A device and method for preparing high-purity titanium powder by continuous electrolysis are provided. The method includes: electrolyzing a titanium-containing conductive ceramic anode and a rotatable cathode in a fused salt electrolytic tank; continuously transferring titanium powder deposited on a surface of the cathode by the rotatable cathode to a position above the fused salt; scraping the titanium powder by a discharging scraper, and collecting; filtering the titanium powder, and recovering the fused salt; cooling separated titanium powder, washing with deoxygenated and deionized water, and vacuum-drying to obtain final titanium powder. The device includes a fused salt electrolysis mechanism, a continuous titanium powder collection mechanism, a filtering mechanism, a washing mechanism, and a vacuum-drying mechanism.

A device and method for preparing high-purity titanium powder by continuous electrolysis are provided. The method includes: electrolyzing a titanium-containing conductive ceramic anode and a rotatable cathode in a fused salt electrolytic tank; continuously transferring titanium powder deposited on a surface of the cathode by the rotatable cathode to a position above the fused salt; scraping the titanium powder by a discharging scraper, and collecting; filtering the titanium powder, and recovering the fused salt; cooling separated titanium powder, washing with deoxygenated and deionized water, and vacuum-drying to obtain final titanium powder. The device includes a fused salt electrolysis mechanism, a continuous titanium powder collection mechanism, a filtering mechanism, a washing mechanism, and a vacuum-drying mechanism.

A device and method for preparing high-purity titanium powder by continuous electrolysis are provided. The method includes: electrolyzing a titanium-containing conductive ceramic anode and a rotatable cathode in a fused salt electrolytic tank; continuously transferring titanium powder deposited on a surface of the cathode by the rotatable cathode to a position above the fused salt; scraping the titanium powder by a discharging scraper, and collecting; filtering the titanium powder, and recovering the fused salt; cooling separated titanium powder, washing with deoxygenated and deionized water, and vacuum-drying to obtain final titanium powder. The device includes a fused salt electrolysis mechanism, a continuous titanium powder collection mechanism, a filtering mechanism, a washing mechanism, and a vacuum-drying mechanism.

A device and method for preparing high-purity titanium powder by continuous electrolysis are provided. The method includes: electrolyzing a titanium-containing conductive ceramic anode and a rotatable cathode in a fused salt electrolytic tank; continuously transferring titanium powder deposited on a surface of the cathode by the rotatable cathode to a position above the fused salt; scraping the titanium powder by a discharging scraper, and collecting; filtering the titanium powder, and recovering the fused salt; cooling separated titanium powder, washing with deoxygenated and deionized water, and vacuum-drying to obtain final titanium powder. The device includes a fused salt electrolysis mechanism, a continuous titanium powder collection mechanism, a filtering mechanism, a washing mechanism, and a vacuum-drying mechanism.

The present invention relates to a method for producing metallic lithium, and specifically a method for preparing lithium metal according to an embodiment of the present invention, comprises: preparing lithium phosphate; preparinge a mixture by adding a chlorine compound to the lithium phosphate; heating the mixture; obtaining lithium chloride by reacting the lithium phosphate and the chloride compound in the mixture; producing molten lithium metal by electrolyzing the lithium chloride; and recovering the molten lithium metal is disclosed.

The present invention relates to a method for producing metallic lithium, and specifically a method for preparing lithium metal according to an embodiment of the present invention, comprises: preparing lithium phosphate; preparinge a mixture by adding a chlorine compound to the lithium phosphate; heating the mixture; obtaining lithium chloride by reacting the lithium phosphate and the chloride compound in the mixture; producing molten lithium metal by electrolyzing the lithium chloride; and recovering the molten lithium metal is disclosed.

A method for collecting a heavy rare earth element from a heavy rare earth element-containing molten salt electrolysis residue and recycling the heavy rare earth element, the method includes: a step of mixing coarse particles of the molten salt electrolysis residue with a fluorinating material followed by firing, to fluorinate the coarse particles of the molten salt electrolysis residue; a step of pulverizing the coarse particles of the fluorinated molten salt electrolysis residue to obtain a powder of the molten salt electrolysis residue; and a step of mixing the powder of the molten salt electrolysis residue with R, an R-M alloy, or an R-M-B alloy (wherein R is one or more types of rare earth elements selected from the group consisting of Y, La, Ce, Nd, Pr, Sm, Gd, Dy, Tb, and Ho, M is a transition metal such as Fe or Co, and B is boron), heating and melting the mixture, separating a molten alloy from slag, and selectively extracting the heavy rare earth element into the molten alloy. Provided are a method for recycling a heavy rare earth element that is capable of efficiently recycling a heavy rare earth element that is rare in an alloy form similar to a product, and a method for recycling a rare earth magnet by using an alloy obtained by the recycling method.

Disclosed is an electrochemical method for high-temperature molten salt electrolysis in humid atmosphere. The method involves preparing hydrogen gas, metals/alloys, metal oxide compounds and metal hydrides in humid high-temperature molten salt environment. Hydrogen gas is generated by electrolyzing water in a molten salt electrolyte at above 100 C., and with a working cathode being a solid-state oxide pellet and a voltage applied to the electrolyzing cell being far lower than that in a direct electro-deoxidation process, the hydrogen gas generated reduces solid-state oxide cathodes to produce metals. The hydrogen ions in the molten salt can be prepared by hydrolysis reaction of the molten salt in a water vapor containing atmosphere. Corresponding metals or alloys or metal oxide compounds can be prepared by reducing iron oxide, molybdenum oxide, tantalum oxide, nickel oxide, copper oxide, titanium oxide or corresponding compound oxides and the like.

Disclosed is an electrochemical method for high-temperature molten salt electrolysis in humid atmosphere. The method involves preparing hydrogen gas, metals/alloys, metal oxide compounds and metal hydrides in humid high-temperature molten salt environment. Hydrogen gas is generated by electrolyzing water in a molten salt electrolyte at above 100 C., and with a working cathode being a solid-state oxide pellet and a voltage applied to the electrolyzing cell being far lower than that in a direct electro-deoxidation process, the hydrogen gas generated reduces solid-state oxide cathodes to produce metals. The hydrogen ions in the molten salt can be prepared by hydrolysis reaction of the molten salt in a water vapor containing atmosphere. Corresponding metals or alloys or metal oxide compounds can be prepared by reducing iron oxide, molybdenum oxide, tantalum oxide, nickel oxide, copper oxide, titanium oxide or corresponding compound oxides and the like.

Methods and systems for removing impurities from a molten salt stream are provided. A molten salt stream is provided that comprises a mixture of compounds selected from the group consisting of LiF, BeF.sub.2, and NaF, and ZrF.sub.4. The molten salt stream is flowed through a loop that may contain a precipitation filter, electrochemical potential, and/or a sparger, which thereby remove impurities in the molten salt stream. Various physical methods and apparatus are used to control the ability to remove impurities from the molten salt stream based on temperature, solubility, and general chemistry control.