This invention relates a wax inhibitor for hydrocarbon oils comprising an esterified copolymer having repeating structural units derived from an esterified ethylenically unsaturated dicarboxylic acid and α-olefins having at least 18 carbon atoms, whereof at least 3 mol-% of the α-olefins have 30 or more carbon atoms, and wherein the ethylenically unsaturated dicarboxylic acid has been esterified with a mixture of alcohols comprising i) 70 to 97 mol-% of a saturated fatty alcohol having 18 to 24 carbon atoms and ii) 3 to 30 mol-% of an unsaturated alcohol having 16 to 24 carbon atoms.

An ecofriendly corrosion inhibitor composition and a method for inhibiting corrosion on a metal surface with the ecofriendly corrosion inhibitor composition are provided. The ecofriendly corrosion inhibitor composition includes 10-30 weight % of fatty acids derived from waste vegetable oils and 70-90 weight % of heavy aromatic naphtha. The fatty acids derived from waste vegetable oils include oleic acid, linoleic acid, and palmitic acid. In the method, the ecofriendly corrosion inhibitor composition is added to a hydrocarbon fluid exposed to the metal surface and the corrosion inhibitor composition inhibits corrosion on the metal surfaces.

The furnace of a delayed coking unit which is utilized for heating residue feeds to high temperatures can suffer from decrease in run length and fouling caused by caustic carryover from the upstream desalter unit. An antifoulant additive for preventing caustic induced fouling of thermal cracker furnace tubes is disclosed. The described antifoulant additive acts by converting the inorganic caustic compound such as NaOH to naphthenate salt of the metal as well as by reducing the fouling tendency of the whole feedstock, thereby making it ineffective in causing coking reaction. The additive finds application in thermal residue upgradation furnaces such as delayed coking unit, visbreaker, etc.

An advanced regulatory controller for a converter of a catalytic olefins unit is disclosed. A Fluid Catalytic Cracking (FCC) type converter (i.e., reactor-regenerator) is combined with an ethylene style cold-end for product recovery. The regulatory controller operates using an Advanced Regulatory Control (ARC) application using variables, such as a controlled variable, four disturbance variables, associated variable, and a manipulated variable. The ARC application manipulates fuel oil or tail gas flow to a regenerator in response to an expected future steady state value of a regenerator bed temperature resulting from changes in the values of a selected set of the variables.

The invention relates to a process for removing red oils deposits formed in an installation comprising the use of a cleaning agent comprising one or more fatty acid esters to dissolve the red oils deposit and to form a mixture comprising the cleaning agent and the dissolved red oils; and removing the mixture comprising the cleaning agent and the dissolved red oils.

This invention relates a wax inhibitor for hydrocarbon oils comprising an esterified copolymer having repeating structural units derived from an esterified ethylenically unsaturated dicarboxylic acid and α-olefins having at least 18 carbon atoms, whereof at least 3 mol-% of the α-olefins have 30 or more carbon atoms, and wherein the ethylenically unsaturated dicarboxylic acid has been esterified with a mixture of alcohols comprising i) 70 to 97 mol-% of a saturated fatty alcohol having 18 to 24 carbon atoms and ii) 3 to 30 mol-% of an unsaturated alcohol having 16 to 24 carbon atoms.

An ultrasonification system is provided. The ultrasonification system includes a duct having a proximal end and a distal end, and a vibrating head disposed within the duct near the proximal end thereof. A fluid enters the duct from the proximal end and flows toward the distal end. Related apparatus, systems, techniques, and articles are also described.

The present disclosure relates to a device for directing a coking-prone liquid to a high temperature environment, where the device includes an inner tube positioned concentrically within an outer tube, creating a first annular space between an outer wall of the inner tube and an inner wall of the outer tube and a first intermediate tube positioned concentrically around the outer tube, creating a second annular space.

Scavenging chemicals used in mitigation treatments of hydrogen sulfide in hydrocarbon streams often continue to react and form polymers that foul the processing system. Disclosed herein are methods for determining if a scavenging chemical mitigator, or its reaction or degradation product, will polymerized during or after mitigation treatments. This information allows for the optimization of mitigation treatments that pre-emptively control or prevent polymer formation. Such pre-emption measures reduce the cost and time related to remedial actions to treat polymer-fouled equipment.

Methods for preventing elemental sulfur deposition from a hydrocarbon fluid is disclosed. A mercaptan is added to a hydrocarbon fluid that has elemental sulfur and reacted with the elemental sulfur to produce a disulfide and hydrogen sulfide. Amines and/or surfactants can assist with the process. Secondary reactions between the disulfide and the elemental sulfur result in a polysulfide and a solvated sulfur-disulfide complex. The disulfide, hydrogen sulfide, polysulfide and solvated sulfur-disulfide complex do not deposit, and can optionally be removed.