Patent classifications
C08F4/6567
Ultrahigh-molecular-weight polyethylene powder
The ultrahigh-molecular-weight polyethylene powder of the present invention is an ultrahigh-molecular-weight polyethylene powder having a viscosity-average molecular weight Mv of 10×10.sup.4 or higher and 1000×10.sup.4 or lower, wherein viscosity-average molecular weight Mv(A) of a kneaded product obtained by kneading under specific kneading conditions, and the Mv satisfy the following relationship: “{Mv−Mv(A)}/Mv is 0.20 or less”, and the ultrahigh-molecular-weight polyethylene powder contains an ultrahigh-molecular-weight polyethylene powder having a particle size of 212 μm or larger, wherein the powder having a particle size of 212 μm or larger has an average pore volume of 0.6 ml/g or larger and an average pore size of 0.3 μm or larger.
PIPELINE MEMBER FOR ULTRAPURE WATER AND POLYETHYLENE-BASED RESIN COMPOSITION FOR PIPELINE MEMBER FOR ULTRAPURE WATER
A pipe (10) includes a polyethylene-based resin layer (21) containing a polyethylene-based resin composition as a major component. The polyethylene-based resin layer (21) forms a pipeline member inner surface (10a). The polyethylene-based resin composition has a calcium concentration of 10 ppm or more and 60 ppm or less.
PIPELINE MEMBER FOR ULTRAPURE WATER AND POLYETHYLENE-BASED RESIN COMPOSITION FOR PIPELINE MEMBER FOR ULTRAPURE WATER
A pipe (10) includes a polyethylene-based resin layer (21) containing a polyethylene-based resin composition as a major component. The polyethylene-based resin layer (21) forms a pipeline member inner surface (10a). The polyethylene-based resin composition has a calcium concentration of 10 ppm or more and 60 ppm or less.
Process for Producing Multimodal Polyethylene in-situ Blends Including Ultra-High Molecular Weight Fractions
The present application relates to a process for producing a multimodal polyethylene composition comprising the steps of polymerizing a polyethylene fraction (A-1) having a weight average molecular weight Mw of equal to or more than 500 kg/mol to equal to or less than 10,000 kg/mol and a density of equal to or more than 915 kg/m.sup.3 to equal to or less than 960 kg/m.sup.3 in one reaction step and polymerizing a polyethylene fraction (A-2) having a lower weight average molecular weight Mw as polyethylene fraction (A-1) and a density of equal to or more than 910 kg/m.sup.3 to equal to or less than 975 kg/m.sup.3 in a second reaction step of a sequential multistage process wherein one of said polyethylene fractions is polymerized in the presence of the other of said polyethylene fractions to form a first polyethylene resin (A) having a weight average molecular weight Mw of equal to or more than 150 kg/mol to equal to or less than 1,500 kg/mol, and a density of equal to or more than 910 kg/m.sup.3 to equal to or less than 975 kg/m.sup.3, wherein the weight average molecular weight Mw of the first polyethylene resin (A) is lower than the weight average molecular weight Mw of the polyethylene fraction (A-1), blending the first polyethylene resin (A) with a second polyethylene resin (B) having a weight average molecular weight Mw of equal to or more than 50 kg/mol to less than 500 kg/mol, and a density of equal to or more than 910 kg/m.sup.3 to equal to or less than 970 kg/m.sup.3 to form said multimodal polyethylene composition, wherein the multimodal polyethylene composition a melt flow rate MFR.sub.5 (190° C., 5 kg) of 0.01 to 10 g/10 min and a density of equal to or more than 910 kg/m.sup.3 to equal to or less than 970 kg/m.sup.3 a polyethylene composition obtainable by said process and the polyethylene resin of said first polymerization step.
