C08J9/28

METHOD FOR PRODUCING AN AEROGEL MATERIAL

The invention relates to a method for producing an aerogel material with a porosity of at least 0.55 and an average pore size of 10 nm to 500 nm, having the following steps: a) preparing and optionally activating a sol; b) filling the sol into a casting mold (10); c) gelling the sol, whereby a gel is produced, and subsequently aging the gel; at least one of the following steps d) and e), d) substituting the pore liquid with a solvent; e) chemically modifying the aged and optionally solvent-substituted gel (6) using a reaction agent; followed by f) drying the gel, whereby the aerogel material is formed. The casting mold used in step b) is provided with a plurality of channel-forming elements (2) which are designed such that the sol filled into the casting mold lies overall at a maximum distance X from a channel-forming element over a specified minimum length L defined in the channel direction of the elements, with the proviso that X<15 mm and L/X>3.

METHOD FOR PRODUCING AN AEROGEL MATERIAL

The invention relates to a method for producing an aerogel material with a porosity of at least 0.55 and an average pore size of 10 nm to 500 nm, having the following steps: a) preparing and optionally activating a sol; b) filling the sol into a casting mold (10); c) gelling the sol, whereby a gel is produced, and subsequently aging the gel; at least one of the following steps d) and e), d) substituting the pore liquid with a solvent; e) chemically modifying the aged and optionally solvent-substituted gel (6) using a reaction agent; followed by f) drying the gel, whereby the aerogel material is formed. The casting mold used in step b) is provided with a plurality of channel-forming elements (2) which are designed such that the sol filled into the casting mold lies overall at a maximum distance X from a channel-forming element over a specified minimum length L defined in the channel direction of the elements, with the proviso that X<15 mm and L/X>3.

FILM WITH VOID SPACES BONDED THROUGH CATALYSIS AND METHOD OF PRODUCING THE SAME

A film is provided with void spaces having a porous structure with less cracks and a high proportion of void space as well as having strength. The film with void spaces includes one kind or two or more kinds of structural units that form a structure with minute void spaces, wherein the structural units are chemically bonded through catalysis. For example, the abrasion resistance measured with BEMCOT® is in the range from 60% to 100%, and the folding endurance measured by the MIT test is 100 times or more. The film with void spaces can be produced by forming the precursor of the silicone porous body using sol containing pulverized products of a gelled silicon compound and then chemically bonding the pulverized products contained in the precursor of the silicone porous body. The chemical bond among the pulverized products is preferably a chemical crosslinking bond among the pulverized products.

FILM WITH VOID SPACES BONDED THROUGH CATALYSIS AND METHOD OF PRODUCING THE SAME

A film is provided with void spaces having a porous structure with less cracks and a high proportion of void space as well as having strength. The film with void spaces includes one kind or two or more kinds of structural units that form a structure with minute void spaces, wherein the structural units are chemically bonded through catalysis. For example, the abrasion resistance measured with BEMCOT® is in the range from 60% to 100%, and the folding endurance measured by the MIT test is 100 times or more. The film with void spaces can be produced by forming the precursor of the silicone porous body using sol containing pulverized products of a gelled silicon compound and then chemically bonding the pulverized products contained in the precursor of the silicone porous body. The chemical bond among the pulverized products is preferably a chemical crosslinking bond among the pulverized products.

PRODUCTION METHOD FOR AEROGEL LAMINATE, AND AEROGEL LAMINATE ROLL

The present invention relates to a production method for an aerogel laminate including a support, and an aerogel layer disposed on the support and having a thickness of 200 μm or less, the method comprising a step of washing a wet gel laminate including the support and a wet gel layer disposed on the support by a roll-to-roll scheme.

PRODUCTION METHOD FOR AEROGEL LAMINATE, AND AEROGEL LAMINATE ROLL

The present invention relates to a production method for an aerogel laminate including a support, and an aerogel layer disposed on the support and having a thickness of 200 μm or less, the method comprising a step of washing a wet gel laminate including the support and a wet gel layer disposed on the support by a roll-to-roll scheme.

NOVEL POROUS POLYMER MONOLITHS ADAPTED FOR SAMPLE PREPARATION

A porous polymer monolith comprises a polymer body having macroporous through-pores that facilitate fluid flow through the body and an array of mesopores adapted to bind from the fluid flow molecules of a predetermined range of sizes, wherein the surface area of the monolith is predominantly provided by the mesopores. Also disclosed is a method of making a porous polymer monolith. The method includes forming a polymer body by phase separation out of a solution containing at least a monomer, a crosslinker and a primary porogen, whereby the body contains multiple macroporous through-pores, wherein the solution further contains a secondary porogen comprising oligomers inert with respect to the monomer and cross-linker but chemically compatible with the monomer so as to form mesostructures within the polymer body during said phase separation, and washing the mesostructures from the body to provide an array of mesopores such that the surface area of the monolith is predominantly provided by the mesopores.

Gels, Porous Bodies, and Method of Preparing a Gel or a Porous Body
20230235146 · 2023-07-27 ·

[PROBLEMS] To easily provide gels and porous bodies having high strength.

[SOLVING MEANS] A method of producing a porous body according to the present invention is characterized by having a first step of dissolving fibrous polymers each having a reactive functional group in a solution, a second step of freezing the solution in which the fibrous polymers are dissolved, and a third step of cross-linking fibrous polymers to each other by adding a predetermined amount of cross-linking agent to the frozen solution.

Gels, Porous Bodies, and Method of Preparing a Gel or a Porous Body
20230235146 · 2023-07-27 ·

[PROBLEMS] To easily provide gels and porous bodies having high strength.

[SOLVING MEANS] A method of producing a porous body according to the present invention is characterized by having a first step of dissolving fibrous polymers each having a reactive functional group in a solution, a second step of freezing the solution in which the fibrous polymers are dissolved, and a third step of cross-linking fibrous polymers to each other by adding a predetermined amount of cross-linking agent to the frozen solution.

ZEARALENONE FUNCTIONALIZED GRAPHENE SURFACE MOLECULARLY IMPRINTED MATERIAL, PREPARATION METHOD THEREFOR AND USE THEREOF

A zearalenone functionalized graphene surface molecularly imprinted material, a preparation method therefor and the use thereof, which belong to the technical field of molecularly imprinted materials. The zearalenone functionalized graphene surface molecularly imprinted material is prepared by using RGO as a carrier, CDHB as a template molecule, 1-ALPP as a functional monomer, TRIM as a cross-linking agent, AIBN as an initiator, and acetonitrile as a pore-forming agent.