Provided herein are compositions comprising covalent and supramolecular polymers, and methods of preparation and use thereof.

Provided herein are compositions comprising covalent and supramolecular polymers, and methods of preparation and use thereof.

The formaldehyde-free binder for materials containing cellulose contains a hydroxy aldehyde resin polycondensed with an ammonium salt, the resin being obtained, in especially preferred embodiments, from glycerin, in situ, with the aid of hydrogen peroxide. A protein component consisting of animal blood is added. The binder is urea-free and can be used as a one-component or two-component binder. It binds materials such as wood, paper and other natural fibres to form high-quality composite material products.

A cell tissue gel, comprising one or more matrix molecules cross-linked with a cross-linking agent, and a quenching agent bound to a reactive group of the cross-linking agent, wherein the quenching agent contains a moiety that is capable of reacting with the reactive group of the cross-linking agent and the one or more matrix molecules contain one or more functional groups that are capable of cross-linking with the reactive group, the amount of the reactive group of the cross-linking agent being equal to or less than a total amount including the amount of the one or more functional groups and the amount of the moiety.

The present invention discloses a phosphorylated polycondensate high-performance water-reducing agent with a phosphorylated melamine derivative, instead of a conventional carboxyl group or sulfonic group, as a main adsorption group. The use of aryl alkoxypolyether as a side chain of the polymer provides a strong steric effect to improve the dispersibility and dispersion-retaining properties of the polymer. A polycondensate high-performance water-reducing agent and a method for preparing the same provided by the present invention have excellent overall performance, high adaptability for current low-grade raw materials of concrete, strong market demands, and vast application prospects. Additionally, the polycondensate has an advanced preparation process provided with the characteristics of industrially scalable production, which offers the prospect of a core technology in the field of water-reducing agent of concrete so as to promote development of the industry.

The present invention discloses a phosphorylated polycondensate high-performance water-reducing agent with a phosphorylated melamine derivative, instead of a conventional carboxyl group or sulfonic group, as a main adsorption group. The use of aryl alkoxypolyether as a side chain of the polymer provides a strong steric effect to improve the dispersibility and dispersion-retaining properties of the polymer. A polycondensate high-performance water-reducing agent and a method for preparing the same provided by the present invention have excellent overall performance, high adaptability for current low-grade raw materials of concrete, strong market demands, and vast application prospects. Additionally, the polycondensate has an advanced preparation process provided with the characteristics of industrially scalable production, which offers the prospect of a core technology in the field of water-reducing agent of concrete so as to promote development of the industry.

A non-aqueous crosslinkable composition comprising a polyurea having a functionality of equal to or greater than 2; an aldehyde or acetal or hemiacetal thereof; and optionally one or more organic solvents is provided. Further provided is a crosslinked composition, a coating, articles including the coating and a method of making a non-aqueous crosslinkable composition.

A non-aqueous crosslinkable composition comprising a polyurea having a functionality of equal to or greater than 2; an aldehyde or acetal or hemiacetal thereof; and optionally one or more organic solvents is provided. Further provided is a crosslinked composition, a coating, articles including the coating and a method of making a non-aqueous crosslinkable composition.

The instant invention provides cross-linkable coating compositions, process for producing the same, and substrates coated therewith. The cross-linkable coating composition comprises: (a) polyaldehyde, or acetal or hemiacetal thereof; (b) an acid catalyst having pKa of less than 6; (c) a liquid media; (d) an acrylic polycarbamate comprising at least an average of 2.0 carbamate functional groups, wherein said polycarbamate has a glass transition (Tg) of less than 25 C.; and (e) one or more fillers having a pH in the range of equal to or less than 9 and/or one or more pigments having a pH in the range of equal to or less than 9, and/or one or more additives having a pH in the range of equal to or less than 9, wherein said composition has a curing temperature in the range of less than 70 C.

The instant invention provides cross-linkable coating compositions, process for producing the same, and substrates coated therewith. The cross-linkable coating composition comprises: (a) polyaldehyde, or acetal or hemiacetal thereof; (b) an acid catalyst having pKa of less than 6; (c) a liquid media; (d) an acrylic polycarbamate comprising at least an average of 2.0 carbamate functional groups, wherein said polycarbamate has a glass transition (Tg) of less than 25 C.; and (e) one or more fillers having a pH in the range of equal to or less than 9 and/or one or more pigments having a pH in the range of equal to or less than 9, and/or one or more additives having a pH in the range of equal to or less than 9, wherein said composition has a curing temperature in the range of less than 70 C.