Systems and methods for analyzing groundwater samples with multiple organic tracer species from a petroleum containing reservoir include obtaining the sample, isolating an aqueous fraction of the groundwater sample, separating the aqueous fraction into a plurality of components, where each component corresponds to a different one of the organic tracer species, combining each of the separated components with at least one lanthanide element to form a plurality of component solutions, where a ratio of the at least one lanthanide element to the separated component in each component solution is 5:1 or greater, and analyzing each component solution to determine a relative amount of each organic tracer species in the groundwater sample.

The invention provides a sample container arrangement for collecting multiphase samples of gas and liquid, particularly oil in water samples that are representative with respect to oil concentration, oil droplet size and oil droplet size distribution, the sample container arrangement comprises a sample container with an upper end, a lower end and a container volume for sample collection, such as a standing cylinder, distinctive in that the container arrangement further comprises: one inlet connected to the upper end or part of the container volume, one outlet with a valve with bleeding function, connected to the upper end or part of the container volume, and one outlet connected to the lower end of the container volume.

Method and system is described to exploration and development hydrocarbon resources. The method involves operations for exploring and developing hydrocarbons with one or more unmanned vehicles. The unmanned vehicles are used to obtain one or more samples that may be used to identify hydrocarbon systems, such as hydrocarbon seeps.

An analytical device configured for the introduction of the liquid or solid sample into a sample chamber where it is extracted by a chlorinated hydrocarbon solvent, wherein the extract then passes into a chamber where it undergoes a Friedel-Crafts (FC) reaction.

The invention is a system and method to measure oil content in water utilizing the fluorescence of oil emitted under excitation by laser. Oil and water mixture is transferred through the system to a measurement section in a microscope, which produces high resolution 3-dimensional images of the oil and water mixture with the fluorescence. The images are analyzed to calculate the amount of oil in water and oil droplets distribution. The image is also analyzed to distinguish oil coated solids from oil droplets, and to calculate the sizes and volumes of the solids.

A method of removing and detecting the presence of substances from at least one of a body of water and the air. The method includes placing into the body of water or into the air an open-cell foam material, removing separate portions of the open-cell foam material from the water or air at different exposure times after the open-cell foam material was placed into the water or air, and determining the presence in the removed separate portions of one or more substances that were removed from the water or air by the open-cell foam material.

The invention is a system and method to measure oil content in water utilizing the fluorescence of oil emitted under excitation by laser. Oil and water mixture is transferred through the system to a measurement section in a microscope, which produces high resolution 3-dimensional images of the oil and water mixture with the fluorescence. The images are analyzed to calculate the amount of oil in water and oil droplets distribution. The image is also analyzed to distinguish oil coated solids from oil droplets, and to calculate the sizes and volumes of the solids.

Online measurement of dispersed oil phase in produced water can be implemented a method on-site of a flowline transporting a fluid that includes dispersed oil in water. A sample of the fluid flowed through the flowline is obtained. The sample includes the oil phase and the water phase. The sample is combined with a chemical element that can separate the oil phase in the sample from the water phase in the sample. The separated oil phase and the chemical element are transferred into a measurement cell. The chemical element is removed from the measurement cell. After the chemical element is removed from the measurement cell, a quantity of the oil phase in the sample in the measurement cell is determined by a capacitive measurement technique. The determined quantity of the oil phase in the sample is provided.

Disclosed are methods of monitoring the presence of naphthenic acids and related compounds. In particular, the invention provides a method of continuously monitoring naphthenic acids and related compounds that break through a filtration step in a wastewater treatment process.

A device for detecting the presence of hydrocarbon fluid in runoff water includes an outer canister and a cartridge situated within the outer canister. The cartridge includes a pre-filter, at least one containment vessel, a diffuser/separator member situated within the containment vessel, a hydrocarbon fluid accumulator and an electronic circuit. The diffuser/separator member slows the flow of runoff water entering the containment vessel so that oil in the runoff water separates from and rises to the surface of the water where it accumulates in the hydrocarbon fluid accumulator. A sensor situated in the hydrocarbon fluid accumulator detects the accumulated oil and sends a signal to the electronic circuit which, in turn, closes a valve and prevents water from flowing through an egress opening in the outer canister.