A three-dimension forming support material for ink jet includes a warm water-soluble radiation curable compound that exhibits solubility in warm water of at least 40° C. to 90° C. after the compound is cured; and at least one polyglycerin compound selected from the group consisting of fatty acid esters of polyglycerin, ethylene oxide adducts of polyglycerin, and propylene oxide adducts of polyglycerin.

Phase change ink compositions having a phase change carrier composition containing a wax and a wax-soluble near-infrared (NIR) dye having an absorption maximum in the wavelength region from about 700 nm to about 1400 nm. Near-infrared prints prepared with such phase change ink compositions. Methods of producing a layer of such a phase change ink on the surface of a substrate.

Phase change ink compositions having a phase change carrier composition containing a wax and a wax-soluble near-infrared (NIR) dye having an absorption maximum in the wavelength region from about 700 nm to about 1400 nm. Near-infrared prints prepared with such phase change ink compositions. Methods of producing a layer of such a phase change ink on the surface of a substrate.

In one aspect, methods of printing a three-dimensional article are described herein. In some embodiments, a method described herein comprises jetting an ink at a temperature T1 onto a substrate at a temperature T2 to form a layer of the ink on the substrate. The method further comprises subsequently curing the layer of the ink. In some embodiments, T1 is greater than T2 and the ink in an uncured state has a liquid-gel transition temperature below T1 and above T2. Further, the layer of the ink is deposited on the substrate at a rate R1 in mg/s/in.sup.2 that is within 60% of a gelation rate R2 of the ink in inverse minutes in an uncured state at T2. The ink can comprise a curable material and a gellant.

In one aspect, methods of printing a three-dimensional article are described herein. In some embodiments, a method described herein comprises jetting an ink at a temperature T1 onto a substrate at a temperature T2 to form a layer of the ink on the substrate. The method further comprises subsequently curing the layer of the ink. In some embodiments, T1 is greater than T2 and the ink in an uncured state has a liquid-gel transition temperature below T1 and above T2. Further, the layer of the ink is deposited on the substrate at a rate R1 in mg/s/in.sup.2 that is within 60% of a gelation rate R2 of the ink in inverse minutes in an uncured state at T2. The ink can comprise a curable material and a gellant.

A printable non-curable thixotropic hot melt composition is described. The composition comprises non-curable holt melt waxes transformed into a thixotropic composition by the use of thickeners. The thickeners can be added separately to the hot melt wax or formed in-situ, either before or after application to the substrate. A process of forming such printable non-curable thixotropic hot melt composition is described.

A printable non-curable thixotropic hot melt composition is described. The composition comprises non-curable holt melt waxes transformed into a thixotropic composition by the use of thickeners. The thickeners can be added separately to the hot melt wax or formed in-situ, either before or after application to the substrate. A process of forming such printable non-curable thixotropic hot melt composition is described.

A printable non-curable thixotropic hot melt composition is described. The composition comprises non-curable holt melt waxes transformed into a thixotropic composition by the use of thickeners. The thickeners can be added separately to the hot melt wax or formed in-situ. A process of forming such printable non-curable thixotropic hot melt composition is described.

A printable non-curable thixotropic hot melt composition is described. The composition comprises non-curable holt melt waxes transformed into a thixotropic composition by the use of thickeners. The thickeners can be added separately to the hot melt wax or formed in-situ. A process of forming such printable non-curable thixotropic hot melt composition is described.

In one aspect, build materials and support materials for use with a 3D printer are described herein. Such materials include a phosphor component in combination with other components. In some embodiments, the phosphor component of a build material or support material is present in the material in an amount of 0.001-0.5 wt. % and has a peak photoluminescence (PL) emission wavelength of 430-750 nm and a photoluminescence quantum yield (QY) of 0.10-1.