Patent classifications
C22B7/004
Method of recovering materials bound to a metallic substrate using cryogenic cooling
A recycling process that facilitates separation of materials from metallic substrates by cryogenically cooling the recyclable items to induce embrittlement of the metals. Embrittled metals may be shattered more efficiently and with a higher yield of materials bound to the metallic substrates. Metal embrittlement may be induced by mixing the source stream with liquid nitrogen, and cooling the stream to approximately minus 200° F. Multiple recovery stages may be employed to maximize the yield of the target materials. Embodiments may enable recovery of platinum group metals (PGMs) from catalytic converters with metallic foil substrates. Yield of PGMs may be enhanced by employing a primary recovery stage and a secondary recovery stage, by cryogenically cooling input materials for each stage, by mixing the pulverized material in secondary recovery with an aqueous solution to dissipate attractive charges, and by wet screening the pulverized material slurry to obtain the PGM particles.
Method for obtaining non-ferrous metals, in particular black and/or raw copper, from scrap containing organic matter
A method for obtaining non-ferrous metals, in particular black and/or raw copper, from scrap containing organic matter, comprises the following steps: i) providing a melting reactor, wherein the melting reactor includes a melting region, a combustion region and a pyrolysis region; ii) supplying the melting reactor with a mixture comprising the scrap such that it first passes through the pyrolysis region and the combustion region before it reaches the melting region, and is at least partially pre-pyrolyzed and/or combusted, such that an energy-containing gas stream is formed; iii) transferring the energy-containing gas stream into a thermal post-combustion chamber, in which the energy-containing gas stream is completely combusted and thermal energy released during combustion is carried off via an energy recovery unit; and iv) melting the scrap containing organic matter at least part of which has been pre-pyrolized and/or combusted.
METHOD FOR PRODUCING A PGM COLLECTOR ALLOY
A method for producing a PGM collector alloy comprising the steps of:
(1) providing (a) copper and/or silver, (b) material, which is to be processed melt-metallurgically, in the form of at least one sodium and/or potassium aluminosilicate support equipped with at least one PGM, and (c) at least one compound selected from the group consisting of iron oxides, calcium oxide, magnesium oxide, calcium carbonate, magnesium carbonate, sodium carbonate, and potassium carbonate,
(2) joint melting of the materials provided in step (1) at a temperature in the range of 1250 to <1450° C. by maintaining a 100:40 to 100:20 weight ratio of the materials provided in sub-steps (1b) and (1c), and a 35:65 to 80:20 weight ratio of copper and/or silver: PGM by forming a melt comprising two phases of different density,
(3) separating the upper phase of low density of molten slag from the lower phase of high density of molten PGM collector alloy by utilizing the density difference,
(4) allowing the melting phases separated from one another to cool down and solidify, and
(5) collecting the solidified PGM collector alloy.
METHOD FOR RECOVERING VALUABLE METAL
Provided is a method which allows for strict control of an oxygen partial pressure required for the heating and melting of a raw material, and thereby more efficient recovery of a valuable metal. The method for recovering a valuable metal (Cu, Ni, and Co) includes the steps of: preparing a charge comprising at least phosphorus (P) and a valuable metal as a raw material; heating and melting the raw material to form a molten body and then converting the molten body into a molten product comprising an alloy and a slag; and separating the slag from the molten product to recover the alloy comprising the valuable metal, wherein the heating and melting of the raw material comprises directly measuring an oxygen partial pressure in the molten body using an oxygen analyzer, and regulating the oxygen partial pressure based on the obtained measurement result.
Recovery of nickel and cobalt from Li-ion batteries or their waste
The present invention lies in the field of pyrometallurgy and discloses a process and a slag suitable for the recovery of Ni and Co from Li-ion batteries or their waste. The slag composition is defined according to:
##STR00001##
##STR00002##
##STR00003##
##STR00004##
##STR00005##
##STR00006##
This composition is particularly adapted to limit or avoid the corrosion of furnaces lined with magnesia-bearing refractory bricks.
Recovery of nickel and cobalt from Black Mass
The present invention lies in the field of pyrometallurgy and discloses a process and a slag suitable for the recovery of Ni and Co from Li-ion batteries or their waste, particularly from Black Mass. The slag composition is defined according to: 25% < MnO < 70%; Al.sub.2O.sub.3 + 0.5 MnO < 45% SiO.sub.2 > 5%; Li.sub.2O > 1%; MnO + Li.sub.2O + Al.sub.2O.sub.3 + CaO + SiO.sub.2 + FeO + MgO + P.sub.2O.sub.5 > 90%; and, wherein (CaO + 2 Li.sub.2O + 0.4 MnO) / SiO.sub.2 ≥ 2.0. This composition is particularly adapted to limit or avoid the wear or corrosion of furnaces lined with magnesia-bearing refractory bricks.
METHOD OF RECOVERING MATERIALS BOUND TO A METALLIC SUBSTRATE USING CRYOGENIC COOLING
A recycling process that facilitates separation of materials from metallic substrates by cryogenically cooling the recyclable items to induce embrittlement of the metals. Embrittled metals may be shattered more efficiently and with a higher yield of materials bound to the metallic substrates. Metal embrittlement may be induced by mixing the source stream with liquid nitrogen, and cooling the stream to approximately minus 200° F. Multiple recovery stages may be employed to maximize the yield of the target materials. Embodiments may enable recovery of platinum group metals (PGMs) from catalytic converters with metallic foil substrates. Yield of PGMs may be enhanced by employing a primary recovery stage and a secondary recovery stage, by cryogenically cooling input materials for each stage, by mixing the pulverized material in secondary recovery with an aqueous solution to dissipate attractive charges, and by wet screening the pulverized material slurry to obtain the PGM particles.
A METHOD, APPARATUS AND SYSTEM FOR PROCESSING A COMPOSITE WASTE SOURCE
A method, apparatus and system for processing a composite waste source, such as e-waste, is disclosed. The composite waste source may comprise low-, moderate and high-melting point constituents, such as plastics, metals and ceramics. The composite waste source is heated to a first temperature zone, causing at least some of the low-melting point constituents to at least partially thermally transform. The composite waste source is subsequently heated to a second, higher, temperature zone, causing at least some of the moderate-melting point constituents to at least partially thermally transform. At least some of the at least partially thermally transformed constituents may be recovered. The method, apparatus and system disclosed may provide for the recovery and reuse of materials which would otherwise be sent to landfill or incinerated.
DROSS HANDLING METHODS AND APPARATUS
A compressing element, devices for using such a compressing element and methods of use are provided, in which the compressing element has: a upper surface provided with an inlet and an outlet; a lower surface; an at least partially hollow interior provided between the upper surface and the lower surface, the hollow interior being connected to the inlet and the outlet; the hollow interior being provided with: one or more fluid flow constraining surfaces provided by one or more walls of the follow interior; and one or more fluid flow control elements provided in the hollow interior, the one or more fluid flow control elements being additional to the one or more fluid flow constraining surfaces provided by the one or more walls of the hollow interior. The arrangement of inlet, outlet, fluid flow constraining surfaces and fluid control elements provides for improved cooling of the compressing element, for instance when used to press molten metal processing by-products to extract molten metal.
LITHIUM-RICH COMPOSITIONS
The present disclosure relates to the production of lithium-enriched compositions from lithium-ion batteries, and the processing of those compositions for the economic recovery of lithium compounds useful for commercial and industrial applications.