Patent classifications
C08J2203/202
TRI-BLEND BLOWING AGENT COMPOSITION FOR POLYMERIC FOAM
A foamable polymer composition is disclosed comprising a thermoplastic matrix polymer composition, and a tri-blend blowing agent composition. The tri-blend blowing agent comprises 5 wt. % to 55 wt. % of a fluorinated alkene having a GWP less than 5; 30 wt. % to 80 wt. % of a first co-blowing agent comprising a hydrofluorocarbon (HFC) blowing agent having a GWP less than 200; and 0.25 to 25 wt. % of a second co-blowing agent comprising an HFC blowing agent having a GWP above 500. The tri-blend blowing agent composition has a total GWP of less than 550.
Azeotrope or azeotrope like compositions comprising 1234yf
The present invention provides azeotropic or azeotrope-like compositions comprising 1234yf and at least one component selected from a group comprising of R-134, and R-134a. The compositions of the present invention are useful as refrigerants, heat transfer fluids, foam blowing agents, aerosol propellants, and fire suppression and fire extinguishing agents.
BLOWING AGENT COMPOSITIONS FOR INSULATING FOAMS
Disclosed is a blowing agent composition comprising a hydrofluoroolefins (HFO) and a branched hydrocarbon, and a foamable polymer composition comprising the blowing agent composition. Also disclosed is a method of making a polymer foam utilizing a blowing agent composition comprising an HFO and a branched hydrocarbon.
PHENOLIC RESIN FOAM LAMINATE BOARD
Provided is a phenolic resin foam laminate board in which a flexible surface material is arranged on at least upper and lower surfaces of a phenolic resin foam. The phenolic resin foam contains HCFO-1224yd(Z), has a density of not less than 20 kg/m.sup.3 and not more than 55 kg/m.sup.3, a closed cell ratio of 80% or more, an average cell diameter of not less than 60 μm and not more than 200 μm, a percentage of an area seeping out from the surface material is 30% or less, and content of HCFO-1224yd(Z) per space volume of 22.4×10.sup.−3 m.sup.3 in the phenolic resin foam is not less than 0.06 mol and not more than 0.35 mol.
METHODS OF MANUFACTURING EXTRUDED POLYSTYRENE FOAMS USING CONDUCTIVE POLYMERS AS AN INFRARED ATTENUATION AGENT
A composition and method for making extruded polystyrene (XPS) foam is provided. The composition includes an infrared attenuation agent composition comprising conductive polymers to achieve an XPS foam having an improved thermal insulation performance. In some exemplary embodiments, the conductive polymers comprise doped polypyrrole and doped polyaniline. In some exemplary embodiments, the XPS foam includes a carbon dioxide-based blowing agent.
Process for Producing Vinyl Aromatic (Co)Polymer Incorporating Post-Consumer and/or Post-Industrial Recycled Polystyrene
The present invention is related to a process for the production of a vinyl aromatic (co)polymer comprising the steps of: a) mixing a fraction (A) comprising one or more monomers selected from the group consisting of styrene, alpha-methyl styrene, acrylonitrile, methyl (meth)acrylate, (meth)acrylic acid and butadiene with a fraction (B) comprising post-consumer recycled vinyl aromatic (co)polymer, wherein the weight ratio of fraction (B) to fraction (A) is comprised between 0.01/1 and 1/1, preferably between 0.05/1 and 0.5/1 b) subjecting the resulting mixture to a free-radical polymerization and polymerizing to a monomer conversion up to 90%, to obtain a polymerized mixture comprising vinyl aromatic (co)polymer; c) vacuum devolatizing the polymerized mixture and recovering vinyl aromatic (co)polymer characterized by a weight average molecular weight comprised between 100,000 and 400,000 g/mol;
wherein one or more bromine derivative capture agents are added before, and/or during and/or after at least one of the steps a) to c); and
wherein 100 parts of one or more bromine derivative capture agents comprises at least 50 parts by weight of hydrotalcite of the formula:
[Mg.sub.1-x Al.sub.x(OH).sub.2].sup.x+(CO.sub.3).sub.x/2.mH.sub.2O
wherein: 0<x≤0.5, and m is a positive number.
The present invention is also related to expandable and extruded expanded vinyl aromatic (co)polymer compositions obtained from vinyl aromatic (co)polymers comprising post-consumer and/or post-industrial vinyl aromatic (co)polymer and to a process for the production of said expandable and extruded expanded vinyl aromatic (co)polymer compositions.
PHENOLIC FOAM AND METHOD OF MANUFACTURE THEREOF
A phenolic foam and method for manufacturing same are described herein. The foam is formed from a foamable phenolic resin composition, and a blowing agent, the phenolic foam comprising 1 to 5% by weight of red phosphorus based on the weight of the phenolic foam wherein said phenolic foam has a density of from 10 kg/m.sup.3 to 100 kg/m.sup.3, a closed cell content of at least 85% as determined in accordance with ASTM D6226 and wherein said foam has a FIGRA.sub.0.2 MJ of 120 W/s or less, when measured according to EN13823 and a thermal conductivity of 0.023 W/m.K or less, at 10° C., in accordance with EN 13166:2012. The foam has excellent thermal insulation performance and excellent fire performance.
BLOWING AGENTS FOR EXTRUDED POLYSTYRENE FOAM AND EXTRUDED POLYSTYRENE FOAM AND METHODS OF FOAMING
Methods, foams and blowing agents for forming for forming extruded polystyrene foam wherein the blowing agent comprises (i) from about 40% by weight to about 70% by weight of one or more HFOs three or four carbon atoms and/or an HFCOs having three or four carbon atoms being selected from the group consisting of 1224yd(Z), 1233zd(E), 1336mzz(Z) and combinations of these; and (ii) from about 30% to about 60% by weight of isobutane, methyl formate and combinations of these.
FIBER REINFORCEMENT FOR ANISOTROPIC FOAMS
The invention relates to a molding composed of extruded foam, wherein at least one fiber (F) is present with a fiber region (FB2) within the molding and is surrounded by the extruded foam, while a fiber region (FB1) of the fiber (F) projects from a first side of the molding and a fiber region (FB3) of the fiber (F) projects from a second side of the molding, and the extruded foam is produced by an extrusion process comprising the following steps: I) providing a polymer melt in an extruder, II) introducing at least one blowing agent into the polymer melt provided in step I) to obtain a foamable polymer melt, III) extruding the foamable polymer melt obtained in step II) from the extruder through at least one die aperture into an area at lower pressure, with expansion of the foamable polymer melt to obtain an expanded foam, and IV) calibrating the expanded foam from step III) by conducting the expanded foam through a shaping tool to obtain the extruded foam.
FIBER-REINFORCEMENT OF FOAM MATERIALS, CONSISTING OF INTERCONNECTED SEGMENTS
The present invention relates to a molding made from foam, wherein at least one fiber (F) is partly within the molding, i.e. is surrounded by the foam. The two ends of the respective fibers (F) that are not surrounded by the foam thus each project from one side of the corresponding molding. The foam comprises at least two mutually bonded foam segments.