The first water repellent agent composition contains amino-modified silicone, a silicone resin, and a polyfunctional isocyanate compound. The second water repellent agent composition comprising dimethylpolysiloxane having a hydroxyl group and/or an alkoxy group having 1 to 3 carbon atoms, an amino group-containing silane coupling agent, a silicone resin, and a polyfunctional isocyanate compound.

The first water repellent agent composition contains amino-modified silicone, a silicone resin, and a polyfunctional isocyanate compound. The second water repellent agent composition comprising dimethylpolysiloxane having a hydroxyl group and/or an alkoxy group having 1 to 3 carbon atoms, an amino group-containing silane coupling agent, a silicone resin, and a polyfunctional isocyanate compound.

A silsesquioxane polymer, composition, method, and article including such polymer, wherein the polymer includes a three-dimensional network of Formula (I): wherein: each R.sup.1 and R.sup.2 is independently a (C1-C4)alkyl; each L.sup.1 and L.sup.2 is independently in a single bond, an alkylene, or an alkylene bonded to a group selected from oxy, thio, carbonyl, NH, and combinations thereof; each R.sup.3 is independently a linear (C14-C100)alkyl; each R.sup.4 is independently a (C1-C30)alkyl, (C2-C30)heteroalkyl having at least one oxygen, sulfur, or NH group, or a (C1-C30)alkyl substituted with a fluoro, thiol, isocyanato, cyanato, hydroxyl, glycidoxy, or epoxy group; with the proviso that L.sup.1, L.sup.2, and R.sup.4 are selected such that each Si atom is directly bonded to an alkylene or an alkyl; m is an integer of at least 2; n is an integer of 0 or above; m+n is an integer of at least 3; each oxygen atom at an asterisk (*) is bonded to another Si atom within the three-dimensional network; and the silsesquioxane polymer is a solid at 25 C.

##STR00001##

A surface treatment agent containing: (A) a water repellent oil repellent polymer having a repeating unit derived from at least one water repellent oil repellent monomer selected from (A1) fluorine-containing monomers and (A2) non-fluorine monomers having a hydrocarbon group with 7-40 carbon atoms; (B) a silicone polymer represented by formula R.sup.53.sub.3SiO[Si(R.sup.51).sub.2O].sub.a[Si(R.sup.51)(R.sup.52)O].sub.bSiR.sup.53.sub.3 (wherein each R.sup.51 group independently represents hydrogen, alkyl having 1-20 carbon atoms, aryl having 6-20 carbon atoms or alkoxy having 1-4 carbon atoms; each R.sup.52 independently represents a saturated hydrocarbon group having 23-40 carbon atoms; each R.sup.53 independently represents a hydrogen atom, an alkyl group having 1-20 carbon atoms, an aryl group having 6-20 carbon atoms, an alkoxy group having 1-4 carbon atoms or a saturated hydrocarbon group having 23-40 carbon atoms; a represents an integer of 0 or more; b represents an integer of 1 or more; and (a+b) is 10-200); and (C) a liquid medium.

A fluorine-free composition includes at least one polycarbodiimide compound derived from a carbodiimidization reaction of a carbodiimidization reaction mixture comprising at least one oligomer, wherein the oligomer comprises at least one isocyanate end group and at least two repeating units, wherein each of the at least two repeating units comprises at least one hydrocarbon group having at least 16 carbon atoms. The composition may also include at least one paraffin wax. Such compositions are useful for treating fibrous substrates to enhance their water-repellency.

A fluorine-free composition includes at least one polycarbodiimide compound derived from a carbodiimidization reaction of a carbodiimidization reaction mixture comprising at least one oligomer, wherein the oligomer comprises at least one isocyanate end group and at least two repeating units, wherein each of the at least two repeating units comprises at least one hydrocarbon group having at least 16 carbon atoms. The composition may also include at least one paraffin wax. Such compositions are useful for treating fibrous substrates to enhance their water-repellency.

The invention relates to polyurethane organopolysiloxanes and their applications, in particular for the finishing of textile fabrics and textile fibres.

The invention relates to polyurethane organopolysiloxanes and their applications, in particular for the finishing of textile fabrics and textile fibres.

An aqueous emulsion including a discontinuous oil phase comprising: a) a polyorganohydrogensiloxane, b) an amino-modified polyorganosiloxane comprising at least one amino group located at a terminal position and c) a blocked isocyanate.

The first water repellent agent composition contains amino-modified silicone, a silicone resin, and a polyfunctional isocyanate compound. The second water repellent agent composition comprising dimethylpolysiloxane having a hydroxyl group and/or an alkoxy group having 1 to 3 carbon atoms, an amino group-containing silane coupling agent, a silicone resin, and a polyfunctional isocyanate compound.