Patent classifications
C10M107/10
Base oils and methods of making the same
Aspects of the present disclosure relate to a process for producing synthetic hydrocarbon base oils having advantageous properties for formulation of engine oils, and the base oils obtained by such processes, involving the production of branched alkenes from the oligomerization of C14-C18 olefins. According to one embodiment, the base oils are obtained by first forming a mixture of two or more olefins ranging from C14-C18, where one of the olefins is an alpha olefin and the other has an average double bond position between 1.5-5.0, and oligomerizing this mixture in the presence of a catalyst to form one or more branched alkenes, hydrogenating the branched alkenes, and fractionating to form base oils. According to one aspect, advantageous properties can be obtained by controlling one or more of the degree of branching, branch length, branching positions, selection of the C14-C18 olefins, and catalytic isomerization, during or after the oligomerization process.
Lubricant composition
The present invention relates to a lubricating oil composition containing: (A) a poly-α-olefin base oil obtained by using a metallocene catalyst; (B) a mineral oil-based base oil exhibiting a distillation curve with a temperature gradient Δ|Dt| of distillation temperature between two points 2.0 vol % and 5.0 vol % of distillation amount being 6.8° C./vol % or less; and (C) an ester-based base oil in an amount of 6% by mass or more based on a total amount of the composition.
Base stocks and oil compositions containing the same
This disclosure relates to base stocks comprising a C28-C32 hydrocarbon fraction and optionally a C42-C48 hydrocarbon fraction produced by dimerization and trimerization of a linear C14 mono-olefin, a linear C16 mono-olefin, or a mixture thereof, in the presence of a Lewis acid, oil compositions comprising such base stock(s), and processes for making such base stocks.
Base stocks and oil compositions containing the same
This disclosure relates to base stocks comprising a C28-C32 hydrocarbon fraction and optionally a C42-C48 hydrocarbon fraction produced by dimerization and trimerization of a linear C14 mono-olefin, a linear C16 mono-olefin, or a mixture thereof, in the presence of a Lewis acid, oil compositions comprising such base stock(s), and processes for making such base stocks.
Drag reducing agent containing a great amount of an active base
The invention relates to agents reducing the hydrodynamic drag of a turbulent flow of petroleum products in the process of transportation in pipelines. The technical result of the solution involves the preservation of the polymer structure so that the polymer is more effective in reducing the hydrodynamic drag, grinding costs in the production of the DRA, the aggregation of the DRA while reducing the amount of the separating agent and the need to inject a smaller amount of the reagent to reduce the hydrodynamic drag. The specified technical result is produced due to the development of a reagent for reducing the hydrodynamic drag of hydrocarbon liquids in pipelines, which consists of the first and the second component, in which case the first component comprises the particles of polyalphaolefin or polyacrylate, the second component is an anti-agglomerating agent.
Drag reducing agent containing a great amount of an active base
The invention relates to agents reducing the hydrodynamic drag of a turbulent flow of petroleum products in the process of transportation in pipelines. The technical result of the solution involves the preservation of the polymer structure so that the polymer is more effective in reducing the hydrodynamic drag, grinding costs in the production of the DRA, the aggregation of the DRA while reducing the amount of the separating agent and the need to inject a smaller amount of the reagent to reduce the hydrodynamic drag. The specified technical result is produced due to the development of a reagent for reducing the hydrodynamic drag of hydrocarbon liquids in pipelines, which consists of the first and the second component, in which case the first component comprises the particles of polyalphaolefin or polyacrylate, the second component is an anti-agglomerating agent.
Dimer selective metallocene catalysts, non-aromatic hydrocarbon soluble activators, and processes to produce poly alpha-olefin oligmers therewith
The present disclosure generally relates to process to produce a poly alpha-olefin (PAO), comprising: a) introducing a first alpha-olefin to a first catalyst system comprising non-aromatic hydrocarbon soluble activator and a metallocene compound into a continuous stirred tank reactor or a continuous tubular reactor under first reactor conditions, wherein the first alpha-olefin is preferably introduced to the reactor at a flow rate of about 100 g/hr or more, to form a first reactor effluent comprising PAO (such as at least 60 wt % of PAO dimer and 40 wt % or less of higher oligomers, where the higher oligomers are oligomers that have a degree of polymerization of 3 or more); and b) introducing the first reactor effluent and a second alpha-olefin to a second catalyst composition comprising an acid catalyst, such as BF.sub.3, in a second reactor to form a second reactor effluent comprising PAO trimer.
Dimer selective metallocene catalysts, non-aromatic hydrocarbon soluble activators, and processes to produce poly alpha-olefin oligmers therewith
The present disclosure generally relates to process to produce a poly alpha-olefin (PAO), comprising: a) introducing a first alpha-olefin to a first catalyst system comprising non-aromatic hydrocarbon soluble activator and a metallocene compound into a continuous stirred tank reactor or a continuous tubular reactor under first reactor conditions, wherein the first alpha-olefin is preferably introduced to the reactor at a flow rate of about 100 g/hr or more, to form a first reactor effluent comprising PAO (such as at least 60 wt % of PAO dimer and 40 wt % or less of higher oligomers, where the higher oligomers are oligomers that have a degree of polymerization of 3 or more); and b) introducing the first reactor effluent and a second alpha-olefin to a second catalyst composition comprising an acid catalyst, such as BF.sub.3, in a second reactor to form a second reactor effluent comprising PAO trimer.
Drag Reducing Agent
The present disclosure provides a drag reducing agent. In an embodiment, the drag reducing agent includes a polymer and a liquid carrier. The polymer is composed of one or more C.sub.6-C.sub.14 α-olefin monomers. The polymer includes a residual amount of zirconium. The polymer has an absolute weight average molecular weight (Mw.sub.(Abs)) greater than 1,300,000 g/mol and a (Mw.sub.(Abs)/Mn.sub.(Abs) from 1.3 to 3.0.
Drag Reducing Agent
The present disclosure provides a drag reducing agent. In an embodiment, the drag reducing agent includes a polymer and a liquid carrier. The polymer is composed of one or more C.sub.6-C.sub.14 α-olefin monomers. The polymer includes a residual amount of zirconium. The polymer has an absolute weight average molecular weight (Mw.sub.(Abs)) greater than 1,300,000 g/mol and a (Mw.sub.(Abs)/Mn.sub.(Abs) from 1.3 to 3.0.