A polymerization catalyst system, a method of using the polymerization catalyst system, and a polymer produced with the catalyst system. The polymerization catalyst system has a non-metallocene catalyst and a metallocene catalyst. The metallocene catalyst has the formula: wherein R.sup.1 and R.sup.2 are each independently, phenyl, methyl, chloro, fluoro, or a hydrocarbyl group.

A mixed metallocene catalyst system can comprise at least one metallocene catalyst compound comprising a structure represented by formula (A) below and optionally at least one other metallocene catalyst compound having a structure represented by formula (B) below: ##STR00001##
A mixed metallocene catalyst system can additionally include a non-coordinating anion type activator comprising a supported alumoxane or aluminum alkyl, and optionally a scavenger. A process for making a polymeric product can comprise: contacting a C.sub.2-C.sub.22 alpha-olefin feed with the catalyst system to obtain a polymerization reaction mixture; and obtaining a polymer product from the polymerization reaction mixture. A polymer product can be made by the process.

Ethylene-based polymers having a density of 0.952 to 0.968 g/cm.sup.3, a ratio of HLMI/MI from 185 to 550, an IB parameter from 1.46 to 1.80, a tan at 0.1 sec.sup.1 from 1.05 to 1.75 degrees, and a slope of a plot of viscosity versus shear rate at 100 sec.sup.1 from 0.18 to 0.28 are described, with low melt flow versions having a HLMI from 10 to 30 g/10 min and a Mw from 250,000 to 450,000 g/mol, and high melt flow versions having a HLMI from 30 to 55 g/10 min and a Mw from 200,000 to 300,000 g/mol. These polymers have the processability of chromium-based resins, but with improved stress crack resistance and topload strength for bottles and other blow molded products.

The ethylene/1-hexene copolymer according to the present invention has excellent processability and mechanical properties, and thus can be applied to various fields such as food containers.

The present invention relates to a supported hybrid catalyst system for ethylene slurry polymerization and a method for preparing ethylene polymer therewith. The supported hybrid catalyst system according to the present invention may exhibit high activity during ethylene slurry polymerization, and enables preparation of an ethylene polymer having a narrow molecular weight distribution but excellent processability.

The present invention relates to an olefin polymer and a preparation method thereof. The olefin polymer exhibits excellent mechanical strength and high processability, and thus is expected to be utilized as a material for various products. Particularly, the olefin polymer can be stably produced into films by a melt-blowing process and thus is expected to be usefully used as a material for products prepared by a melt-blowing process.

Disclosed herein is a catalyst compound represented by Formula (I) or Formula (II): ##STR00001##
M is a group 4 metal. Each of R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7, R.sup.8, and R.sup.9 is independently hydrogen, or a C1-C50 substituted or unsubstituted hydrocarbyl, halocarbyl, silylcarbyl, alkoxyl, siloxyl, or one or more of R.sup.1 and R.sup.2, R.sup.2 and R.sup.3, R.sup.3 and R.sup.4, R.sup.5 and R.sup.6, R.sup.6 and R.sup.7, and R.sup.7 and R.sup.8 are joined to form cyclic a saturated or unsaturated ring. Each X is independently a halide or C1-C50 substituted or unsubstituted hydrocarbyl, hydride, amide, alkoxide, sulfide, phosphide, halide, or a combination thereof, or two Xs are joined together to form a metallocycle ring, or two Xs are joined to form a chelating ligand, a diene ligand, or an alkylidene. Also disclosed is a method for using the catalyst compound in a catalyst system to produce polyolefin polymers.

This invention relates to a supported catalyst system and process for use thereof. In particular, the catalyst system includes bridged hafnium metallocene compound, an unbridged metallocene compound, a support material and an activator. The catalyst system may be used for preparing polyolefins.

The present invention provides an olefin polymer in which LCB (long chain branch) is introduced into mLLDPE (metallocene linear low-density polyethylene) to control the storage modulus, whereby the olefin polymer has excellent bubble stability and processing load characteristics and exhibits excellent processability during preparation of a film, and further has excellent mechanical properties and transparency.

Methods for determining the concentration of transition metal compounds in a solution containing more than one transition metal compound are described. Polymerization reactor systems providing real-time monitoring and control of the concentrations of the transition metal components of a multicomponent catalyst system are disclosed, as well as methods for operating such polymerization reactor systems and for improving methods of preparing the multicomponent catalyst system.