ring, or two Xs are joined to form a chelating ligand, a diene ligand, or an alkylidene; n is the oxidation state of M and is 3, 4, 5, or 6.

Low molecular weight, highly branched polyolefins are provided. Also provided are catalyst-mediated methods of making the low molecular weight, highly branched polyolefins and a catalyst system for carrying out the methods. The catalyst system is a homogeneous catalytic system that includes a single-site organozirconium complex and hydrocarbon-soluble perfluoroarylborate co-catalyst that is highly active for the oligomerization of olefin monomers in non-polar media.

Low molecular weight, highly branched polyolefins are provided. Also provided are catalyst-mediated methods of making the low molecular weight, highly branched polyolefins and a catalyst system for carrying out the methods. The catalyst system is a homogeneous catalytic system that includes a single-site organozirconium complex and hydrocarbon-soluble perfluoroarylborate co-catalyst that is highly active for the oligomerization of olefin monomers in non-polar media.

Embodiments of the invention described herein relate to a polyethylene polymer composition suitable for use in the manufacture of packaging articles, flexible films and/or sheets. In one embodiment, the copolymer comprises a polyethylene resin with density 0.918 g/cm.sup.3 to about 0.935 g/cm.sup.3, G′ at G″.sub.(500 Pa) value, as determined from Dynamic Mechanical Analysis at 190° C., of less than 40 Pa, M.sub.z/M.sub.w of greater than 2, CDBI.sub.50 of greater than 60. Other embodiments relate to polymer compositions with defined molecular characteristics and formulations suitable for use in the manufacture of articles including films, sheets, bags and pouches with improved creep resistance and high toughness and a good balance of film stiffness and processability in monolayer and/or multi-layer film structures.

Embodiments of the invention described herein relate to a polyethylene polymer composition suitable for use in the manufacture of packaging articles, flexible films and/or sheets. In one embodiment, the copolymer comprises a polyethylene resin with density 0.918 g/cm.sup.3 to about 0.935 g/cm.sup.3, G′ at G″.sub.(500 Pa) value, as determined from Dynamic Mechanical Analysis at 190° C., of less than 40 Pa, M.sub.z/M.sub.w of greater than 2, CDBI.sub.50 of greater than 60. Other embodiments relate to polymer compositions with defined molecular characteristics and formulations suitable for use in the manufacture of articles including films, sheets, bags and pouches with improved creep resistance and high toughness and a good balance of film stiffness and processability in monolayer and/or multi-layer film structures.