The invention relates to biodegradable iron alloy-containing compositions for use in preparing medical devices. In addition, biodegradable crystalline and amorphous compositions of the invention exhibit properties that make them suitable for use as medical devices for implantation into a body of a patient. The compositions include elemental iron and one or more elements selected from manganese, magnesium, zirconium, zinc and calcium. The compositions can be prepared using a high energy milling technique. The resulting compositions and the devices formed therefrom are useful in various surgical procedures, such as but not limited to orthopedic, craniofacial and cardiovascular.

Provided is an Fe-based nanocrystalline alloy powder. The Fe-based nanocrystalline alloy powder has a chemical composition, excluding inevitable impurities, represented by a composition formula of Fe.sub.aSi.sub.bB.sub.cP.sub.dCu.sub.eM.sub.f, where the M in the composition formula is at least one element selected from the group consisting of Nb, Mo, Zr, Ta, W, Hf, Ti, V, Cr, Mn, C, Al, S, O, and N, 79 at %≤a≤84.5 at %, 0 at %≤b<6 at %, 0 at %<c≤10 at %, 4 at %<d≤11 at %, 0.2 at %≤e≤0.53 at %, 0 at %≤f≤4 at %, a+b+c+d+e+f=100 at %, a degree of crystallinity is more than 10% by volume, and an Fe crystallite diameter of the Fe-based nanocrystalline alloy powder is 50 nm or less.

Provided is an Fe-based nanocrystalline alloy powder. The Fe-based nanocrystalline alloy powder has a chemical composition, excluding inevitable impurities, represented by a composition formula of Fe.sub.aSi.sub.bB.sub.cP.sub.dCu.sub.eM.sub.f, where the M in the composition formula is at least one element selected from the group consisting of Nb, Mo, Zr, Ta, W, Hf, Ti, V, Cr, Mn, C, Al, S, O, and N, 79 at %≤a≤84.5 at %, 0 at %≤b<6 at %, 0 at %<c≤10 at %, 4 at %<d≤11 at %, 0.2 at %≤e≤0.53 at %, 0 at %≤f≤4 at %, a+b+c+d+e+f=100 at %, a degree of crystallinity is more than 10% by volume, and an Fe crystallite diameter of the Fe-based nanocrystalline alloy powder is 50 nm or less.

The specification relates to the technical field of magnetic materials, in particular to an Fe-based amorphous nanocrystalline alloy and a preparation method thereof. The Fe-based amorphous nanocrystalline alloy comprises elements, the atomic percentages of which are as shown by the formula Fe.sub.(100-a-b-c-d-e-f)B.sub.aSi.sub.bP.sub.cC.sub.dCu.sub.eNb.sub.f, wherein 8≤a≤12, 0.2≤b≤6, 2.0≤c≤6.0, 0.5≤d≤4, 0.6≤e≤1.3, 0.6≤f≤0.9, and 1≤e/f≤1.4. The Fe-based amorphous nanocrystalline alloy has good magnetic properties, excellent thermal properties and a wide crystallization temperature zone, thus being suitable for industrial production.

The specification relates to the technical field of magnetic materials, in particular to an Fe-based amorphous nanocrystalline alloy and a preparation method thereof. The Fe-based amorphous nanocrystalline alloy comprises elements, the atomic percentages of which are as shown by the formula Fe.sub.(100-a-b-c-d-e-f)B.sub.aSi.sub.bP.sub.cC.sub.dCu.sub.eNb.sub.f, wherein 8≤a≤12, 0.2≤b≤6, 2.0≤c≤6.0, 0.5≤d≤4, 0.6≤e≤1.3, 0.6≤f≤0.9, and 1≤e/f≤1.4. The Fe-based amorphous nanocrystalline alloy has good magnetic properties, excellent thermal properties and a wide crystallization temperature zone, thus being suitable for industrial production.

