A silole derivative is of formula (I): ##STR00001## each of the groups in the above formula is defined as those in the description. The silole derivative of formula (I) has aggregation-induced emission performance, and is particularly applicable in luminescent parts and devices, fluorescent probes, biological imaging, lubricating oils and greases. A lubricating grease composition has photoluminescence performance, as well as one or more of advantageous anti-oxidation properties, anti-wear properties, extreme pressure properties and anti-rust properties. It is applicable in many mechanical equipment in electrical industry, metallurgical industry, food industry, paper industry, automobile industry and aircraft industry.

A method for improving wear control and sludge control, while maintaining or improving fuel efficiency, of a lubricating oil in an engine or other mechanical component lubricated with the lubricating oil by using as the lubricating oil a formulated oil. The formulated oil has a composition including a lubricating oil base stock as a major component, and at least one lubricating oil additive, as a minor component. The at least one lubricating oil additive includes a zirconium-containing compound. The zirconium-containing compound is present in an amount from about 0.1 to about 1200 parts per million (ppm). The zirconium-containing compound is soluble in the lubricating oil base stock. The lubricating oil is useful as a passenger vehicle engine oil (PVEO), a commercial vehicle engine oil (CVEO), and other lubricating oils (hydraulic, gear, transmission, etc.).

A process for detecting oil or lubricant contamination in a manufactured product, the process comprising adding a fluorescent taggant to oils or lubricants contained in processing machinery for said product, conveying said product past an infrared detection apparatus, irradiating said product with infrared radiation from said detection apparatus as it passes the detection apparatus, and detecting infrared radiation emitted from said irradiated product.

An inspection station for detecting oil or lubricant contamination in a manufactured product, the inspection station having (a) a conveyor for advancing manufactured product, and (b) an infrared detection apparatus, including (i) a high intensity infrared light source for directing at the manufactured product, and (ii) a high speed NIR spectrometer sensor tuned to detect an emitted signal from a taggant disposed in the oil or lubricant.

The present invention relates to a method of marking a petroleum hydrocarbon by adding to and uniformly mixing with said petroleum hydrocarbon a chemical marker of general formula (I) ##STR00001##
wherein two of the residues R.sup.1-R.sup.10 are independently of each other selected from C.sub.1-C.sub.4-alkoxy, and eight of the residues R.sup.1-R.sup.10 are independently of each other selected from the group consisting of hydrogen and C.sub.1-C.sub.4-alkyl, as well as to a composition of a petroleum hydrocarbon comprising a petroleum hydrocarbon and at least one chemical marker of general formula (I). The presence and concentration of the chemical marker of general formula (I) in the composition of the petroleum hydrocarbon can be advantageously determined by laser ionization coupled with mass spectrometry or by laser ionization coupled with ion mobility spectrometry.

An inspection station for detecting oil or lubricant contamination in a manufactured product, the inspection station having (a) a conveyor for advancing manufactured product, and (b) an infrared detection apparatus, including (i) a high intensity infrared light source for directing at the manufactured product, and (ii) a high speed NIR spectrometer sensor tuned to detect an emitted signal from a taggant disposed in the oil or lubricant.

The use, as markers of petroleum products, crude oils, biofuels or lubricants, of rare earth complexes or one of the constituents thereof chosen from rare earth ligands or salts, being capable of forming a rare earth complex after the addition of a developing solution. Preferably, the rare earth complex can be detected by time-resolved fluorescence. Also, a marking method and a method for detecting a rare earth complex as a marker of petroleum products, crude oils, biofuels or lubricants.

The present invention relates to a method of marking a petroleum hydrocarbon by adding to and uniformly mixing with said petroleum hydrocarbon a chemical marker of general formula (I)

##STR00001## wherein two of the residues R.sup.1-R.sup.10 are independently of each other selected from C.sub.1-C.sub.4-alkoxy, and eight of the residues R.sup.1-R.sup.10 are independently of each other selected from the group consisting of hydrogen and C.sub.1-C.sub.4-alkyl, as well as to a composition of a petroleum hydrocarbon comprising a petroleum hydrocarbon and at least one chemical marker of general formula (I). The presence and concentration of the chemical marker of general formula (I) in the composition of the petroleum hydrocarbon can be advantageously determined by laser ionization coupled with mass spectrometry or by laser ionization coupled with ion mobility spectrometry.

A method for marking a petroleum hydrocarbon or a liquid biologically derived fuel by adding to the petroleum hydrocarbon or liquid biologically derived fuel a compound having formula C{Ph(R.sup.1).sub.i(OR.sup.2).sub.j}.sub.2{Ph(R.sup.3).sub.m(OR.sup.4).sub.n}{Ph(R.sup.5).sub.o(OR.sup.6).sub.p}, wherein Ph represents a benzene ring, R.sup.1, R.sup.3 and R.sup.5 independently are C.sub.1-C.sub.18 alkyl or C.sub.4-C.sub.18 heteroalkyl; R.sup.2, R.sup.4 and R.sup.6 independently are C.sub.1-C.sub.18 alkyl or C.sub.4-C.sub.18 heteroalkyl, i, j, m, n, o and p independently are zero, one or two. Each compound having formula C{Ph(R.sup.1).sub.i(OR.sup.2).sub.j}.sub.2{Ph(R.sup.3).sub.m(OR.sup.4).sub.n}{Ph(R.sup.5).sub.o(OR.sup.6).sub.p} is present at a level from 0.01 ppm to 20 ppm.

The present disclosure provides compositions, methods, and systems for identifying marked hydrocarbon fluids. These compositions, methods, and systems utilize a gas chromatography marker including a pyrrolidinone. The methods and systems can identify the presence or absence of the gas chromatography marker and/or the pyrrolidinone. The compositions, methods, and systems can optionally utilize a spectroscopic marker.