The invention provides polyurethane and polyisocyanurate foams and methods for the preparation thereof. More particularly, the invention relates to closed-celled, polyurethane and polyisocyanurate foams and methods for their preparation. The foams are characterized by a fine uniform cell structure and little or no foam collapse. The foams are produced with a polyol premix composition which comprises a combination of a hydrohaloolefin blowing agent, a polyol, a silicone surfactant, and a precipitation-resistant metal-based catalyst used alone or in combination with an amine catalyst.

HCFO-containing isocyanate-reactive compositions, foam-forming compositions containing such isocyanate-reactive compositions, rigid PUR-PIR foams made using such foam-forming compositions, and methods for producing such foams, including use of such foams as insulation in discontinuous foam panel applications. The isocyanate-reactive composition includes a polyol blend, a blowing agent composition, and a tertiary amine catalyst. The polyol blend includes: (1) an aromatic polyester polyol having a functionality of 1.5 to less than 2.5 and an OH number of 150 to 360 mg KOH/g; (2) an aromatic polyester polyol having a functionality of at least 2.5 and an OH number greater than 360 mg KOH/g, which is present in an amount of at least 10% by weight, based on the total weight of the aromatic polyester polyol in the polyol blend; and (3) an amine-initiated polyether polyol having an OH number of at least 500 mg KOH/g and a functionality of 2.5 to 4. The blowing agent composition includes a hydrochlorofluoroolefin and a carbon dioxide generating chemical blowing agent.

The present invention relates to compositions for use in refrigeration, air-conditioning, and heat pump systems wherein the composition comprises a fluoroolefin and at least one other component. The compositions of the present invention are useful in processes for producing cooling or heat, as heat transfer fluids, foam blowing agents, aerosol propellants, and fire suppression and fire extinguishing agents.

This invention relates to rigid polyurethane foams which are co-blown with a mixture of a hydrocarbon blowing agent and a halogenated olefin blowing agent. This invention also relates to a process for preparing these rigid polyurethane foams, and to an isocyanate-reactive component containing a polyol blend and the mixture of blowing agents. Phase stable isocyanate-reactive blends are also described.

1,1,1,2-tetrafluoropropene (HFO-1234yf) in automobile air conditioning methods are disclosed.

A reactive mixture and method for making a thermoplastic polyurethane (TPU) flexible foam having a predominantly open-cell structure (open-cell content of ≥50% by volume calculated on the total volume of the foam and measured according to ASTM D6226-10) and an apparent density below 200 kg/m.sup.3.

The present disclosure relates to acid-blocked pyrrolidine catalysts for use in a polyurethane formulation. The polyurethane formulation includes the acid-blocked pyrrolidine catalyst, a compound containing an isocyanate functional group, an active hydrogen-containing compound and a halogenated olefin compound. The use of such acid-blocked pyrrolidine catalysts show surprisingly low reactivity with halogenated olefin compounds yet sufficient reactivity to catalyze polyurethane formation.

The invention relates to a thermally insulated conduit pipe, comprising at least one medium pipe, at least one thermal insulation arranged around the medium pipe, and at least one outer jacket arranged around the thermal insulation, wherein the outer jacket possibly comprises a barrier made of plastic, and wherein the thermal insulation comprises a foam, the cell gas of which contains at least 10 vol % HFOs. Such conduit pipe has good insulating behavior, good environmental balance, and is easily producible.

A foamed polymeric insulation product comprises a polymeric foam formed from a foamable polymer composition comprising: a) a thermoplastic matrix polymer composition, and b) a blowing agent composition. A barrier coating is formed on at least one of the first major surface and the second major surface, the barrier coating being formed from a barrier coating composition comprising a dispersion of at least one polymer comprising at least one polymer selected from polyvinylidene dichloride (PVDC), polyvinylidene fluoride (PVDF), polyvinyl chloride (PVC), polyvinyl alcohol, ethylene vinyl alcohol, polyurethane, styrene butadiene (SBR), and combinations or copolymers thereof; and a viscosity modifier.

The invention pertains generally to a shelf-stable polyurethane HFO-blown two-component polyurethane foam composition which includes controlling the ratio of tin-containing catalyst(s) to potassium-containing catalyst(s).