C08F6/22

ACRYLIC RUBBER EXCELLENT IN WATER RESISTANCE
20220389141 · 2022-12-08 · ·

An acrylic rubber including: a polymer composition of: 70 to 99.9% by weight of a bonding unit derived from at least one (meth) acrylic acid ester selected from (meth) acrylic acid alkyl ester and (meth) acrylic acid alkoxyalkyl ester; 0.1 to 10% by weight of a bonding unit derived from a monomer containing a reactive group; and 0 to 20% by weight of a bonding unit derived from other monomer, wherein ash content is 0.15% by weight or less, total amount of sodium and sulfur in the ash is 60% by weight or more, a ratio of sodium to sulfur by weight ratio is in the range of 0.5 to 2.5, ratio of Z-average molecular weight to weight average molecular weight is 1.3 or more, and weight average molecular weight is in the range of 1,000,000 to 5,000,000.

Method for producing polytetrafluoroethylene powder

A method for producing a polytetrafluoroethylene powder, which includes applying an ultrasonic wave to a polytetrafluoroethylene aqueous dispersion containing polytetrafluoroethylene particles to coagulate the polytetrafluoroethylene particles.

Method for producing polytetrafluoroethylene powder

A method for producing a polytetrafluoroethylene powder, which includes applying an ultrasonic wave to a polytetrafluoroethylene aqueous dispersion containing polytetrafluoroethylene particles to coagulate the polytetrafluoroethylene particles.

Process for producing ABS graft copolymers

The invention relates to a process for producing graft copolymers based on acrylonitrile-butadiene-styrene copolymers (ABS), wherein the graft copolymers may be dewatered particularly readily after production and precipitation and have a low residual moisture content after centrifugation. The invention further relates to a process for producing thermoplastic molding materials using the thus obtained ABS graft copolymers.

Process for producing ABS graft copolymers

The invention relates to a process for producing graft copolymers based on acrylonitrile-butadiene-styrene copolymers (ABS), wherein the graft copolymers may be dewatered particularly readily after production and precipitation and have a low residual moisture content after centrifugation. The invention further relates to a process for producing thermoplastic molding materials using the thus obtained ABS graft copolymers.

ACRYLIC EMULSION
20220356283 · 2022-11-10 ·

The present invention addresses the problem of providing an emulsion having excellent emulsion stability and excellent coagulability (salting-out properties) in manufacturing of an acrylic rubber. The present invention provides an acrylic emulsion containing an acrylic polymer having an average particle diameter of 150-300 nm in a step for emulsion-polymerizing a monomer in manufacturing of an acrylic rubber.

ACRYLIC EMULSION
20220356283 · 2022-11-10 ·

The present invention addresses the problem of providing an emulsion having excellent emulsion stability and excellent coagulability (salting-out properties) in manufacturing of an acrylic rubber. The present invention provides an acrylic emulsion containing an acrylic polymer having an average particle diameter of 150-300 nm in a step for emulsion-polymerizing a monomer in manufacturing of an acrylic rubber.

TRANSPARENT THERMOPLASTIC RESIN AND METHOD OF PREPARING THE SAME

The present disclosure relates to a thermoplastic resin having excellent non-whitening properties, impact strength, gloss, and fluidity, and a method of preparing the thermoplastic resin. The thermoplastic resin includes an alkyl acrylate-alkyl methacrylate graft copolymer (A), or the copolymer (A) and a matrix resin (B) including an alkyl methacrylate polymer and/or an alkyl methacrylate-alkyl acrylate copolymer. A transparency of the thermoplastic resin having a thickness of 0.15 mm is less than 2, a total content of the alkyl acrylate in the thermoplastic resin is 20 to 50% by weight, and a butyl acrylate coverage value (X) as calculated by Equation 1 below is 50 or more:


X={(G−Y)/Y}×100,  [Equation 1] wherein G represents a total gel content (%) of the thermoplastic resin, and Y represents a content (% by weight) of butyl acrylate in the gel of the thermoplastic resin.

TRANSPARENT THERMOPLASTIC RESIN AND METHOD OF PREPARING THE SAME

The present disclosure relates to a thermoplastic resin having excellent non-whitening properties, impact strength, gloss, and fluidity, and a method of preparing the thermoplastic resin. The thermoplastic resin includes an alkyl acrylate-alkyl methacrylate graft copolymer (A), or the copolymer (A) and a matrix resin (B) including an alkyl methacrylate polymer and/or an alkyl methacrylate-alkyl acrylate copolymer. A transparency of the thermoplastic resin having a thickness of 0.15 mm is less than 2, a total content of the alkyl acrylate in the thermoplastic resin is 20 to 50% by weight, and a butyl acrylate coverage value (X) as calculated by Equation 1 below is 50 or more:


X={(G−Y)/Y}×100,  [Equation 1] wherein G represents a total gel content (%) of the thermoplastic resin, and Y represents a content (% by weight) of butyl acrylate in the gel of the thermoplastic resin.

ABS MOLDING COMPOSITION FOR SHEET EXTRUSION AND THERMOFORMING WITH HIGH ESCR, HIGH COLOR AND THERMAL STABILITY AND LOW TENDENCY TO DELAMINATION

A thermoplastic molding composition comprising (A) 15 to 45 wt.-% graft copolymer (A) obtained by emulsion polymerization of styrene and acrylonitrile in presence of an agglomerated butadiene rubber latex (A1) with D50 of 150 to 800 nm; (B) 40 to 75 wt.-% copolymer (B) of styrene and acrylonitrile having a weight ratio of 80:20 to 65:35 and Mw of 150,000 to 300,000 g/mol, (C) 2.0 to 5.0 wt.-% elastomeric block copolymer (C) made from 15 to 65 wt.-% diene, and 35 to 85% by weight vinylaromatic monomer; (D) 2.0 to 5.0 wt.-% titanium dioxide pigment D comprising at least 95 wt.-% titanium dioxide and 1.7 to 3.3 wt.-% alumina; and (E) 0 to 7.0 wt.-% of at least one additive/processing aid (E) different from (D); having a high chemical resistance, high color and thermal stability and low tendency to delamination. This can be used for sheet extrusion and thermoforming, in particular as inner liner for a cooling apparatus.