Disclosed are electrolyte compositions comprising aryl group containing certain fluorinated carbonate, and batteries, especially batteries having a high nominal voltage, comprising such electrolyte composition.

An ultracapacitor that contains a first electrode, second electrode, separator, nonaqueous electrolyte, and housing is provided. The first electrode comprises a first current collector electrically coupled to a first carbonaceous coating and the second electrode comprises a second current collector electrically coupled to a second carbonaceous coating. The first current collector and the second current collector each contain a substrate that includes a conductive metal, wherein a plurality of fiber-like whiskers project outwardly from the substrate of the first current collector, the substrate of the second current collector, or both.

The present invention is directed to a method for pre-lithiation of negative electrodes during lithium loaded electrode manufacturing for use in lithium-ion capacitors. There is provided a system and method of manufacture of LIC electrodes using thin lithium film having holes therein, and in particular, to the process of manufacturing lithium loaded negative electrodes for lithium-ion capacitors by pre-lithiating electrodes with thin lithium metal films, wherein the thin lithium metal films include holes therein, and the lithium loaded negative electrodes are manufactured using a roll-to-roll lamination manufacturing process.

Technologies are generally described for an electron conductive polymer capacitor may incorporate a conductive polymer mixture embedded with carbon nanoparticles between electrodes to rapidly charge and store large amounts of charge compared to conventional electrolytic capacitors. Such a capacitor may be constructed with a laminate sheet including layers of inner and outer electrodes, an electrolyte mixture between the electrodes, a conductive polymer mixture, and a composite mixture of carbon nanoparticles embedded in the conductive polymer between the inner electrodes. The laminate sheet may be wound into a roll and the inner and outer electrodes are coupled electrically. When an electric field is applied, cations within the electrolyte mixture move towards the outer electrodes and anions towards the inner electrodes. Further, the inner conductive polymer layer is ionized causing electrons to move toward the inner electrodes to be deposited onto high surface area carbon nanoparticles where charge is stored.

Technologies are generally described for an electron conductive polymer capacitor may incorporate a conductive polymer mixture embedded with carbon nanoparticles between electrodes to rapidly charge and store large amounts of charge compared to conventional electrolytic capacitors. Such a capacitor may be constructed with a laminate sheet including layers of inner and outer electrodes, an electrolyte mixture between the electrodes, a conductive polymer mixture, and a composite mixture of carbon nanoparticles embedded in the conductive polymer between the inner electrodes. The laminate sheet may be wound into a roll and the inner and outer electrodes are coupled electrically. When an electric field is applied, cations within the electrolyte mixture move towards the outer electrodes and anions towards the inner electrodes. Further, the inner conductive polymer layer is ionized causing electrons to move toward the inner electrodes to be deposited onto high surface area carbon nanoparticles where charge is stored.

An energy storage device comprises a first porous semiconducting structure (510) comprising a first plurality of channels (511) that contain a first electrolyte (514) and a second porous semiconducting structure (520) comprising a second plurality of channels (521) that contain a second electrolyte (524). In one embodiment, the energy storage device further comprises a film (535) on at least one of the first and second porous semiconducting structures, the film comprising a material capable of exhibiting reversible electron transfer reactions. In another embodiment, at least one of the first and second electrolytes contains a plurality of metal ions. In another embodiment, the first and second electrolytes, taken together, comprise a redox system.

An energy storage device comprises a first porous semiconducting structure (510) comprising a first plurality of channels (511) that contain a first electrolyte (514) and a second porous semiconducting structure (520) comprising a second plurality of channels (521) that contain a second electrolyte (524). In one embodiment, the energy storage device further comprises a film (535) on at least one of the first and second porous semiconducting structures, the film comprising a material capable of exhibiting reversible electron transfer reactions. In another embodiment, at least one of the first and second electrolytes contains a plurality of metal ions. In another embodiment, the first and second electrolytes, taken together, comprise a redox system.

The electrolyte includes one or more salts and a silane. The silane has a silicon linked to one or more first substituents that each include a poly(alkylene oxide) moiety or a cyclic carbonate moiety. The silane can be linked to four of the first substituents. Alternately, the silane can be linked to the one or more first substituents and one or more second substituents that each exclude both a poly(alkylene oxide) moiety and a cyclic carbonate moiety.

The present disclosure further provides an exemplary energy storage device fabricated from rectangular-tube polyaniline (PANI) that is chemically synthesized by a simple and convenient method. The rectangular-tube PANI, as an active material, is synthesized on a functionalized carbon cloth (FCC) as a substrate, and the obtained composite is immobilized on a stainless steel mesh as a current collector. The present disclosure additionally presents a facile technique for the direct synthesis of PANI nanotubes, with rectangular pores, on chemically activated CC.

A gas detection sheet wherein a porous coordination polymer represented by formula (1) is supported on a supporter and the air permeability of the gas detection sheet is 0.8 seconds or more and 60 seconds or less.

Fe.sub.x(pz)[Ni.sub.1-yM.sub.y(CN).sub.4]  (1)

(wherein, pz=pyrazine, 0.95≦x<1.05, M=Pd or Pt, 0≦y<0.15).