A synergistic flame retardant composition comprising a phenolic compound comprising condensed tannin, hydrolysable tannin, lignin, cardanol, quercetin, catechin, epicatechin, anthocyanidin, catechol, dopamine, hydroxytyrosol, adrenaline, 4-hydroxyphenylacetic acid, gallic acid, digallic acid, methyl gallate, ellagic acid, phloroglucinol, hexahydroxydiphenic acid, luteic acid, casuarictin, or a combination thereof; and a phosphorus-containing compound comprising a C.sub.5-7 carbocyclic polyol substituted with at least one phosphate group.

A synergistic flame retardant composition comprising a phenolic compound comprising condensed tannin, hydrolysable tannin, lignin, cardanol, quercetin, catechin, epicatechin, anthocyanidin, catechol, dopamine, hydroxytyrosol, adrenaline, 4-hydroxyphenylacetic acid, gallic acid, digallic acid, methyl gallate, ellagic acid, phloroglucinol, hexahydroxydiphenic acid, luteic acid, casuarictin, or a combination thereof; and a phosphorus-containing compound comprising a C.sub.5-7 carbocyclic polyol substituted with at least one phosphate group.

A flame-retardant fabric may include a cellulosic fiber and a modacrylic fiber, the cellulosic fiber being a natural cellulose fiber containing a phosphorus compound, the modacrylic fiber containing an antimony compound, the flame-retardant fabric including the modacrylic fiber containing the antimony compound in an amount of 14 to 54 wt %, antimony in an amount of not less than 1.7 wt %, and phosphorus in an amount of 0.3 to 1.5 wt % with respect to the total weight of the flame-retardant fabric, and the flame-retardant fabric having a weight per unit area of not less than 160 g/m.sup.2. The flame-retardant fabric can be produced by subjecting a fabric including a natural cellulose fiber and a modacrylic fiber containing an antimony compound to flame-retardant treatment with a phosphorus compound.

A flame-retardant fabric may include a cellulosic fiber and a modacrylic fiber, the cellulosic fiber being a natural cellulose fiber containing a phosphorus compound, the modacrylic fiber containing an antimony compound, the flame-retardant fabric including the modacrylic fiber containing the antimony compound in an amount of 14 to 54 wt %, antimony in an amount of not less than 1.7 wt %, and phosphorus in an amount of 0.3 to 1.5 wt % with respect to the total weight of the flame-retardant fabric, and the flame-retardant fabric having a weight per unit area of not less than 160 g/m.sup.2. The flame-retardant fabric can be produced by subjecting a fabric including a natural cellulose fiber and a modacrylic fiber containing an antimony compound to flame-retardant treatment with a phosphorus compound.

Provided is a fabric that has excellent stain resistance and excellent flame retardancy and that is less likely to generate water spots and is less likely to cause pieces thereof to attach to each other, and a method of manufacturing the fabric. The fabric according to the present invention is a polyester fabric impregnated with a fluorinated water-and-oil repellent agent and includes a coating layer on one surface thereof, the coating layer containing a fluorinated water-and-oil repellent agent, an organic phosphorus flame retardant having a solubility in water at 20 C. of 4% or less, and an acrylic resin having a glass-transition temperature of 43 C. to 20 C.

The present invention provides a fiber sizing agent composition containing a polyester resin (A) and a reactive compound (B), wherein the polyester resin (A) is a polyester resin having an HLB of 4 to 18 and a viscosity at 30 C. of 10 to 1,000,000 Pa.Math.s, the reactive compound (B) is at least one reactive compound selected from the group consisting of blocked isocyanates, tertiary amines, tertiary amine salts, quaternary ammonium salts, quaternary phosphonium salts, and phosphine compounds, and the weight ratio of the polyester resin (A) to the reactive compound (B) [(A)/(B)] in the fiber sizing agent composition is 99.9/0.1 to 10/90.

