Alkaline electrochemical cells are provided, wherein an organic additive is included in at least one component of the cell in order to increase electron discharge of the cathode, so as to improve the specific capacity of the cell. Methods for preparing such cells are also provided.

Provided is a method for producing a composite alloy for use in an electrode for an alkaline storage battery, including a powder preparation step of preparing a hydrogen storage alloy powder containing Ti and Cr and having a BCC structure, an etching step of applying an acid to the hydrogen storage alloy powder prepared in the powder preparation step, a Pd film forming step of coating the surface of the hydrogen storage alloy powder subjected to the etching step with Pd using a substitution plating method, and a heat treatment step of heating the hydrogen storage alloy powder having a Pd film formed, at said heating being a temperature of 500° C. or less, wherein in the Pd coating forming step, the hydrogen storage alloy powder is coated with Pd under the condition that the Pd element weight ratio of the composite alloy to be produced is 0.47% or more.

A system and method for implementing and manufacturing a hierarchy system for use with a TMCCC-containing electrically-conductive structure (e.g., an electrode) as well as methods for use and manufacturing of such structures and electrochemical cells including these devices. Structures and methods include a coordination complex having L.sub.xM.sub.yN.sub.zTi.sub.a1V.sub.a2Cr.sub.a3Mn.sub.a4Fe.sub.a5Co.sub.a6Ni.sub.a7Cu.sub.a8Zn.sub.a9Ca.sub.a10Mg.sub.a11[R(CN).sub.6].sub.b (H.sub.2O).sub.c. The method includes binding electrochemically active material to produce a hierarchical structure, the hierarchical structure having a plurality of primary crystallites having a size D1, the plurality of these primary crystallites agglomerated into a set of agglomerates each agglomerate having a size D2>D1.

A system and method for implementing and manufacturing a hierarchy system for use with a TMCCC-containing electrically-conductive structure (e.g., an electrode) as well as methods for use and manufacturing of such structures and electrochemical cells including these devices. Structures and methods include a coordination complex having L.sub.xM.sub.yN.sub.zTi.sub.a1V.sub.a2Cr.sub.a3Mn.sub.a4Fe.sub.a5Co.sub.a6Ni.sub.a7Cu.sub.a8Zn.sub.a9Ca.sub.a10Mg.sub.a11[R(CN).sub.6].sub.b (H.sub.2O).sub.c. The method includes binding electrochemically active material to produce a hierarchical structure, the hierarchical structure having a plurality of primary crystallites having a size D1, the plurality of these primary crystallites agglomerated into a set of agglomerates each agglomerate having a size D2>D1.

Provided is a layered double hydroxide (LDH) separator capable of more effectively restraining short circuiting caused by zinc dendrites. The LDH separator includes a porous substrate made of a polymer material and LDH plugging pores in the porous substrate, and has a linear transmittance of 1% or more at a wavelength of 1000 nm.

Provided is a layered double hydroxide (LDH) separator capable of more effectively restraining short circuiting caused by zinc dendrites. The LDH separator includes a porous substrate made of a polymer material and LDH plugging pores in the porous substrate, and has a linear transmittance of 1% or more at a wavelength of 1000 nm.

A positive-electrode core laminate of a portion of a positive-electrode core on which no positive-electrode active material layer is formed is bonded to a positive-electrode current collector by ultrasonic bonding. A core recess is formed in a bonding region of the positive-electrode core laminate bonded to the positive-electrode current collector by ultrasonic bonding, a region of the positive-electrode core laminate in which the core recess is formed includes a solid-state bonding layer and a central layer, the solid-state bonding layer being formed by solid-state bonding between layers of the positive-electrode core, the central layer being disposed between the solid-state bonding layers formed on both faces of the positive-electrode core, and the first average grain size of metal crystal grains constituting the solid-state bonding layer is smaller than the second average grain size of metal crystal grains constituting the central layer.

Provided is a layered double hydroxide (LDH) separator including a porous substrate made of a polymeric material; and a hydroxide-ion conductive layered compound being a LDH and/or a LDH-like compound with which pores of the porous substrate are plugged. The LDH separator has a mean porosity of 0.03% to less than 1.0%.

Provided is a layered double hydroxide (LDH) separator including a porous substrate made of a polymeric material; and a hydroxide-ion conductive layered compound being a LDH and/or a LDH-like compound with which pores of the porous substrate are plugged. The LDH separator has a mean porosity of 0.03% to less than 1.0%.

A system and method for implementing and manufacturing a hierarchy system for use with a TMCCC-containing electrically-conductive structure (e.g., an electrode) as well as methods for use and manufacturing of such structures and electrochemical cells including these devices. Structures and methods include a coordination complex having L.sub.xM.sub.yN.sub.zTi.sub.a1V.sub.a2Cr.sub.a3Mn.sub.a4Fe.sub.a5Co.sub.a6Ni.sub.a7Cu.sub.a8Zn.sub.a9Ca.sub.a10Mg.sub.a11[R(CN).sub.6].sub.b (H.sub.2O).sub.c. The method includes binding electrochemically active material to produce a hierarchical structure, the hierarchical structure having a plurality of primary crystallites having a size D1, the plurality of these primary crystallites agglomerated into a set of agglomerates each agglomerate having a size D2>D1.