Composition, characterized in that: —it comprises, in a solution of demineralized water: between 10 and 80, preferably between 15 and 20, more preferably 17, g/l of a composition of phosphoric acid H.sub.3PO.sub.4, and between 2 and 15, preferably between 4 and 8, more preferably 6, g/l of a composition of potassium permanganate KMnO.sub.4, —the weight ratio H.sub.3PO.sub.4/KMnO.sub.4 is between 1.5 and 10, preferably between 1.8 and 5, mote preferably equal to 2.8, —said composition has a pH between 2.4 and 3, preferably 2.5.

Composition, characterized in that: —it comprises, in a solution of demineralized water: between 10 and 80, preferably between 15 and 20, more preferably 17, g/l of a composition of phosphoric acid H.sub.3PO.sub.4, and between 2 and 15, preferably between 4 and 8, more preferably 6, g/l of a composition of potassium permanganate KMnO.sub.4, —the weight ratio H.sub.3PO.sub.4/KMnO.sub.4 is between 1.5 and 10, preferably between 1.8 and 5, mote preferably equal to 2.8, —said composition has a pH between 2.4 and 3, preferably 2.5.

Disclosed is a phosphate coating, comprising: a phosphate portion, wherein the phosphate portion comprises pores, wherein the pores are at least partially filled with a corrosion inhibition sealant, wherein the corrosion inhibition sealant comprises: a base, wherein the base comprises a matrix and a metal within the matrix, wherein the metal within the matrix comprises aluminum, an aluminum alloy, zinc, a zinc alloy, magnesium, a magnesium alloy, or a combination thereof and an inhibitor mixed within the base, wherein the inhibitor comprises zinc molybdate, magnesium metasilicate, trivalent chromium, tungstenate, a metal phosphate silicate, or a combination thereof.

The disclosure relates to thin layers comprising a catechol containing polymer or oligomer, as well as methods of making and using the thin layers comprising the catechol containing polymer or oligomer. The layers demonstrate improved adhesion between two materials without substantial modification of the adhesive matrix.

Provided are coated metal, the metal having improved properties due to a novel coating, a coating-forming treatment solution for forming the novel coating, and a method for producing the coated metal that has the novel coating. The coated metal includes metal and a coating formed on the metal. The coating includes Si, P, and O, and at least one selected from the group consisting of Mg, Ca, Ba, Sr, Zn, Al, and Mn. The coating includes a compound having a NASICON-type crystal structure represented by the general formula M.sup.IM.sup.IV.sub.2(M.sup.VO.sub.4).sub.3.

A method of improving corrosion and mar resistance of steel components by creating a black magnetite finish, with a medium temperature process, prior to application of a phosphate layer coating.

Disclosed herein is an aqueous composition having a pH value at 55° C. in the range from 5 to 9, containing at least one different amino organophosphonic acid derivatives of formula (I)

##STR00001##

where residues R independently of each other are CH.sub.2—PO(OR″).sub.2, residues R′ independently of each other are alkylene residues with 2 to 4 carbon atoms, residues R″ independently of each other are H, Na, K, Li or NH.sub.4; and n is an integer from 0 to 4; and at least one copolymer, which is water-soluble or water-dispersible Further disclosed herein are a concentrate to produce such compositions, a pickling method for pickling metallic substrates making use of the compositions, a coating method for coating metallic substrates including the pickling method and a method of using the compositions for pickling metallic substrates.

A method for treating and phosphatizing a metal board without using acid includes the following steps: performing a degreasing step to remove grease and dirt from a surface of the metal board with a degreasing agent; performing a blast-peening step by blasting and peening polygon blast-peening granules on the metal board through a centrifugal impeller to remove an oxidized layer; performing a washing step to clean remaining powders from the metal board after the blast-peening step; performing a phosphatizing step to form a protective phosphate coating on the metal board; performing another washing step to wash off remaining phosphatizing agents from the metal board; performing a rustproofing step to apply a rustproofing agent on the metal board; and performing a drying step to dry the metal board.

A method for treating and phosphatizing a metal board without using acid includes the following steps: performing a degreasing step to remove grease and dirt from a surface of the metal board with a degreasing agent; performing a blast-peening step by blasting and peening polygon blast-peening granules on the metal board through a centrifugal impeller to remove an oxidized layer; performing a washing step to clean remaining powders from the metal board after the blast-peening step; performing a phosphatizing step to form a protective phosphate coating on the metal board; performing another washing step to wash off remaining phosphatizing agents from the metal board; performing a rustproofing step to apply a rustproofing agent on the metal board; and performing a drying step to dry the metal board.

A method for post-treatment of a chromium finish surface to improve corrosion resistance comprising a) providing a substrate having a chromium finish surface, and at least one intermediate layer between the chromium finish surface and the substrate, selected from the group consisting of nickel, nickel alloys, copper and copper alloys, wherein the chromium finish surface is a surface of a trivalent chromium plated layer, obtained by electroplating the substrate, having the at least one intermediate layer, in a plating bath, the plating bath comprising chromium (III) ions; b) contacting the chromium finish surface with an aqueous solution, comprising a permanganate, at least one compound which is selected from a phosphorus-oxygen compound, a hydroxide, a nitrate, a borate, boric acid, a silicate, or a mixture of two or more of these compounds; c) forming a transparent corrosion protection layer onto the chromium finish surface during step b.