The present invention provides a fiber sizing agent composition containing a polyester resin (A) and a reactive compound (B), wherein the polyester resin (A) is a polyester resin having an HLB of 4 to 18 and a viscosity at 30 C. of 10 to 1,000,000 Pa.Math.s, the reactive compound (B) is at least one reactive compound selected from the group consisting of blocked isocyanates, tertiary amines, tertiary amine salts, quaternary ammonium salts, quaternary phosphonium salts, and phosphine compounds, and the weight ratio of the polyester resin (A) to the reactive compound (B) [(A)/(B)] in the fiber sizing agent composition is 99.9/0.1 to 10/90.

This disclosure provides high-efficiency and low-energy-consumption synthetic methods of a series of phosphorus-nitrogen-based intumescent flame retardants and the use thereof in paint flame retarding. 1 part by weight of a phosphorization agent and 0.5-4.0 parts by weight of a nitrogen-containing foaming agent are uniformly mixed and stirred at room temperature, and an amount of water is further added to emit heat and initiate reaction. 0.5-3.0 parts by weight of a charring agent and 0.5-4.0 parts by weight of a hydroxy-containing polyfuctional crosslinking agent are then added, and reacted with stirring. An amine compound is finally added for neutralization until pH value is 5-8, and solid liquid separation is performed. The solid portion is dried to obtain a main body portion of a phosphorus-nitrogen-based intumescent flame retardant. The resultant filtrate is diluted with - volume of water, and a flame retardant product is obtained. This flame retardant product is mainly used in the flame retarding of paper and cotton fabrics. The main body and different proportions of other nitrogen-containing foaming agents and charring agents are uniformly mixed and pulverized into nano- and micro-scale, and a phosphorus-nitrogen-based intumescent flame retardant is obtained. The nano- and micro-scale phosphorus-nitrogen intumescent flame retardant is mixed into a paint at a weight ratio of 15-30%, to obtain a flame-retardant paint which is capable of maintaining mechanical and physical properties of the paint. The phosphorus-nitrogen-based intumescent flame retardant of this disclosure is an intumescent flame retardant having a synergistic effect of phosphorus and nitrogen.

This disclosure provides high-efficiency and low-energy-consumption synthetic methods of a series of phosphorus-nitrogen-based intumescent flame retardants and the use thereof in paint flame retarding. 1 part by weight of a phosphorization agent and 0.5-4.0 parts by weight of a nitrogen-containing foaming agent are uniformly mixed and stirred at room temperature, and an amount of water is further added to emit heat and initiate reaction. 0.5-3.0 parts by weight of a charring agent and 0.5-4.0 parts by weight of a hydroxy-containing polyfuctional crosslinking agent are then added, and reacted with stirring. An amine compound is finally added for neutralization until pH value is 5-8, and solid liquid separation is performed. The solid portion is dried to obtain a main body portion of a phosphorus-nitrogen-based intumescent flame retardant. The resultant filtrate is diluted with - volume of water, and a flame retardant product is obtained. This flame retardant product is mainly used in the flame retarding of paper and cotton fabrics. The main body and different proportions of other nitrogen-containing foaming agents and charring agents are uniformly mixed and pulverized into nano- and micro-scale, and a phosphorus-nitrogen-based intumescent flame retardant is obtained. The nano- and micro-scale phosphorus-nitrogen intumescent flame retardant is mixed into a paint at a weight ratio of 15-30%, to obtain a flame-retardant paint which is capable of maintaining mechanical and physical properties of the paint. The phosphorus-nitrogen-based intumescent flame retardant of this disclosure is an intumescent flame retardant having a synergistic effect of phosphorus and nitrogen.

Disclosed is a grain-finished artificial leather including: an artificial leather base material; and a resin layer stacked on at least one surface of the artificial leather base material, wherein the artificial leather base material contains: a fiber-entangled body of ultrafine fibers; 3 to 50 mass % of a first elastic polymer; 2.5 to 6 mass %, in terms of phosphorus atoms, of first phosphorous-based flame retardant particles having an average particle size of 1 to 10 m; and 1 to 6 mass % of a plasticizer, and the resin layer contains: a second elastic polymer; and a total content, in terms of phosphorus atoms or in terms of hydroxyl groups, of 0 to 8 mass % of flame retardant particles having an average particle size of 1 to 10 m and being at least one selected from the group consisting of second phosphorous-based flame retardant particles and first metal hydroxide particles.