Embodiments are directed to catalyst systems comprising at least one metal ligand complex and to processes for polyolefin polymerization incorporating the catalyst systems. The metal ligand complexes have the following structures: (I)

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Embodiments are directed to catalyst systems comprising at least one metal ligand complex and to processes for polyolefin polymerization incorporating the catalyst systems. The metal ligand complexes have the following structures:

Embodiments are directed to catalyst systems comprising at least one metal ligand complex and to processes for polyolefin polymerization incorporating the catalyst systems. The metal ligand complexes have the following structures:

Methods for determining the concentration of transition metal compounds in a solution containing more than one transition metal compound are described. Polymerization reactor systems providing real-time monitoring and control of the concentrations of the transition metal components of a multicomponent catalyst system are disclosed, as well as methods for operating such polymerization reactor systems and for improving methods of preparing the multicomponent catalyst system.

Disclosed herein is a cast film comprising a polyethylene composition comprising the reaction product of ethylene and optionally one or more alpha-olefin comonomers, wherein said polyethylene composition is characterized by the following properties: a melt index, I2, measured according to ASTM D1238 (2.16 kg, 190 C.), of from 1 to 20 g/10 min; a density (measured according to ASTM D792) of from 0.935 to 0.970 g/cm3; a melt flow ratio, I.sub.10/I.sub.2, wherein I.sub.10 is measured according to ASTM D1238 (10 kg, 190 C.) of from 5.5 to 7.0; a molecular weight distribution (Mw/Mn) of from 2.2 to 3.5; and a vinyl unsaturation of greater than 0.12 vinyls per one thousand carbon atoms present in the backbone of the composition.

Disclosed herein is a cast film comprising a polyethylene composition comprising the reaction product of ethylene and optionally one or more alpha-olefin comonomers, wherein said polyethylene composition is characterized by the following properties: a melt index, I2, measured according to ASTM D1238 (2.16 kg, 190 C.), of from 1 to 20 g/10 min; a density (measured according to ASTM D792) of from 0.935 to 0.970 g/cm3; a melt flow ratio, I.sub.10/I.sub.2, wherein I.sub.10 is measured according to ASTM D1238 (10 kg, 190 C.) of from 5.5 to 7.0; a molecular weight distribution (Mw/Mn) of from 2.2 to 3.5; and a vinyl unsaturation of greater than 0.12 vinyls per one thousand carbon atoms present in the backbone of the composition.

Processes of polymerizing olefins include contacting ethylene, a (C.sub.3-C.sub.40)alpha-olefin comonomer, and a solvent in the presence of a chain transfer agent and a catalyst system, the catalyst system comprising a metal-ligand complex according to formula (I). ##STR00001##

Processes of polymerizing olefins include contacting ethylene, a (C.sub.3-C.sub.40)alpha-olefin comonomer, and a solvent in the presence of a chain transfer agent and a catalyst system, the catalyst system comprising a metal-ligand complex according to formula (I). ##STR00001##