The invention relates to polybutadiene, which contains the monomer units derived from 1,3-butadiene having a vinyl double bond in a proportion of 25 to 75 mole percent, having a trans-double bond in a proportion of 0 to 10 mole percent and a cis-double bond in a proportion of 25 to 75 mole percent, wherein the totality of the monomer units (A), (B) and (C) is supplemented to 100 mole percent, and which is characterized in that it has a number-average mole mass of 1,000 to 3,000 g/mole. The invention further relates to a method for producing polybutadienes, the use of the polybutadiene according to the invention and compositions containing polybutadiene according to the invention.

The invention relates to polybutadiene, which contains the monomer units derived from 1,3-butadiene having a vinyl double bond in a proportion of 25 to 75 mole percent, having a trans-double bond in a proportion of 0 to 10 mole percent and a cis-double bond in a proportion of 25 to 75 mole percent, wherein the totality of the monomer units (A), (B) and (C) is supplemented to 100 mole percent, and which is characterized in that it has a number-average mole mass of 1,000 to 3,000 g/mole. The invention further relates to a method for producing polybutadienes, the use of the polybutadiene according to the invention and compositions containing polybutadiene according to the invention.

A polyester composition includes a polyester, a copolyester-ether, a styrene-butadiene copolymer, and a catalyst. The styrene-butadiene copolymer includes a butadiene monomer unit which is in an amount ranging from 12 wt % to 50 wt % based on a total weight of the styrene-butadiene copolymer. The styrene-butadiene copolymer is in an amount ranging from 0.2 to 4 parts by weight based on 100 parts by weight of the polyester.

The present invention is a method for producing a vulcanized rubber composition that contains a rubber component containing a polyisoprene rubber, and a syndiotactic 1,2-polybutadiene, wherein the syndiotactic 1,2-polybutadiene and the polyisoprene rubber are kneaded at a temperature higher by 10 to 100 C. than the melting point of the syndiotactic 1,2-polybutadiene, and the resultant unvulcanized rubber composition is vulcanized at a temperature falling within a range of the melting point of the syndiotactic 1,2-polybutadiene 15 C. The method improves the crack growth resistance of the vulcanized rubber composition.

The present invention is a method for producing a vulcanized rubber composition that contains a rubber component containing a polyisoprene rubber, and a syndiotactic 1,2-polybutadiene, wherein the syndiotactic 1,2-polybutadiene and the polyisoprene rubber are kneaded at a temperature higher by 10 to 100 C. than the melting point of the syndiotactic 1,2-polybutadiene, and the resultant unvulcanized rubber composition is vulcanized at a temperature falling within a range of the melting point of the syndiotactic 1,2-polybutadiene 15 C. The method improves the crack growth resistance of the vulcanized rubber composition.

The invention relates to polybutadiene, which contains the monomer units derived from 1,3-butadiene having a vinyl double bond in a proportion of 25 to 75 mole percent, having a trans-double bond in a proportion of 0 to 10 mole percent and a cis-double bond in a proportion of 25 to 75 mole percent, wherein the totality of the monomer units (A), (B) and (C) is supplemented to 100 mole percent, and which is characterized in that it has a number-average mole mass of 1,000 to 3,000 g/mole. The invention further relates to a method for producing polybutadienes, the use of the polybutadiene according to the invention and compositions containing polybutadiene according to the invention.

The invention relates to polybutadiene, which contains the monomer units derived from 1,3-butadiene having a vinyl double bond in a proportion of 25 to 75 mole percent, having a trans-double bond in a proportion of 0 to 10 mole percent and a cis-double bond in a proportion of 25 to 75 mole percent, wherein the totality of the monomer units (A), (B) and (C) is supplemented to 100 mole percent, and which is characterized in that it has a number-average mole mass of 1,000 to 3,000 g/mole. The invention further relates to a method for producing polybutadienes, the use of the polybutadiene according to the invention and compositions containing polybutadiene according to the invention.

The present disclosure provides a redox initiator system for initiating polymerization comprising an oxidizing agent, a photolabile reducing agent, and a transition metal complex that participates in a redox cycle. On exposure to actinic radiation, such as UV, the photolabile compound photolyzes, releasing the reducing agent and initiating the redox-initiated polymerization

The present invention provides a method for preparing a transition metal complex, including a step of preparing a dispersion including a transition metal salt or alkoxide, and a coordinating solvent; and a step of reacting an organic borate-based compound containing a carbon-based, silyl-based or amine-based cation and a borate-based bulky anion, with the dispersion, wherein the transition metal is one or more selected from the metals in group 7 to group 12.

The present invention provides a method for preparing a transition metal complex, including a step of preparing a dispersion including a transition metal salt or alkoxide, and a coordinating solvent; and a step of reacting an organic borate-based compound containing a carbon-based, silyl-based or amine-based cation and a borate-based bulky anion, with the dispersion, wherein the transition metal is one or more selected from the metals in group 7 to group 12.