Methods for the fracking or stimulation of a hydrocarbon-bearing formation are provided in multiple embodiments. According to one method, it comprises the steps of: providing a wellbore having a casing; inserting a plug in the wellbore at a predetermined location; inserting a perforating tool and an acidic composition into the wellbore; wherein the acidic composition includes a corrosion inhibiting composition comprising at least two compounds selected from: Group A-I, and wherein at least two compounds are selected from different groups of the Groups A-I.

Methods for the fracking or stimulation of a hydrocarbon-bearing formation are provided in multiple embodiments. According to one method, it comprises the steps of: providing a wellbore having a casing; inserting a plug in the wellbore at a predetermined location; inserting a perforating tool and an acidic composition into the wellbore; wherein the acidic composition includes a corrosion inhibiting composition comprising at least two compounds selected from: Group A-I, and wherein at least two compounds are selected from different groups of the Groups A-I.

The invention includes methods for stimulating a hydrocarbon-bearing formation by perforating a wellbore and introducing an acidic composition in the wellbore. A preferred embodiment includes inserting an isolation plug in the wellbore at a predetermined location followed by inserting a perforating tool and a breakdown acid into the wellbore. The wellbore is perforated by the tool to create a perforated area. The breakdown acid is allowed to come into contact with the perforated area for a predetermined period of time sufficient to prepare the formation for stimulation. The tool is then removed from the wellbore wherein stimulation of the perforated area is thereby initiated. Also disclosed is a corrosion inhibiting composition for use with the acidic composition.

The invention includes methods for stimulating a hydrocarbon-bearing formation by perforating a wellbore and introducing an acidic composition in the wellbore. A preferred embodiment includes inserting an isolation plug in the wellbore at a predetermined location followed by inserting a perforating tool and a breakdown acid into the wellbore. The wellbore is perforated by the tool to create a perforated area. The breakdown acid is allowed to come into contact with the perforated area for a predetermined period of time sufficient to prepare the formation for stimulation. The tool is then removed from the wellbore wherein stimulation of the perforated area is thereby initiated. Also disclosed is a corrosion inhibiting composition for use with the acidic composition.

A surfactant of formula (I)

##STR00001##

wherein each of R.sub.1 and R.sub.2 are independently a hydrogen, an optionally substituted alkyl, an optionally substituted cycloalkyl, or an optionally substituted arylalkyl, R.sub.3 and R.sub.4 are independently an optionally substituted alkyl, an optionally substituted cycloalkyl, or an optionally substituted arylalkyl, x is an integer in a range of 2-8, y is an integer in a range of 1-15, z is an integer in a range of 4-10, n is an integer in a range of 2-5, and A is one of a carboxybetaine group, a sulfobetaine group, or a hydroxy sulfobetaine group. An oil and gas well servicing fluid containing the surfactant and methods of servicing an oil and gas well are also described.

A surfactant of formula (I)

##STR00001##

wherein each of R.sub.1 and R.sub.2 are independently a hydrogen, an optionally substituted alkyl, an optionally substituted cycloalkyl, or an optionally substituted arylalkyl, R.sub.3 and R.sub.4 are independently an optionally substituted alkyl, an optionally substituted cycloalkyl, or an optionally substituted arylalkyl, x is an integer in a range of 2-8, y is an integer in a range of 1-15, z is an integer in a range of 4-10, n is an integer in a range of 2-5, and A is one of a carboxybetaine group, a sulfobetaine group, or a hydroxy sulfobetaine group. An oil and gas well servicing fluid containing the surfactant and methods of servicing an oil and gas well are also described.

Methods and compositions including silicate shale inhibitor additives. In some embodiments, the methods include introducing a shale inhibitor additive comprising a silicate anion and a quaternary ammonium cation into a treatment fluid; introducing the treatment fluid into a wellbore penetrating at least a portion of a subterranean formation that comprises shale; and allowing the shale inhibitor additive to interact with the shale in the subterranean formation to at least partially inhibit the shale.

Methods and compositions including silicate shale inhibitor additives. In some embodiments, the methods include introducing a shale inhibitor additive comprising a silicate anion and a quaternary ammonium cation into a treatment fluid; introducing the treatment fluid into a wellbore penetrating at least a portion of a subterranean formation that comprises shale; and allowing the shale inhibitor additive to interact with the shale in the subterranean formation to at least partially inhibit the shale.

A method of producing a synthetic functionalized additive including the steps of mixing an amount of a magnesium salt with a fluid medium to produce a magnesium-containing fluid, adding an amount of a silane to the magnesium-containing fluid to produce a reactant mix, adding an amount of an aqueous hydroxide to the reactant mix to produce a reaction mixture, mixing the reaction mixture for a mix period, refluxing the reaction mixture for a reflux period to produce a product mix, treating the product mix to separate the synthetic functionalized additive.

A method of producing a synthetic functionalized additive including the steps of mixing an amount of a magnesium salt with a fluid medium to produce a magnesium-containing fluid, adding an amount of a silane to the magnesium-containing fluid to produce a reactant mix, adding an amount of an aqueous hydroxide to the reactant mix to produce a reaction mixture, mixing the reaction mixture for a mix period, refluxing the reaction mixture for a reflux period to produce a product mix, treating the product mix to separate the synthetic functionalized additive.