Orthodontic articles and polymerizable resin compositions are described. The orthodontic article comprises a cured composition comprising the reaction product of free-radically polymerizable resin comprising 30 to 70 wt. %, inclusive, of at least one urethane component, and 25 to 70 wt. %, inclusive, of reactive diluent(s) comprising at least one monofunctional (meth)acrylate monomer. The polymerizable resin comprises no greater than 35 wt. % of reactive diluent(s) having a high affinity for water. Reactive diluent(s) such as monofunctional (meth)acrylate monomers having a high affinity for water have low log P values. In one embodiment, the polymerizable resin comprises at least one acidic monomer.

Orthodontic articles and polymerizable resin compositions are described. The orthodontic article comprises a cured composition comprising the reaction product of free-radically polymerizable resin comprising 30 to 70 wt. %, inclusive, of at least one urethane component, and 25 to 70 wt. %, inclusive, of reactive diluent(s) comprising at least one monofunctional (meth)acrylate monomer. The polymerizable resin comprises no greater than 35 wt. % of reactive diluent(s) having a high affinity for water. Reactive diluent(s) such as monofunctional (meth)acrylate monomers having a high affinity for water have low log P values. In one embodiment, the polymerizable resin comprises at least one acidic monomer.

The present disclosure discloses a modified hydroxypropyl methyl cellulose for an enhanced ceramic tile adhesive, which is prepared from the following raw materials by mass percent: 54%-94% of hydroxypropyl methyl cellulose, 5%-40% of starch ether, 0.5%-3% of dispersing agent and 0.5%-3% of rheological agent, wherein the hydroxypropyl methyl cellulose is prepared from cellulose powder, granular caustic soda, liquid caustic soda, chloromethane and propylene oxide. A preparation method includes: (1) weighing the raw materials; (2) mixing the cellulose powder, the granular caustic soda, the liquid caustic soda, the chloromethane and the propylene oxide, carrying out etherification reaction, and then sequentially carrying out neutralization, washing, centrifugation, drying and crushing to obtain the hydroxypropyl methyl cellulose; and (3) mixing and stirring the hydroxypropyl methyl cellulose, the starch ether, the dispersing agent and the rheological agent to obtain the modified hydroxypropyl methyl cellulose.

The present disclosure discloses a modified hydroxypropyl methyl cellulose for an enhanced ceramic tile adhesive, which is prepared from the following raw materials by mass percent: 54%-94% of hydroxypropyl methyl cellulose, 5%-40% of starch ether, 0.5%-3% of dispersing agent and 0.5%-3% of rheological agent, wherein the hydroxypropyl methyl cellulose is prepared from cellulose powder, granular caustic soda, liquid caustic soda, chloromethane and propylene oxide. A preparation method includes: (1) weighing the raw materials; (2) mixing the cellulose powder, the granular caustic soda, the liquid caustic soda, the chloromethane and the propylene oxide, carrying out etherification reaction, and then sequentially carrying out neutralization, washing, centrifugation, drying and crushing to obtain the hydroxypropyl methyl cellulose; and (3) mixing and stirring the hydroxypropyl methyl cellulose, the starch ether, the dispersing agent and the rheological agent to obtain the modified hydroxypropyl methyl cellulose.

The present disclosure discloses a modified hydroxyethyl methyl cellulose for an enhanced ceramic tile adhesive, which is prepared from the following raw materials by mass percent: 54%-94% of hydroxyethyl methyl cellulose, 5%-40% of starch ether, 0.5%-3% of dispersing agent and 0.5%-3% of rheological agent, wherein the hydroxyethyl methyl cellulose is prepared from cellulose powder, granular caustic soda, liquid caustic soda, chloromethane and ethylene oxide. A preparation method includes: (1) weighing the raw materials; (2) mixing the cellulose powder, the granular caustic soda, the liquid caustic soda, the chloromethane and the ethylene oxide, carrying out etherification reaction, and then sequentially carrying out neutralization, washing, centrifugation, drying and crushing to obtain the hydroxyethyl methyl cellulose; and (3) mixing and stirring the hydroxyethyl methyl cellulose, the starch ether, the dispersing agent and the rheological agent to obtain the modified hydroxyethyl methyl cellulose.

The present disclosure discloses a modified hydroxyethyl methyl cellulose for an enhanced ceramic tile adhesive, which is prepared from the following raw materials by mass percent: 54%-94% of hydroxyethyl methyl cellulose, 5%-40% of starch ether, 0.5%-3% of dispersing agent and 0.5%-3% of rheological agent, wherein the hydroxyethyl methyl cellulose is prepared from cellulose powder, granular caustic soda, liquid caustic soda, chloromethane and ethylene oxide. A preparation method includes: (1) weighing the raw materials; (2) mixing the cellulose powder, the granular caustic soda, the liquid caustic soda, the chloromethane and the ethylene oxide, carrying out etherification reaction, and then sequentially carrying out neutralization, washing, centrifugation, drying and crushing to obtain the hydroxyethyl methyl cellulose; and (3) mixing and stirring the hydroxyethyl methyl cellulose, the starch ether, the dispersing agent and the rheological agent to obtain the modified hydroxyethyl methyl cellulose.

Provided is a resin composition capable of forming a coated product that exhibits low adhesion to a metal roll during production and is superior in oxygen barrier property and capable of forming a film or sheet superior in oxygen barrier property, impact strength under low humidity and color tone. The resin composition of the present invention contains 50 to 98 parts by mass of a modified starch (A), 2 to 50 parts by mass of a polyvinyl alcohol (B), 0.1 to 10 parts by mass of a polyoxyalkylene (C), and optionally 0 to 5 parts of a polyol plasticizer (D), wherein the total content of the (A), (B), (C) and (D) is 100 parts by mass.

Provided is a resin composition capable of forming a coated product that exhibits low adhesion to a metal roll during production and is superior in oxygen barrier property and capable of forming a film or sheet superior in oxygen barrier property, impact strength under low humidity and color tone. The resin composition of the present invention contains 50 to 98 parts by mass of a modified starch (A), 2 to 50 parts by mass of a polyvinyl alcohol (B), 0.1 to 10 parts by mass of a polyoxyalkylene (C), and optionally 0 to 5 parts of a polyol plasticizer (D), wherein the total content of the (A), (B), (C) and (D) is 100 parts by mass.

Provided is a resin composition capable of forming a coated product that exhibits low adhesion to a metal roll during production and is superior in oxygen barrier property and capable of forming a film or sheet superior in oxygen barrier property, impact strength under low humidity and color tone. The resin composition of the present invention contains 50 to 98 parts by mass of a modified starch (A), 2 to 50 parts by mass of a polyvinyl alcohol (B), 0.1 to 10 parts by mass of a polyoxyalkylene (C), and optionally 0 to 5 parts of a polyol plasticizer (D), wherein the total content of the (A), (B), (C) and (D) is 100 parts by mass.

Orthodontic articles and polymerizable resin compositions are described. The orthodontic article comprises a cured composition comprising the reaction product of free-radically polymerizable resin comprising 30 to 70 wt. %, inclusive, of at least one urethane component, and 25 to 70 wt. %, inclusive, of reactive diluent(s) comprising at least one monofunctional (meth)acrylate monomer. The polymerizable resin comprises no greater than 35 wt. % of reactive diluent(s) having a high affinity for water. Reactive diluent(s) such as monofunctional (meth)acrylate monomers having a high affinity for water have low log P values. In one embodiment, the polymerizable resin comprises at least one acidic monomer.