A curable composition including: a component (a): a polycarbonate polyol having a hydroxyl value of 40 to 75 mgKOH/g; a component (b): a polycarbonate polyol having a hydroxyl value of 100 to 280 mgKOH/g; and a component (c): a polyisocyanate having an average number of functional groups per molecule, of 2 to 6.

The description relates to solvent free films and textiles that receive the solvent free films.

Provided is a production method in which a sheet-like article that has high moist heat resistance and has good surface quality and texture can be produced, regardless of the coagulation technique used for the polyurethane, by an environmentally friendly manufacturing process that is designed to cause reaction of a crosslinking agent while maintaining the texture possessed by the material before crosslinking. The production method for sheet-like articles is a sheet-like article production method characterized by impregnating a fibrous base material with water dispersed polyurethane as a binder, coagulating it to provide a sheet, adding a solution or dispersion liquid of a crosslinking agent to the sheet, and then heating it at a temperature of 100° C. or more and 200° C. or less.

An aqueous polyurethane dispersion comprises a polyurethane polymer obtainable by the reaction of an isocyanate-functional polyurethane prepolymer A) with an isocyanate-reactive component B), wherein the isocyanate-functional prepolymer A) is obtainable by the reaction of a mixture comprising: a polyol component comprising a polyester polyol obtainable by the reaction of a mixture comprising an aliphatic dicarboxylic acid and at least one diol selected from the group consisting of linear aliphatic diols and a branched aliphatic diols; and a polyisocyanate component comprising ≧50 weight-%, based on the total weight of polyisocyanates, of dicyclohexylmethane diisocyanate. The isocyanate-reactive component B) comprises a compound comprising sulfonate groups which is employed in an amount of ≧3.5 weight-% to ≦10 weight-%, based on the total weight of the polyol component, the polyisocyanate component and the isocyanate-reactive component B). The invention also concerns the use of such an aqueous polyurethane dispersion for coatings, a method of manufacturing a coated substrate and to a coated substrate.

A suede type artificial leather having an antifouling property is provided. A polymeric elastomer is impregnated in a nonwoven fabric formed by three-dimensionally interlacing ultrafine fibers and raising is formed, wherein the polymeric elastomer is a fluorine-containing modified polyurethane, and the fluorine-containing modified polyurethane is obtained by a polymerization of a urethane prepolymer having isocyanate groups at terminals, obtained by reacting a diol and a diisocyanate, and a fluorinated carbon compound having hydroxy functional groups at both terminals. The fluorine-containing modified polyurethane has a weight average molecular weight of 500,000 to 800,000. The suede type artificial leather is prepared by using the fluorine-containing polyurethane elastomer.

The present disclosure relates to a fire retardant laminate and a fire-resistant wood product comprising the fire retardant laminate.

Disclosed are a soft solvent-free flame-retardant polyurethane synthetic leather and a preparation method therefor. The soft solvent-free flame-retardant polyurethane synthetic leather comprises an antifouling layer, a surface layer, an intermediate layer, a bonding layer and a base cloth in sequence from top to bottom, wherein the bonding layer is prepared from component A and an isocyanate; the molar ratio of —NCO in the isocyanate to —OH in the component A is 0.85-0.93; and the component A is composed of a polyhydric alcohol, an inhibition-type catalyst, a flame retardant, a filler and a viscosity modifier in parts by weight.

Disclosed are a soft solvent-free flame-retardant polyurethane synthetic leather and a preparation method therefor. The soft solvent-free flame-retardant polyurethane synthetic leather comprises an antifouling layer, a surface layer, an intermediate layer, a bonding layer and a base cloth in sequence from top to bottom, wherein the bonding layer is prepared from component A and an isocyanate; the molar ratio of —NCO in the isocyanate to —OH in the component A is 0.85-0.93; and the component A is composed of a polyhydric alcohol, an inhibition-type catalyst, a flame retardant, a filler and a viscosity modifier in parts by weight. The polyurethane synthetic leather prepared by the present invention has daily life antifouling properties, a good durability, is soft to the touch, is strongly skin-friendly, and has a very superior flame-retardant performance, and also has excellent antifouling, scratch resistance and flexure resistance properties; the production process is simple, efficient and environmentally friendly and same can satisfy market demands.

The present disclosure relates to a polyurethane-urea resin composition for synthetic leather and a method of preparing the polyurethane-urea resin composition, the polyurethane-urea resin composition having excellent resin stability, heat resistance and aesthetic properties by including an ionic compound containing a sulfonic acid group, and by not including a neutralizer. In addition, the polyurethane-urea resin composition for synthetic leather may be applicable for various purposes by controlling a polyurethane-urea particle size to a desired size by controlling a content of the ionic compound containing a sulfonic acid group.

The disclosure provides a new method for preparing a WPU synthetic leather foaming layer based on a Pickering foam template method. The key of the method is to use the soft waterborne polyurethane as raw materials, add waterborne crosslinking agent and hydrophobic inorganic solid particles as Pickering waterborne foam stabilizers to obtain Pickering waterborne foam slurry of polyurethane latex particles through high-speed emulsification; and dry the slurry to obtain the waterborne polyurethane foam layer. The preparation process does not use any organic solvents, is clean and environmentally-friendly, and is simple to operate, making it easier to realize industrialized production. In addition, the Pickering foam has strong interface stability, which effectively solves the problem of difficult adjustment of the pore size caused by the accumulation and collapse of bubbles during the drying process of the mechanical foaming method, and the prepared synthetic leather foam layer has good hygienic properties.

A waterborne polyurethane dispersion is provided. The waterborne polyurethane dispersion comprises residual moiety of a hydroxy-terminated siloxane compound in the main chain and exhibits good anti-stickiness and/or wet color fastness while retaining superior mechanical properties. A laminated synthetic leather article prepared with said waterborne polyurethane dispersion as well the method for preparing the synthetic leather article are also provided.