A valve spring which has an excellent fatigue limit is provided. A chemical composition of the valve spring according to the present embodiment contains, in mass %, C: 0.50 to 0.80%, Si: 1.20 to less than 2.50%, Mn: 0.25 to 1.00%, P: 0.020% or less. S: 0.020% or less: Cr: 0.40 to 1.90%, V: 0.05 to 0.60%, Ca: 0.0001 to 0.0050%, and N: 0.0100% or less, with the balance being Fe and impurities. In the valve spring, a number density of V-based precipitates having a maximum diameter ranging from 2 to 10 nm is 5000 to 80000 pieces/μm.sup.3, and a numerical proportion of Ca sulfides with respect to a total number of oxide-based inclusions and sulfide-based inclusions is 0.20% or less.

The present disclosure provides a method of making low carbon steel. The method includes tapping the liquid steel out of a primary steelmaking furnace. Deoxidizing the liquid steel. Transferring the deoxidized liquid steel to a ladle metallurgy furnace. Removing sulfur at the ladle metallurgy furnace. Adding fluxes and arcing the liquid steel to prevent sulfur reversion. Transferring the liquid steel from the ladle metallurgy furnace to an RH degasser for carbon removal. The removal of oxygen and sulfur prior to transferring the liquid steel to the RH degasser facilitates nitrogen removal and prevents carbon pick up during the step sulfur removal.

The present disclosure provides a method of making low carbon steel. The method includes tapping the liquid steel out of a primary steelmaking furnace. Deoxidizing the liquid steel. Transferring the deoxidized liquid steel to a ladle metallurgy furnace. Removing sulfur at the ladle metallurgy furnace. Adding fluxes and arcing the liquid steel to prevent sulfur reversion. Transferring the liquid steel from the ladle metallurgy furnace to an RH degasser for carbon removal. The removal of oxygen and sulfur prior to transferring the liquid steel to the RH degasser facilitates nitrogen removal and prevents carbon pick up during the step sulfur removal.

The present invention discloses a wire rod for an ultrahigh-strength steel cord and a manufacturing method thereof. The manufacturing method includes: smelting molten steel where inclusions in sizes ≥5 μm are at a number density ≤0.5/mm.sup.2 and sizes of inclusions are ≤30 μm; casting the molten steel into an ingot blank with a center carbon segregation value of 0.92-1.08; cogging the ingot blank into an intermediate blank with a center carbon segregation value of 0.95-1.05; rolling the intermediate blank into a wire rod; and performing temperature control cooling on the wire rod to obtain a wire rod with high purity, high homogeneity and tensile strength ≤1,150 MPa. The wire rod may be used for an ultrahigh-strength steel cord with single tensile strength ≥3,600 MPa.

A steel wire which has excellent cold coiling workability, and which has an excellent fatigue limit when made into a spring is provided. A chemical composition of the steel wire according to the present, embodiment containing, in mass %, C: 0.50 to 0.80%, Si: 1.20 to less than 2.50%, Mn: 0.25 to 1.00%, P: 0.020% or less, S: 0.020% or less, Cr: 0.40 to 1.90%, V: 0.05 to 0.60%, and N: 0.0100% or less, with the balance being Fe and impurities. In the steel wire, a number density of V-based precipitates having a maximum diameter ranging from 2 to 10 nm is 5000 to 80000 pieces/μm.sup.3.

A steel consists of, in mass %, C: 0.25 to 0.45%, Si: 0.10 to 0.50%, Mn: 0.40 to 0.70%, P: 0.015% or less, S: 0.005% or less, Cr: 0.80 to 1.50%, Mo: 0.17 to 0.30%, V: 0.24 to 0.40%, Al: 0.005 to 0.100%, N: 0.0300% or less, O: 0.0015% or less, and the balance being Fe and impurities, and satisfies Formula (1) to Formula (4) described in the present specification, wherein: its microstructure is composed of ferrite and pearlite having a total area fraction of 5.0 to 100.0%, and a hard phase having a total area fraction of 0 to 95.0%; a proportion of a total area of CaO—CaS—MgO—Al.sub.2O.sub.3 composite oxides with respect to a total area of oxides in the steel is 30.0% or more; and a number density of oxides having an equivalent circle diameter of 20.0 μm or more is 15.0 pieces/mm.sup.2 or less.

A method of making steel by deeply dephosphorization in a hot metal tank and decarburization using semi-steel with nearly zero phosphorus load in a converter includes the following steps: putting an efficient dephosphorization agent into the hot metal tank in advance, and conducting dephosphorization during blast furnace tapping and transportation of blast furnace hot metal by the hot metal tank to obtain semi-steel with [P] less than 0.04 wt. % and [C] greater than or equal to 3.5 wt. %; and removing dephosphorization slag, and pouring the semi-steel into the converter for decarburization to obtain molten steel. The efficient dephosphorization agent includes iron oxide scale, lime, and composite calcium ferrite. According to the method, a phosphorus content of the blast furnace hot metal is reduced to be less than or equal to 0.04 wt. % through the efficient dephosphorization agent.

Technologies are disclosed herein for cross-correlating metrics for anomaly root cause detection. Primary and secondary metrics associated with an anomaly are cross-correlated by first using the derivative of an interpolant of data points of the primary metric to identify a time window for analysis. Impact scores for the secondary metrics can be then be generated by computing the standard deviation of a derivative of data points of the secondary metrics during the identified time window. The impact scores can be utilized to collect data relating to the secondary metrics most likely to have caused the anomaly. Remedial action can then be taken based upon the collected data in order to address the root cause of the anomaly.

There is provided a carburized bearing that is excellent in rolling contact fatigue life with a change in structure under a hydrogen-generating environment. In the carburized bearing, a chemical composition of a core portion consists of, in mass %, C: 0.25 to 0.45%, Si: 0.10 to 0.50 %, Mn: 0.40 to 0.70 %, P: 0.015% or less, S: 0.005% or less, Cr: 0.80 to 1.50%, Mo: 0.17 to 0.30%, V: 0.24 to 0.40%. Al: 0.005 to 0.100%, N: 0.0300% or less, O: 0.0015% or less, and the balance being Fe and impurities, and satisfies Formula (1) to Formula (4) described in the present specification. A proportion of a total area of CaO—CaS—MgO—Al.sub.2O.sub.3 composite oxides with respect to a total area of oxides in the carburized leaping is 30.0% or more, and a number density of oxides having an equivalent circle diameter of 20.0 μm or more is 15.0 pieces/mm.sup.2or less.

A dual-phase stainless steel or dual-phase stainless steel seamless pipe has a certain composition, the dual-phase stainless steel or dual-phase stainless steel seamless pipe having a microstructure containing 20 to 70% austenitic phase and 30 to 80% ferritic phase by volume, the dual-phase stainless steel or dual-phase stainless steel seamless pipe having a yield strength, YS, of 448 MPa or more, and containing oxide inclusions of which oxide inclusions having an average particle diameter of 1 μm or more have a number density of 15/mm.sup.2 or less, and at most 50 mass % of the oxide inclusions having an average particle diameter of 1 μm or more are oxide inclusions containing aluminum.