The present invention relates to a process for producing olefins from a hydrocarbon feedstock 11 with a sulfur content of at least 0.1 weight %, an initial boiling point of at least 180? C. and a final boiling point of at least 600? C.

The present disclosure relates to processes for the removal of paraffins. The processes generally include providing a C.sub.4 containing stream including isobutylene, 1-butene, 2-butene, n-butane and isobutane, introducing the C.sub.4 containing stream into a paraffin removal process to form an olefin rich stream, wherein the paraffin removal process is selected from extractive distillation utilizing a solvent including an organonitrile, passing the C.sub.4 containing stream over a semi-permeable membrane and combinations thereof; and recovering the olefin rich stream from the paraffin removal process, wherein the olefin rich stream includes less than 5 wt. % paraffins.

Apparatuses and processes are provided for regulating C7 and C8 feed to an aromatics complex to increase the ratio of a selected xylene isomer to benzene ratio. Reformate may be split into three cuts in a splitter column. A side cut stream comprises predominantly C7 hydrocarbons and a bottoms steam from the splitter column comprises predominantly C8+ hydrocarbons. The relative proportion of the C7 and C8+ hydrocarbon streams sent to the aromatics complex are metered to determine the resulting ratio of a selected xylene isomer to benzene produced by the aromatics complex.

Process and apparatuses for producing benzene and para-xylene from a reformate stream is provided. The process comprises separating the reformate stream to provide a first stream comprising C.sub.4 and lighter hydrocarbons and a second stream comprising aromatic hydrocarbons. The second steam is provided to a reformate splitter to provide a reformate bottoms stream comprising C.sub.8+ aromatic hydrocarbons and a reformate overhead stream comprising C.sub.7 aromatic hydrocarbons. The reformate overhead stream is passed to an aromatics extraction unit to provide an aromatics extract stream comprising benzene and toluene and a raffinate stream comprising non-aromatic hydrocarbons. The reformate bottoms stream and one of the first stream and the raffinate stream is passed to an olefin reduction zone, wherein the reformate bottoms stream and one of the first stream and the raffinate stream are contacted with an olefin saturation catalyst under olefin saturation conditions to produce an olefin-treated reformate stream.

Methods of extracting 1-4 cycle heterocyclic compounds and 2-5 cycle polynuclear aromatic hydrocarbons from a hydrocarbon feedstock are described. The methods include providing a hydrocarbon feedstock containing crude oil fractions, and determining an A/R ratio and an asphaltene concentration of the hydrocarbon feedstock. Based upon the A/R ratio and the asphaltene concentration, the treatable hydrocarbon feedstock undergoes one or more of cracking and fractionating. Subsequently, at least one targeted portion of the heterocyclic compounds is extracted from the fractionated stream with an aqueous solvent. A stream containing the 2-5 cycle polynuclear aromatic hydrocarbons is transferred to an extractor and the 2-5 cycle polynuclear aromatic hydrocarbons are extracted with a solvent system comprising an aprotic solvent.

Process scheme configurations are disclosed that enable conversion of crude oil feeds with several processing units in an integrated manner into petrochemicals. The designs utilize minimum capital expenditures to prepare suitable feedstocks for the steam cracker complex. The integrated process for converting crude oil to petrochemical products including olefins and aromatics, and fuel products, includes mixed feed steam cracking and gas oil steam cracking. Feeds to the mixed feed steam cracker include light products and naphtha from hydroprocessing zones within the battery limits, recycle streams from the C3 and C4 olefins recovery steps, and raffinate from a pyrolysis gasoline aromatics extraction zone within the battery limits. Feeds to the gas oil steam cracker include gas oil range intermediates from the vacuum gas oil hydroprocessing zone. Furthermore, vacuum residue is processed in a delayed coker unit to produce coker naphtha, which is hydrotreated and passed as additional feed to aromatics extraction zone and/or the mixed feed steam cracker, and coker gas oil range intermediates as additional feed to the gas oil hydroprocessing zone.

Apparatuses and processes are provided for regulating C7 and C8 feed to an aromatics complex to increase the ratio of a selected xylene isomer to benzene ratio. Reformate may be split into three cuts in a splitter column. A side cut stream comprises predominantly C7 hydrocarbons and a bottoms steam from the splitter column comprises predominantly C8+ hydrocarbons. The relative proportion of the C7 and C8+ hydrocarbon streams sent to the aromatics complex are metered to determine the resulting ratio of a selected xylene isomer to benzene produced by the aromatics complex.

The present disclosure relates to processes for the removal of paraffins. The processes generally include providing a C.sub.4 containing stream including isobutylene, 1-butene, 2-butene, n-butane and isobutane, introducing the C.sub.4 containing stream into a paraffin removal process to form an olefin rich stream, wherein the paraffin removal process is selected from extractive distillation utilizing a solvent including an organonitrile, passing the C.sub.4 containing stream over a semi-permeable membrane and combinations thereof; and recovering the olefin rich stream from the paraffin removal process, wherein the olefin rich stream includes less than 5 wt. % paraffins.

A process for heavy base oil production, comprising: a. performing an aromatic extraction of a first hydrocarbon feed to produce an aromatic extract, and a waxy raffinate; b. mixing the aromatic extract with a second hydrocarbon feed to make a mixed feed having greater than 2,000 wt ppm sulfur; c. feeding the mixed feed to a hydroprocessing unit to produce a heavy API Group II base oil having a kinematic viscosity at 70 C. from 22.6 to 100 mm.sup.2/s. An integrated refinery process unit for making heavy base oils, comprising: a. an aromatic extraction unit fluidly connected to a solvent dewaxing unit and a hydroprocessing unit; b. a first line from the aromatic extraction unit, that feeds an aromatic extract to a second hydrocarbon feed to make a mixed feed having greater than 2,000 wt ppm sulfur; and c. a connection that feeds the mixed feed to the hydroprocessing unit.

A process for heavy base oil production, comprising: a. performing an aromatic extraction of a first hydrocarbon feed to produce an aromatic extract, and a waxy raffinate; b. mixing the aromatic extract with a second hydrocarbon feed to make a mixed feed having greater than 2,000 wt ppm sulfur; c. feeding the mixed feed to a hydroprocessing unit to produce a heavy API Group II base oil having a kinematic viscosity at 70 C. from 22.6 to 100 mm.sup.2/s. An integrated refinery process unit for making heavy base oils, comprising: a. an aromatic extraction unit fluidly connected to a solvent dewaxing unit and a hydroprocessing unit; b. a first line from the aromatic extraction unit, that feeds an aromatic extract to a second hydrocarbon feed to make a mixed feed having greater than 2,000 wt ppm sulfur; and c. a connection that feeds the mixed feed to the hydroprocessing unit.