A carbon compound manufacturing system includes: a recovery unit; a conversion unit; a synthesis unit; a first flow path to supply the supply gas to the recovery unit; a second flow path connecting the recovery and the conversion units; a third flow path connecting the conversion and the synthesis units; at least one of first to third detectors to respectively measure a flow rate of the supply gas flowing through the first flow path to generate a first data signal, a flow rate of the carbon dioxide flowing through the second flow path to generate a second data signal, and a value of voltage or current to the conversion unit to generate a third data signal; and an integration controller to collate at least one data of the first to third data signals with a corresponding plan data to generate at least one of first to third control signals.

A carbon compound manufacturing system includes: a recovery unit; a conversion unit; a synthesis unit; a first flow path to supply the supply gas to the recovery unit; a second flow path connecting the recovery and the conversion units; a third flow path connecting the conversion and the synthesis units; at least one of first to third detectors to respectively measure a flow rate of the supply gas flowing through the first flow path to generate a first data signal, a flow rate of the carbon dioxide flowing through the second flow path to generate a second data signal, and a value of voltage or current to the conversion unit to generate a third data signal; and an integration controller to collate at least one data of the first to third data signals with a corresponding plan data to generate at least one of first to third control signals.

Herein discussed is an electrochemical reactor comprising a mixed-conducting membrane, wherein the membrane comprises an electronically conducting phase and an ionically conducting phase, wherein the reactor is capable of reforming a hydrocarbon electrochemically, wherein the electrochemical reforming reactions involve the exchange of an ion through the membrane to oxidize the hydrocarbon. Further discussed herein is a method of producing hydrogen comprising providing an electrochemical (EC) reactor having a mixed-conducting membrane, introducing a first stream comprising a hydrocarbon to the reactor, introducing a second stream comprising water to the reactor, and reducing the water in the second stream to produce hydrogen, wherein the first stream and the second stream do not come in contact with each other in the reactor, and wherein the hydrocarbon is reformed electrochemically in the EC reactor.

Herein discussed is a hydrogen production system comprising a first reactor zone and a second reactor zone, wherein both reactor zones comprise an ionically conducting membrane, wherein the first zone is capable of reforming a hydrocarbon electrochemically and the second zone is capable of performing water gas shift reactions electrochemically, wherein the electrochemical reforming reactions involve the exchange of an ion through the membrane to oxidize the hydrocarbon and wherein electrochemical water gas shift reactions involve the exchange of an ion through the membrane and include forward water gas shift reactions, or reverse water gas shift reactions, or both. In an embodiment, the membrane is mixed conducting. In an embodiment, the membrane comprises an electronically conducting phase and an ionically conducting phase.

The electrochemical carbon dioxide reduction reaction (CO.sub.2RR) provides opportunities to synthesize value-added products from this greenhouse gas in a sustainable manner. Efficient catalysts for this reaction are provided that selectively drive CO.sub.2 reduction over the thermodynamic and kinetically competitive hydrogen evolution reaction (HER) in organic or aqueous electrolytes. The catalysts are metal-polypyridyl coordination complexes of a redox non-innocent terpyridine-based pentapyridine ligand and a first-row transition metal. The metal-ligand cooperativity in [Fe(tpyPY2Me)].sup.2+ drives the electrochemical reduction of CO.sub.2 to CO at low overpotentials with high selectivity for CO.sub.2RR (>90%).

The present application provides systems, apparatuses, and methods for simultaneous processing of tow waster gases, namely H.sub.2S and CO.sub.2. In an exemplary process of this disclosure H.sub.2S is supplied to anode side of an electrochemical cell, while CO.sub.2 is supplied to the cathode side. As a result, valuable commercial products are produced. In particular, SO.sub.2 is harvested from the anode side, while synthesis gas, CO+H.sub.2) is harvested from the cathode side. An electric current is also produced, which can be supplied to a local utility grid.

The present application provides systems, apparatuses, and methods for simultaneous processing of tow waster gases, namely H.sub.2S and CO.sub.2. In an exemplary process of this disclosure H.sub.2S is supplied to anode side of an electrochemical cell, while CO.sub.2 is supplied to the cathode side. As a result, valuable commercial products are produced. In particular, SO.sub.2 is harvested from the anode side, while synthesis gas, CO+H.sub.2) is harvested from the cathode side. An electric current is also produced, which can be supplied to a local utility grid.

Herein discussed is a method of producing hydrogen comprising introducing a first stream comprising a fuel to an electrochemical (EC) reactor having a mixed-conducting membrane, introducing a second stream comprising water to the reactor, reducing the water in the second stream to produce hydrogen, and recycling at least portion of the produced hydrogen to the first stream, wherein the membrane comprises an electronically conducting phase and an ionically conducting phase; and wherein the first stream and the second stream do not come in contact with each other in the reactor.

Aspects of the present disclosure generally relate to catalyst compositions, processes for producing such catalyst compositions, and uses of such catalyst compositions. In an embodiment, a composition is provided. The composition includes an electrolyte material or an ion thereof, an amphiphile material or an ion thereof, and a metal component, the metal component comprising an alloy having the formula (M.sup.1).sub.a(M.sup.2).sub.b, wherein M.sup.1 is a Group 10-11 metal of the periodic table of the elements, M.sup.2 is a first Group 8-11 metal of the periodic table of the elements, M.sup.1 and M.sup.2 are different, and a and b are positive numbers. In another embodiment, a device is provided that includes an electrolyte material or ion thereof, an amphiphile material or ion thereof, and a metal component disposed on an electrode, the metal component comprising a bimetallic nanoframe, a trimetallic nanoframe, or a combination thereof.

Herein discussed is a method of producing hydrogen or carbon monoxide comprising introducing a waste gas having a total combustible species (TCS) content of no greater than 60 vol % into an electrochemical (EC) reactor, wherein the EC reactor comprises a mixed-conducting membrane, wherein the membrane comprises an electronically conducting phase and an ionically conducting phase. Also disclosed herein is an integrated hydrogen production system comprising a waste gas source and an electrochemical (EC) reactor comprising a mixed-conducting membrane, wherein the membrane comprises an electronically conducting phase and an ionically conducting phase, wherein the waste gas source is configured to send its exhaust to the EC reactor, wherein the exhaust has a total combustible species (TCS) content of no greater than 60 vol %.