Process for Producing Multimodal Polyethylene in-situ Blends Including Ultra-High Molecular Weight Fractions
The present application relates to a process for producing a multimodal polyethylene composition comprising the steps of polymerizing a polyethylene fraction (A-1) having a weight average molecular weight Mw of equal to or more than 500 kg/mol to equal to or less than 10,000 kg/mol and a density of equal to or more than 915 kg/m.sup.3 to equal to or less than 960 kg/m.sup.3 in one reaction step and polymerizing a polyethylene fraction (A-2) having a lower weight average molecular weight Mw as polyethylene fraction (A-1) and a density of equal to or more than 910 kg/m.sup.3 to equal to or less than 975 kg/m.sup.3 in a second reaction step of a sequential multistage process wherein one of said polyethylene fractions is polymerized in the presence of the other of said polyethylene fractions to form a first polyethylene resin (A) having a weight average molecular weight Mw of equal to or more than 150 kg/mol to equal to or less than 1,500 kg/mol, and a density of equal to or more than 910 kg/m.sup.3 to equal to or less than 975 kg/m.sup.3, wherein the weight average molecular weight Mw of the first polyethylene resin (A) is lower than the weight average molecular weight Mw of the polyethylene fraction (A-1), blending the first polyethylene resin (A) with a second polyethylene resin (B) having a weight average molecular weight Mw of equal to or more than 50 kg/mol to less than 500 kg/mol, and a density of equal to or more than 910 kg/m.sup.3 to equal to or less than 970 kg/m.sup.3 to form said multimodal polyethylene composition, wherein the multimodal polyethylene composition a melt flow rate MFR.sub.5 (190° C., 5 kg) of 0.01 to 10 g/10 min and a density of equal to or more than 910 kg/m.sup.3 to equal to or less than 970 kg/m.sup.3 a polyethylene composition obtainable by said process and the polyethylene resin of said first polymerization step.
POLYETHYLENE HOMO- OR COPOLYMER HAVING IMPROVED WEAR PROPERTIES
The present invention relates to a polyethylene homo- or copolymer having improved wear properties. In particular, the invention relates to an ultra-high molecular weight polyethylene having improved wear properties prepared using a heterogeneous Ziegler catalyst system. Said polyethylene homo- or copolymer is characterized in that the abrasion index of said polyethylene is related to the elongational stress according to the formula (I): in which ES=elongational stress as measured according to ISO 11542-2:1998 AI=abrasion index, as measured according to ISO 15527:2010 where the reference material according to ISO 15527:2010 is set to 100; β<1.8; and −0.015<a<−0.017.
POLYETHYLENE HOMO- OR COPOLYMER HAVING IMPROVED WEAR PROPERTIES
The present invention relates to a polyethylene homo- or copolymer having improved wear properties. In particular, the invention relates to an ultra-high molecular weight polyethylene having improved wear properties prepared using a heterogeneous Ziegler catalyst system. Said polyethylene homo- or copolymer is characterized in that the abrasion index of said polyethylene is related to the elongational stress according to the formula (I): in which ES=elongational stress as measured according to ISO 11542-2:1998 AI=abrasion index, as measured according to ISO 15527:2010 where the reference material according to ISO 15527:2010 is set to 100; β<1.8; and −0.015<a<−0.017.
A CONTINUOUS PROCESS FOR THE PRODUCTION OF ULTRA-HIGH MOLECULAR WEIGHT POLYETHYLENE
The invention relates to a continuous process for the production of ultra-high molecular weight polyethylene with an Elongational Stress of at least 0.43 N/mm.sup.2. The polymerisation of ethylene takes place in the presence of a catalyst and hydrogen. It is an advantage of the process according to the invention that the use of small amounts of hydrogen during the production of UHM-WPE reduces reactor fouling. Furthermore, the process according to the invention results in longer run times in polymerization reactors, less cleaning cycles to remove reactor fouling and in less need for other anti-fouling agents or anti-static agents.
A CONTINUOUS PROCESS FOR THE PRODUCTION OF ULTRA-HIGH MOLECULAR WEIGHT POLYETHYLENE
The invention relates to a continuous process for the production of ultra-high molecular weight polyethylene with an Elongational Stress of at least 0.43 N/mm.sup.2. The polymerisation of ethylene takes place in the presence of a catalyst and hydrogen. It is an advantage of the process according to the invention that the use of small amounts of hydrogen during the production of UHM-WPE reduces reactor fouling. Furthermore, the process according to the invention results in longer run times in polymerization reactors, less cleaning cycles to remove reactor fouling and in less need for other anti-fouling agents or anti-static agents.
CATALYST COMPOSITION FOR THE POLYMERIZATION OF OLEFINS
The invention relates to a catalyst composition for the polymerization of olefins, in which the catalyst is produced using a metal-containing compound having the formula (I): MeR.sub.nX.sub.3-n (I), in which X is a halogen, Me is a metal of group III of Mendelejev's Periodic Table of Elements, R is a hydrocarbon moiety comprising>2 carbon atoms, and n is 1≦n<3, or a dimer of a compound of formula (I); and the average particle size of the catalyst as reflected by D.sub.50 (measured according to ISO13320) is between 0.5 and 4.5 μηη. The invention also relates to a process for production of said catalyst composition. The invention further relates to ultra-high molecular weight polyethylene produced via a polymerization process using said catalyst composition.