Systems, apparatuses, and methods are described that combine a sorbent containing a flame retardant with a substrate, which is capable of responding to temperature increases to prevent, suppress, delay the spread of, or otherwise mitigate a proximal thermal event. A flame retardant system has a flame retardant material that is incorporated into a matrical sorbent material, which is incorporated into a substrate. The matrical sorbent material is configured to release the flame retardant material upon exposure to an elevated temperature, e.g., a temperature that is greater than 300° C. in one embodiment.

Systems, apparatuses, and methods are described that combine a sorbent containing a flame retardant with a substrate, which is capable of responding to temperature increases to prevent, suppress, delay the spread of, or otherwise mitigate a proximal thermal event. A flame retardant system has a flame retardant material that is incorporated into a matrical sorbent material, which is incorporated into a substrate. The matrical sorbent material is configured to release the flame retardant material upon exposure to an elevated temperature, e.g., a temperature that is greater than 300° C. in one embodiment.

The invention relates to a method for the coating of a textile material, said method comprising the following steps: d) providing a coating composition comprising an aqueous solvent and an organosilicon precursor; e) impregnating the textile material with the coating composition by means of pad finishing; f) drying the impregnated textile material; characterized in that the coating composition contains no polycarboxylic acid or catalyst.

Systems, apparatuses, and methods are described that combine a sorbent containing a flame retardant with a substrate, which is capable of responding to temperature increases to prevent, suppress, delay the spread of, or otherwise mitigate a proximal thermal event. A flame retardant system has a flame retardant material that is incorporated into a matrical sorbent material, which is incorporated into a substrate. The matrical sorbent material is configured to release the flame retardant material upon exposure to an elevated temperature, e.g., a temperature that is greater than 300° C. in one embodiment.

Systems, apparatuses, and methods are described that combine a sorbent containing a flame retardant with a substrate, which is capable of responding to temperature increases to prevent, suppress, delay the spread of, or otherwise mitigate a proximal thermal event. A flame retardant system has a flame retardant material that is incorporated into a matrical sorbent material, which is incorporated into a substrate. The matrical sorbent material is configured to release the flame retardant material upon exposure to an elevated temperature, e.g., a temperature that is greater than 300° C. in one embodiment.

A method of synthesis of metal organic frameworks (“MOFs”) includes preparing a metal solution by dissolving at least one metal salt in an aqueous solution and buffering the metal solution with a base to achieve a first pH, the metal solution optionally comprising an organic co-solvent, preparing a linker solution by adding at least one organic acid linker and at least one base to an aqueous solution, and mixing the metal solution and the linker solution to produce the MOFs. The at least one organic acid linker has an ability to be protonated or deprotonated in response to a second pH, and the mixture of the metal solution and the linker solution has a third pH value, where the third pH value is greater than a highest pK.sub.a of the organic acid linker. The MOFs may be applied to a textile.

A method of synthesis of metal organic frameworks (“MOFs”) includes preparing a metal solution by dissolving at least one metal salt in an aqueous solution and buffering the metal solution with a base to achieve a first pH, the metal solution optionally comprising an organic co-solvent, preparing a linker solution by adding at least one organic acid linker and at least one base to an aqueous solution, and mixing the metal solution and the linker solution to produce the MOFs. The at least one organic acid linker has an ability to be protonated or deprotonated in response to a second pH, and the mixture of the metal solution and the linker solution has a third pH value, where the third pH value is greater than a highest pK.sub.a of the organic acid linker. The MOFs may be applied to a textile.

The present invention relates to a waterborne sizing composition for treating natural fibers to be used as reinforcing material in thermoplastic, comprising: (a) a polymeric material having structure (I) wherein, R represents an alkyl group, X represents a reversible covalently bonded crosslinkable group, p, q, and r represent order on a main polymer chain, wherein the total sum of order greater than 50; (b) a water-soluble metal complex having an antimicrobial property; and (c) a redox active water-soluble compound.

##STR00001##

The present invention relates to a waterborne sizing composition for treating natural fibers to be used as reinforcing material in thermoplastic, comprising: (a) a polymeric material having structure (I) wherein, R represents an alkyl group, X represents a reversible covalently bonded crosslinkable group, p, q, and r represent order on a main polymer chain, wherein the total sum of order greater than 50; (b) a water-soluble metal complex having an antimicrobial property; and (c) a redox active water-soluble compound.

##STR00001##

In example implementations, a method to convert metal precursors in textiles is provided. The method includes applying a liquid metal precursor to a textile. Then, energy (e.g., heat and/or pressure) is applied to the textile. The metal precursor is converted into metal nanoparticles in the textile by sustaining application of the energy.