Process embodiments for producing green coke from residual oil comprise introducing residual oil and a solvent mixture into a mixing vessel to produce a feed mixture, the solvent mixture comprising at least one paraffinic solvent with a carbon number from 3 to 8 and at least one aromatic solvent, where the solvent mixture comprises from 0.1 to 10% by volume of aromatic solvent and 90 to 99.9% by volume of paraffinic solvent, passing the feed mixture to a solvent deasphalting unit to produce a deasphalted oil (DAO) fraction and an asphalt fraction, and passing the DAO fraction to a delayed coker to produce the green coke and a delayed coker effluent.

Process embodiments for producing high grade coke and fuel grade coke from residual oil comprises: introducing the residual oil and a first paraffinic solvent having a carbon number C.sub.n to a first solvent deasphalting unit to produce a high quality deasphalted oil (HQDAO) fraction and a first asphalt fraction; passing the HQDAO fraction to a delayed coker to produce green coke; passing at least a portion of the first asphalt fraction and a second paraffinic solvent carbon number of C.sub.n+1 to a second solvent deasphalting unit to produce a low quality deasphalted oil (LQDAO) fraction and a second asphalt fraction; and passing the LQDAO fraction to the delayed coker to produce the fuel grade coke.

Methods and systems for producing anode grade coke are disclosed, which allow anode grade coke to be produced from crude oil having a high sulfur content. A fraction of the resid is hydrotreated while another fraction of the resid is treated in a solvent deasphalting unit. A synthetic stream is provided by blending hydrotreated resid with one or more streams from the deasphalting unit. The synthetic stream is fed to an anodic coker unit.

A method of producing low CTE graphite electrodes from needle coke formed from a coal tar distillate material having a relatively high initial boiling point.

The present invention is directed to a method for the prediction of coke morphology from feed characteristics using cross-polarized light optical microscopy, image segmentation, and statistical analysis.

Provided are petroleum coke having a sufficiently small coefficient of thermal expansion (CTE) and yielding sufficiently suppressed puffing phenomenon and a method for stably producing the petroleum coke. Specifically, the method for producing the petroleum coke comprises the step of coking feedstock oil comprising light oil having an end point of distillation of 380° C. or less, and heavy oil having an initial boiling point of 200° C. or more and comprising 50% by mass or more of an aromatic component, sulfur content of 0.5% by mass or less, and nitrogen content of 0.2% by mass or less.

Provided are a method for producing artificial graphite through a vertical graphitization furnace with easy circulation of inert gas, uniform heating and no damage to the furnace; and particulates used therefor. The method comprises steps of: introducing graphitizable particulates having average particle diameter of 3 to 30 mm into an inside of the furnace from upper part thereof, heating the particulates at 2200° C. to 3200° C. while making inert gas flow from lower part toward upper part thereof to graphitize the particulates, and removing the graphite through lower part thereof. The particulates have average particle diameter of 3 to 30 mm and are obtained by granulating mixture comprising 100 wt parts of graphitizable carbonaceous substance powder having average particle diameter of 10 to 20 μm, 3 to 20 wt parts of binder decomposable at lower than 1000° C., and 5 to 30 wt parts of liquid which can dissolve the binder.

To provide low CTE and low puffing needle coke more stably while dealing with changes in the properties of a feedstock. The low CTE and low puffing needle coke is obtained by mixing and coking a needle coke main feedstock of a coal tar-based heavy oil or petroleum-based heavy oil having a weak hydrogen donating property with a PDQI value expressed by equation (1) of less than 5.0, with a secondary feedstock having a strong hydrogen donating property with a PDQI value expressed by equation (1) of 5.0 or more, and calcining the obtained raw coke. [Equation (1)] PDQI=H %×10×(HNβ/H), wherein H % is a hydrogen amount (% by weight) obtained by elemental analysis, and HNβ/H is a ratio of β naphthenic hydrogen to total hydrogen measured by .sup.1H-NMR.

A method for preparing needle coke for ultra-high power (UHP) electrodes from heavy oil is provided. In this method, heavy oil is used as a raw material. The size exclusion chromatography (SEC) is conducted with polystyrene (PS) as a packing material to separate out specific components with a relative molecular weight of 400 to 1,000. The ion-exchange chromatography (IEC) is conducted to remove acidic and alkaline components to obtain a neutral raw material. The neutral raw material is subjected to two-stage consecutive carbonization to obtain green coke, and the green coke is subjected to high-temperature calcination to obtain the needle coke for UHP electrodes. The needle coke has a true density of more than 2.13 g/cm.sup.3 and a coefficient of thermal expansion (CTE) of ≤1.15×10.sup.−6/° C. at 25° C. to 600° C.

Provided here are systems and methods of production of needle coke by processing an aromatic rejects stream containing long chain alkyl monoaromatics and bridged diaromatics through a delayed coking process. Various other embodiments may be disclosed and claimed.