The present invention provides a precoating agent which is used in an image forming method using an active ray curable ink and which is applied to a surface of a recording medium before the active ray curable ink is applied, the precoating agent comprising a crystalline resin and an active ray polymerizable compound.

This invention provides preparations and applications of a highly strong and tough photo-crosslinked hydrogel material. The hydrogel materials are made from the o-nitrobenzyl phototriggers modified photosensitive polymer derivative, double bond groups modified polymer derivative, and photoinitiator. This invention significantly improved the properties of hydrogels by controlling the average molecular weight (arm length) of photosensitive poly (ethylene glycol) (with o-nitrobenzyl phototriggers modification) and its derivatives, and the molar ratio of o-nitrobenzyl phototriggers to poly (ethylene glycol) and its derivatives. Compared with prior technologies, the strength and/or toughness of the hydrogels in this invention are increased by one order of magnitude or even higher. These advances solve the problems of weak mechanical properties in current hydrogel materials and widen the applications of hydrogel materials.

This invention provides preparations and applications of a highly strong and tough photo-crosslinked hydrogel material. The hydrogel materials are made from the o-nitrobenzyl phototriggers modified photosensitive polymer derivative, double bond groups modified polymer derivative, and photoinitiator. This invention significantly improved the properties of hydrogels by controlling the average molecular weight (arm length) of photosensitive poly (ethylene glycol) (with o-nitrobenzyl phototriggers modification) and its derivatives, and the molar ratio of o-nitrobenzyl phototriggers to poly (ethylene glycol) and its derivatives. Compared with prior technologies, the strength and/or toughness of the hydrogels in this invention are increased by one order of magnitude or even higher. These advances solve the problems of weak mechanical properties in current hydrogel materials and widen the applications of hydrogel materials.

Provided is an aqueous resin composition containing a polycarbonate-modified acrylic resin that is a reaction product of a polycarbonate diol (A) made from 1,4-butanediol as an essential raw material and an unsaturated monomer mixture (B) containing methyl methacrylate, an unsaturated monomer (b1) having a hydroxy group, an unsaturated monomer (b2) having a carboxy group, and an unsaturated monomer (b3) having an alicyclic structure as essential components, and an aqueous medium, in which the ratio of the unsaturated monomer (b3) in the unsaturated monomer mixture (B) is in the range of 3 to 60% by mass. This aqueous resin composition is suitable for aqueous paints and plastic molded articles since the composition can form a coating film having high adhesion to a plastic substrate and having high water-resistant adhesion and fragrance resistance.

Provided is an aqueous resin composition containing a polycarbonate-modified acrylic resin that is a reaction product of a polycarbonate diol (A) made from 1,4-butanediol as an essential raw material and an unsaturated monomer mixture (B) containing methyl methacrylate, an unsaturated monomer (b1) having a hydroxy group, an unsaturated monomer (b2) having a carboxy group, and an unsaturated monomer (b3) having an alicyclic structure as essential components, and an aqueous medium, in which the ratio of the unsaturated monomer (b3) in the unsaturated monomer mixture (B) is in the range of 3 to 60% by mass. This aqueous resin composition is suitable for aqueous paints and plastic molded articles since the composition can form a coating film having high adhesion to a plastic substrate and having high water-resistant adhesion and fragrance resistance.

A curable resin composition contains a polycarbonate resin and a styrenic monomer, the polycarbonate resin comprising a terminal structure that has an unsaturated group represented by the following Formula (1):

##STR00001## and a constitutional unit represented by the following Formula (2):

##STR00002##

A curable resin composition contains a polycarbonate resin and a styrenic monomer, the polycarbonate resin comprising a terminal structure that has an unsaturated group represented by the following Formula (1):

##STR00001## and a constitutional unit represented by the following Formula (2):

##STR00002##

The present specification relates to an optical film including a transparent film, and a coating layer on at least one surface of the transparent film, wherein the coating layer includes a polyester-based resin and a polyurethane-based resin, and is formed using a composition having a minimum film-forming temperature difference of 40° C. to 110° C. between the polyester-based resin and the polyurethane-based resin, and a polarizing plate including the same.

The present specification relates to an optical film including a transparent film, and a coating layer on at least one surface of the transparent film, wherein the coating layer includes a polyester-based resin and a polyurethane-based resin, and is formed using a composition having a minimum film-forming temperature difference of 40° C. to 110° C. between the polyester-based resin and the polyurethane-based resin, and a polarizing plate including the same.

There is described an aqueous coating composition, the aqueous coating composition comprising an acrylic polyester resin, obtainable by grafting an acrylic polymer and a polyester material, the polyester material being obtainable by polymerizing: (i) a polyacid component, with (ii) a polyol component. At least one of the polyacid component and/or the polyol component comprises a functional monomer operable to impart functionality on to the polyester resin, such that an acrylic polymer may be grafted with the polyester material via the use of said functionality. The coating composition further containing a crosslinking material, wherein the crosslinking material comprises material according to formula (I); as shown in claim 1; wherein R.sub.1 is selected from aryl (such as C.sub.4 to C.sub.24 aryl), or aralkyl (such as C.sub.5 to C.sub.25 aralkyl); R.sub.2 to R.sub.5 are each independently hydrogen, alkyl (such as C.sub.1 to C.sub.20 alkyl), aryl (such as C.sub.4 to C.sub.24 aryl), aralkyl (such as C.sub.5 to C.sub.25 aralkyl) or —CHR.sub.8OR.sub.9;

wherein R.sub.8 and R.sub.9 are each independently hydrogen, alkyl (such as C.sub.1 to C.sub.20 alkyl), aryl (such as C.sub.4 to C.sub.24 aryl), aralkyl (such as C.sub.5 to C.sub.25 aralkyl), alkoxyalkyl (such as C.sub.2 to C.sub.40 alkoxyalkyl) or an alkaryl (such as C.sub.5 to C.sub.25 alkaryl);
wherein at least one of R.sub.2 to R.sub.5, is —CHR.sub.8OR.sub.9, suitably all of R.sub.2 to R.sub.5, are —CHR.sub.8OR.sub.9.