Patent classifications
C08F290/147
RESIN COMPOSITION FOR STEREOLITHOGRAPHY
The present invention provides a resin composition for stereolithography that enables easy stereolithographical fabrication; and that can produce a cured object having desirable strain recovery, desirable toughness, and desirable water resistance. The present invention relates to a resin composition for stereolithography comprising a polymerizable compound (A) whose homopolymer has a glass transition temperature (Tg) of 37° C. or higher; and a photopolymerization initiator (B), and having a tan δ at 37° C. of 0.3 or less after cure.
RESIN COMPOSITION FOR STEREOLITHOGRAPHY
The present invention provides a resin composition for stereolithography that enables easy stereolithographical fabrication; and that can produce a cured object having desirable strain recovery, desirable toughness, and desirable water resistance. The present invention relates to a resin composition for stereolithography comprising a polymerizable compound (A) whose homopolymer has a glass transition temperature (Tg) of 37° C. or higher; and a photopolymerization initiator (B), and having a tan δ at 37° C. of 0.3 or less after cure.
Photo-curable resin composition for three-dimensional molding, method for three-dimensional molding using the same, and three-dimensional molded product
A photo-curable resin composition for three-dimensional molding which does not require a support material is provided and can be cured by light irradiation while being extruded from a nozzle through a simple FDM method to be stacked and molded in a short period of time. The photo-curable resin composition has a viscosity at 20° C. of 0.2 Pa.Math.s or more and a viscosity at 150° C. of 1000 Pa.Math.s or less.
Photo-curable resin composition for three-dimensional molding, method for three-dimensional molding using the same, and three-dimensional molded product
A photo-curable resin composition for three-dimensional molding which does not require a support material is provided and can be cured by light irradiation while being extruded from a nozzle through a simple FDM method to be stacked and molded in a short period of time. The photo-curable resin composition has a viscosity at 20° C. of 0.2 Pa.Math.s or more and a viscosity at 150° C. of 1000 Pa.Math.s or less.
Resin composition and optical fiber
A resin composition comprises a base resin containing a urethane (meth)acrylate oligomer, a monomer and a photopolymerization initiator, and a hydrophobized spherical inorganic oxide, wherein the inorganic oxide is dispersed in the resin composition and a content of the inorganic oxide is 1 to 60% by mass based on a total amount of the resin composition.
Resin composition and optical fiber
A resin composition comprises a base resin containing a urethane (meth)acrylate oligomer, a monomer and a photopolymerization initiator, and a hydrophobized spherical inorganic oxide, wherein the inorganic oxide is dispersed in the resin composition and a content of the inorganic oxide is 1 to 60% by mass based on a total amount of the resin composition.
LOW-GLOSS CURED PRODUCT HAVING EXCELLENT STAIN RESISTANCE, AND MANUFACTURING METHOD THEREFOR
The present invention relates to a cured product having excellent stain resistance and low gloss, a method of manufacturing the same, and an interior material including the cured product. The cured product according to the present invention includes, along with an acrylic oligomer, an oligomer having a functional group containing silicon (Si) and an oligomer having a functional group containing fluorine (F), and thus, has excellent stain resistance and can implement a micro-folded structure on a surface thereof through extreme ultraviolet rays to be used during curing, thereby being capable of realizing low gloss without a matting agent.
LOW-GLOSS CURED PRODUCT HAVING EXCELLENT STAIN RESISTANCE, AND MANUFACTURING METHOD THEREFOR
The present invention relates to a cured product having excellent stain resistance and low gloss, a method of manufacturing the same, and an interior material including the cured product. The cured product according to the present invention includes, along with an acrylic oligomer, an oligomer having a functional group containing silicon (Si) and an oligomer having a functional group containing fluorine (F), and thus, has excellent stain resistance and can implement a micro-folded structure on a surface thereof through extreme ultraviolet rays to be used during curing, thereby being capable of realizing low gloss without a matting agent.
POLYURETHANE-BASED COMPOSITE MATERIAL PRODUCTION METHOD, POLYURETHANE-BASED COMPOSITE MATERIAL, AND MATERIAL FOR DENTAL CUTTING
To produce a cured body excellent in strength, water resistance, and uniformity, provided is a method of producing a polyurethane-based composite material, including: a polyaddition reaction step of performing a polyaddition reaction in a first raw material composition containing a radically polymerizable monomer (B) free from causing a polyaddition reaction with any of a radically polymerizable diol compound (a1) and a diisocyanate compound (a2), to thereby form a polyurethane component (A) having a number average molecular weight of from 1,500 to 5,000; a second raw material composition-preparing step of preparing a second raw material composition containing the component A, the component B, a radical polymerization initiator, and a filler; and a radical polymerization step of performing radical polymerization using the second raw material composition after completion of the polyaddition reaction step and the second raw material composition-preparing step, wherein a ratio R represented by the following equation 1 is from 20 mass % to 80 mass %: Equation 1 R=100×B/[a1+a2+A+B], where a1, a2, A, and B represent the contents (parts by mass) of the component a1, the component a2, the component A, and the component B in the second raw material composition.
Prepreg resin composition, prepreg, and molded article
Provided is a prepeg resin composition, containing: a urethane (meth)acrylate (A) that is a reaction product of polyisocyanate (a1), polyol (a2), and hydroxy alkyl (meth)acrylate (a3); and a polymerization initiator (B), as an essential component, in which the polyisocyanate (a1) is at least one polyisocyanate selected from 2,4′-diphenyl methane diisocyanate, 4,4′-diphenyl methane diisocyanate, a carbodiimide modified product of 4,4′-diphenyl methane diisocyanate, and polymethylene polyphenyl polyisocyanate, and the polyol (a2) has an aromatic-ring and an oxyalkylene structure. The prepreg resin composition of the invention is excellent in workability and molding properties, and is capable of forming a molded article excellent in various physical properties such as external appearance and heat resistance, and thus, can be preferably used in a prepreg and a molded article thereof.