A solvent-based polyurethane retort adhesive system for producing laminates including: (A) at least one isocyanate compound, Component A, comprising: a blend of: (i) at least one aliphatic-based isocyanate and (ii) at least one aromatic-based isocyanate; and (B) at least one isocyanate-reactive component, Component B, comprising: (i) at least one phosphate ester compound and (ii) at least one polyether polyol having an average molecular weight of less than 1,500 g/mol; a process for producing the above adhesive; a multi-layer laminate product including the above adhesive; and a process for producing a laminate product using the above adhesive.

A solvent-based polyurethane retort adhesive composition for producing laminates including: (A) at least one isocyanate compound, Component A; and (B) at least one isocyanate (NCO)-reactive component, Component B, comprising (i) at least one phosphate ester compound and (ii) at least one polyester polyol having an average molecular weight of greater than 3,000 g/mol; a process for producing the above adhesive; a multi-layer laminate product including the above adhesive; and a process for producing a laminate product using the above adhesive.

A two-part curable urethane-based composition comprising a main agent (A); and a curing agent (B), wherein the main agent (A) contains a urethane prepolymer (a), an isocyanurate modified product of a polyisocyanate compound (b), and a silane coupling agent (c) in a specified ratio, the curing agent (B) contains a polyol (d) having a hydroxyl value of 50 to 500 mgKOH/g and an amine catalyst (e) in a specified amount, a mixing mass ratio of the main agent (A) to the curing agent (B) is 3:1 to 10:1, and an equivalent ratio of NCO group/OH group in the main agent (A) and the curing agent (B), respectively, is 1.0 to 5.0.

Disclosed is an organic amine salt foaming agent, that is, a composite polyurethane foaming agent, comprising: 1) hexafluorobutene; and 2) an alkanolamine salt mixture (MAA), the alkanolamine salt mixture (MAA) contains an organic amine salt compound having the following general formula (I): A.sup.n−[B.sup.m+].sub.p (I); wherein A.sup.n− is one or two or three selected from the following anions: (b) carbonate: CO.sub.3.sup.2−; (c) formate: HCOO.sup.−; (d) bicarbonate: HO—COO.sup.−. A polyurethane foaming method using carbon dioxide and an organic amine in combination is also disclosed, in which carbon dioxide is added to a polyurethane composition for foaming. A method for preparing an alkanolamine carbonate salt with low water content from ammonium carbonate and an epoxide is additionally disclosed, in which a liquid alkanolamine salt mixture is used as a dispersion medium or as a solvent for reaction raw material.

Aqueous hydrophobic polyurethane dispersions are made from urethane prepolymers derived from reacting constituents including at least one polyisocyanate, vegetable oil based saturated monoglycerides, non-isocyanate based urethane polyols prepared from polyamines and cyclic carbonates, at least one long-chain polymeric polyol or long-chain polyol from biorenewable resources, polyols with hydrophilic groups, optional polydimethysiloxane based polyols with hydroxyl functional groups terminated in one end and alkyl groups terminated in another end.

The present disclosure relates to a two-component polyurethane adhesive, based on a polyol component A and a polyisocyanate component B. The two-component polyurethane adhesive exhibits fast cure speed, good adhesion properties and good durability. The two-component polyurethane adhesive is developed for the adhesion adhesion of substrates, wherein the substrates are preferably selected from the group comprising sheet molding compounds (SMCs) and plastic substrates.

Polyurethane foam-forming compositions, methods of producing polyurethane foams, polyurethane foams produced from such compositions made by such methods, as well as isocyanate-reactive compositions. The polyurethane foam-forming compositions include a polyisocyanate; a polyol blend, and a physical blowing agent composition. The polyol blend includes an aromatic amine-initiated polyether polyol having an OH number of at least 200 mg KOH/g and a functionality of at least 3, wherein (i) the aromatic amine-initiated polyether polyol having an OH number of at least 200 mg KOH/g is present in amount of at least 20% by weight, based on the total weight of polyol, and (ii) the polyol blend has a content of —C.sub.2H.sub.4O— units of 2 to 7% by weight, based on total weight of the polyurethane foam-forming composition. The physical blowing agent composition includes cis-1,1,1,4,4,4-hexafluoro-2-butene and trans-1,1,1,4,4,4-hexafluoro-2-butene.

Embodiments of the present disclosure are directed towards formulated polyol compositions that include a sucrose propoxylated, a propoxylated homopolymer triol, and an amine-initiated polyether alcohol.

Disclosed are a foaming material, a thermal insulation cabinet, and preparation methods therefor. The foaming material comprises 100 parts of a combined polyol, 10-30 parts of a foaming agent composition, and 120-150 parts of an isocyanate. In the present invention, the type of the polyol used in a foaming system is adjusted in order to increase the content of a polyester polyol and reduce the content of a polyether polyol, such that the compressive strength of the foaming material is significantly improved without increasing or changing the injection amount.

Provided herein is a dual cure resin useful for the production of an object by additive manufacturing, comprising or consisting essentially of: (a) a photoinitiator; (b) not more than 5, 10 or 20 ppm of a polyurethane catalyst (e.g., tin, tertiary amine, bismuth, zinc, zirconium, or nickel catalysts); (c) a polyol; (d) free (i.e., unblocked) polyisocyanate; and (e) blocked polyisocyanate, the isocyanate groups of which are blocked by reaction with an amine (meth)acrylate blocking agent. Methods of making an object with the resin are also provided.