A thermoplastic resin composition including a graft copolymer (B) produced by graft polymerization of a vinyl monomer mixture (m1) including an alkyl (meth)acrylate ester, a vinyl cyanide compound, and an aromatic vinyl compound onto a copolymer (A) produced by copolymerizing an alkyl (meth)acrylate ester (a) and a (meth)acrylate ester (b) including an aromatic hydrocarbon group at a specific ratio and a copolymer (C) that is a product of a polymerization reaction of a vinyl monomer mixture (m2) including an alkyl (meth)acrylate ester. The graft copolymer (B) includes at least a graft copolymer (B) having a specific volume-average particle size. The copolymer (A) has a specific volume-average particle size and a specific particle size distribution.

An aqueous polymer latex composition is described for the preparation of an elastomeric film comprising: (I) particles of a latex polymer obtained by free-radical emulsion polymerization of a mixture of ethylenically unsaturated monomers, the particles bearing functional groups (a); and (II) a cross-linking component selected from monomeric compounds and oligomeric or polymeric compounds that are not prepared be free-radical addition polymerization, the cross-linking component comprising functional groups (b) and (c) that are different from each other, wherein functional group (b) forms upon reaction with functional group (a) a thermally reversible linkage selected from one or more of (i) a linkage having the structural formula

##STR00001##  wherein X, n, R1 and R2 are as defined; and (ii) a beta-hydroxy ester linkage; and functional groups (c) on different molecules of component (II) are capable of reacting with each other to provide elastomeric films having self-healing properties that can be repaired and recycled.

There is provided a water-based resin composition that contains a polymer (A) containing, as essential raw materials, a hydrogenated polybutadiene (a1) with an iodine value in the range of 5 to 25, a monomer (a2) with an acid group, and a monomer (a3) with a hydroxy group, a basic compound (B), and an aqueous medium (C), wherein the hydrogenated polybutadiene (a1) constitutes 4% to 38% by mass of the raw materials of the polymer (A), and the polymer (A) has an acid value in the range of 10 to 65 mgKOH/g. A water-based resin composition of the present invention has high storage stability and forms a coating film with good physical properties, such as high adhesiveness to various substrates and high blocking resistance, and is therefore suitably used in a water-based paint.

There is provided a water-based resin composition that contains a polymer (A) containing, as essential raw materials, a hydrogenated polybutadiene (a1) with an iodine value in the range of 5 to 25, a monomer (a2) with an acid group, and a monomer (a3) with a hydroxy group, a basic compound (B), and an aqueous medium (C), wherein the hydrogenated polybutadiene (a1) constitutes 4% to 38% by mass of the raw materials of the polymer (A), and the polymer (A) has an acid value in the range of 10 to 65 mgKOH/g. A water-based resin composition of the present invention has high storage stability and forms a coating film with good physical properties, such as high adhesiveness to various substrates and high blocking resistance, and is therefore suitably used in a water-based paint.

A laminated sheet with a cover material, an adhesive cover tape, and an electronic component packaging container molded. A laminated sheet having a surface layer on both sides of a substrate layer, and the substrate layer includes 30 to 70 mass % of a component mentioned below, 70 to 30 mass % of a component mentioned below, and 0 to 30 mass % of a recycled material of the laminated sheet to the total mass of the substrate layer. The component is a rubber modified (meth)acrylic acid ester-vinyl aromatic hydrocarbon copolymer having a conjugated diene rubber component content of 5 to 15 mass %. The component is a vinyl aromatic hydrocarbon-conjugated diene block copolymer containing 15 to 30 mass % of monomeric units derived from conjugated dienes. The component is at least one polymer selected from the group consisting of a vinyl aromatic hydrocarbon polymer and a rubber modified vinyl aromatic hydrocarbon polymer.

Compositions which are curable by, for example, exposure to radiation to form useful articles such as three-dimensionally printed objects are prepared using multistage polymers, polymerizing organic substances and (meth)acrylic polymers. The multistage polymer is effective to toughen and impact modify the cured articles, yet the compositions prior to curing are relatively low in viscosity and agglomerate content even at high loadings of multistage polymer.

Compositions which are curable by, for example, exposure to radiation to form useful articles such as three-dimensionally printed objects are prepared using multistage polymers, polymerizing organic substances and (meth)acrylic polymers. The multistage polymer is effective to toughen and impact modify the cured articles, yet the compositions prior to curing are relatively low in viscosity and agglomerate content even at high loadings of multistage polymer.

Disclosed area coating-free metallic thermoplastic resin composition having improved metallic texture and gloss and a molded product having extrusion-molded the same. For example, the molded produce may be manufactured by feeding a master batch containing a styrene-acrylonitrile (SAN) resin and a metal in a weather resistant thermoplastic resin containing an acrylonitrile styrene acrylate (ASA) resin in a side feeding method. The coating-free metallic thermoplastic resin composition may be optimized in types and contents of the master batch and dispersant contained therein. The molded product may be manufactured by feeding the master batch in the side feeding method to improve various physical properties, increase the dispensability and compatibility between compositions, and improve black streaks and flow marks, thereby improving metallic texture and gloss as well as suppressing the occurrence of the appearance defects.

Disclosed area coating-free metallic thermoplastic resin composition having improved metallic texture and gloss and a molded product having extrusion-molded the same. For example, the molded produce may be manufactured by feeding a master batch containing a styrene-acrylonitrile (SAN) resin and a metal in a weather resistant thermoplastic resin containing an acrylonitrile styrene acrylate (ASA) resin in a side feeding method. The coating-free metallic thermoplastic resin composition may be optimized in types and contents of the master batch and dispersant contained therein. The molded product may be manufactured by feeding the master batch in the side feeding method to improve various physical properties, increase the dispensability and compatibility between compositions, and improve black streaks and flow marks, thereby improving metallic texture and gloss as well as suppressing the occurrence of the appearance defects.

There is provided a water-based resin composition that contains a polymer (A) containing, as essential raw materials, a hydrogenated polybutadiene (a1) with an iodine value in the range of 5 to 25, a monomer (a2) with an acid group, and a monomer (a3) with a hydroxy group, a basic compound (B), and an aqueous medium (C), wherein the hydrogenated polybutadiene (a1) constitutes 4% to 38% by mass of the raw materials of the polymer (A), and the polymer (A) has an acid value in the range of 10 to 65 mgKOH/g. A water-based resin composition of the present invention has high storage stability and forms a coating film with good physical properties, such as high adhesiveness to various substrates and high blocking resistance, and is therefore suitably used in a water-based paint.