The present invention provides a method for manufacturing a conductive film, comprising the steps of: applying, to a substrate, a conductive paste dispersed in an organic material and comprising metal particles and Fe—B—Cu—C alloy magnetic heating element particles; and selectively sintering the applied conductive paste by means of induction heating so as to form a conductive film, wherein the magnetic heating element particles are implemented with crystallized Fe—B—Cu—C alloy particles. Therefore, it is possible to selectively form a conductive adhesive layer by sintering through induction heating. In addition, it is possible to produce an adhesive capable of low-temperature bonding by forming a magnetic heating element having crystal grains with a large coercive force through heat treatment after formation of an alloy.

An alloy particle contains: total content of Fe and Co: from 82.2 to 96.5 parts by mass; Co: 0 to 30.0 parts by mass; P: 0 to 4.5 parts by mass; B: more than 0 to 5.0 parts by mass; C: 0 to 3.0 parts by mass; Si: 0 to 6.7 parts by mass; Ni: more than 0 to 12.0 parts by mass; Cr: more than 0 to 4.2 parts by mass; total content of Mo, W, Zr, and Nb: 0 to 4.2 parts by mass; total content of P and Cr: 7.4 parts by mass or less; multiplication product of the parts by mass of Ni and Cr: 0.5 or more; and total content of Fe, Co, and Ni: 97.0 parts by mass or less. The alloy particle contains an amorphous phase, and a volume percentage of the amorphous phase is 70% or higher.

An alloy particle contains: total content of Fe and Co: from 82.2 to 96.5 parts by mass; Co: 0 to 30.0 parts by mass; P: 0 to 4.5 parts by mass; B: more than 0 to 5.0 parts by mass; C: 0 to 3.0 parts by mass; Si: 0 to 6.7 parts by mass; Ni: more than 0 to 12.0 parts by mass; Cr: more than 0 to 4.2 parts by mass; total content of Mo, W, Zr, and Nb: 0 to 4.2 parts by mass; total content of P and Cr: 7.4 parts by mass or less; multiplication product of the parts by mass of Ni and Cr: 0.5 or more; and total content of Fe, Co, and Ni: 97.0 parts by mass or less. The alloy particle contains an amorphous phase, and a volume percentage of the amorphous phase is 70% or higher.

A soft magnetic powder of the invention has a composition represented by Fe.sub.100-a-b-c-d-e-fCu.sub.aSi.sub.bB.sub.cM.sub.dM′.sub.eX.sub.f (at %) [wherein M is Nb, W, Ta, Zr, Hf, Ti, or Mo, M′ is V, Cr, Mn, Al, a platinum group element, Sc, Y, Au, Zn, Sn, or Re, X is C, P, Ge, Ga, Sb, In, Be, or As, and a, b, c, d, e, and f are numbers that satisfy the following formulae: 0.1≤a≤3, 0<b≤30, 0<c≤25, 5≤b+c≤30, 0.1≤d≤30, 0≤e≤10, and 0≤f≤10], wherein a crystalline structure having a particle diameter of 1 nm or more and 30 nm or less is contained in an amount of 40 vol % or more, and the difference in the coercive force of the powder after classification satisfies predetermined conditions.

A soft magnetic powder of the invention has a composition represented by Fe.sub.100-a-b-c-d-e-fCu.sub.aSi.sub.bB.sub.cM.sub.dM′.sub.eX.sub.f (at %) [wherein M is Nb, W, Ta, Zr, Hf, Ti, or Mo, M′ is V, Cr, Mn, Al, a platinum group element, Sc, Y, Au, Zn, Sn, or Re, X is C, P, Ge, Ga, Sb, In, Be, or As, and a, b, c, d, e, and f are numbers that satisfy the following formulae: 0.1≤a≤3, 0<b≤30, 0<c≤25, 5≤b+c≤30, 0.1≤d≤30, 0≤e≤10, and 0≤f≤10], wherein a crystalline structure having a particle diameter of 1 nm or more and 30 nm or less is contained in an amount of 40 vol % or more, and the difference in the coercive force of the powder after classification satisfies predetermined conditions.