A fluorine-free treating composition that includes Component A and Component B, wherein: Component (A) includes one or more polymeric compounds derived from the polymerization of at least one (meth)acrylate monomer comprising at least one hydrocarbon group having from 1 to 60 carbon atoms and at least one isocyanate-derived group, and Component (C) includes one or more polycarbodiimide compounds.

Described herein is a coating material system which includes components (A) to (C) and (K) and also, optionally, further components, where all components (A) to (C) and (K) and also, where present, the further optional components are present separately from one another or are mixed wholly or at least partly with one another.

Component (A) includes at least one polyhydroxy group-containing compound, where the polyhydroxy group-containing compound of component (A) has an acid number of between 0 and 30 mg KOH/g, and component (B) includes at least one polyisocyanate-containing compound. Component (C) is a catalyst including bismuth (Bi) as metal component and at least one further metal component such as lithium (Li). Component (K) is at least one mercapto group-containing compound. Further components which may be present in the coating material system include, for example, hydroxyl-containing compounds (D), coating additives (F), pigments (H) and/or solvents (J).

In an example, a process of forming a flame-retardant polyurethane material includes chemically reacting a polyisocyanate (that includes at least three isocyanate groups) with a phosphonate that includes at least one hydroxyl group to form a polyisocyanate-phosphonate compound. The process also includes forming a mixture that includes the polyisocyanate-phosphonate compound and a polyol. The process further includes polymerizing the mixture to form a flame-retardant polyurethane material.

According to one embodiment, a polyisocyanurate foam board is described. The foam board includes a polyisocyanurate core that is produced from: an isocyanate, a polyol, and a phosphorous containing non-halogenated fire retardant. The foam board also includes a facer material that is applied to at least one surface of the polyisocyanurate core. The polyisocyanurate core has an isocyanate index greater than about 200 and is able to forms a sufficiently stable char when exposed to flame conditions to enable the polyisocyanurate core to pass the ASTM E-84 test. The foam board has an initial R-value of at least 6.40 and exhibits an ASTM E1354-11b test performance that is equivalent with or better than a similar foam board having a halogenated fire retardant, such as tris(2-chloroisopropyl)phosphate (TCPP).

The present invention relates to a self-emulsifying polyisocyanate composition including a reaction mixture of (a) an anionic compound having a specific structure, (b) nonionic hydrophilic group-containing monofunctional alcohol having a specific structure, (c) organic polyisocyanate, and (d) tertiary amine, a two-part coating composition that contains the composition, and a coating film that can be obtained from the coating composition.

The present disclosure provides a liquid-state reactive polyurethane adhesive, which includes a polyurethane prepolymer. The polyurethane prepolymer is blocked by an isocyanate group, and the polyurethane prepolymer is obtained by a polymerization reaction, a reactive monomer of the polymerization reaction includes a polyisocyanate, a polyol, a stabilizer, a catalyst and a hydrophobic filler. A functionality of the polyisocyanate is 2.4 to 3. A molecular weight of the polyol is 1000 to 8000, and the polyol has hydrolysis resistance. The stabilizer has a structure represented by formula (I). The catalyst has a structure represented by formula (II). Formula (I) and formula (II) are as defined in the specification.

The present disclosure provides a liquid-state reactive polyurethane adhesive, which includes a polyurethane prepolymer. The polyurethane prepolymer is blocked by an isocyanate group, and the polyurethane prepolymer is obtained by a polymerization reaction, a reactive monomer of the polymerization reaction includes a polyisocyanate, a polyol, a stabilizer, a catalyst and a hydrophobic filler. A functionality of the polyisocyanate is 2.4 to 3. A molecular weight of the polyol is 1000 to 8000, and the polyol has hydrolysis resistance. The stabilizer has a structure represented by formula (I). The catalyst has a structure represented by formula (II). Formula (I) and formula (II) are as defined in the specification.

A multi-functional polyurethane coating composition can include water and polyurethane particles including a blend of polyurethane polymers with polyurethane backbones. The polyurethane particles can include multiple pendant groups independently attached to one or multiple polyurethane backbones within the blend of polyurethane polymers. The multiple pendant groups of the polyurethane particles include polyalkylene oxides, aliphatic phosphonium salts, and epoxides.

A multi-functional polyurethane coating composition can include water and polyurethane particles including a blend of polyurethane polymers with polyurethane backbones. The polyurethane particles can include multiple pendant groups independently attached to one or multiple polyurethane backbones within the blend of polyurethane polymers. The multiple pendant groups of the polyurethane particles include polyalkylene oxides, aliphatic phosphonium salts, and epoxides.

The invention relates to a process for producing polyisocyanates containing sulfonate groups, the products obtainable or obtained by said process and also to the use thereof as starting component for producing polyurethane plastics. The invention further relates to coating compositions comprising polyisocyanates containing sulfonate groups and also to the substrates coated with said coating compositions.