Disclosed herein is an anode for a secondary battery manufactured thereby. The anode for a secondary battery includes a first adhesive member and a second adhesive member to which a plurality of electrolytes are fused, a first case configured to be fused to the first adhesive member, and a second case configured to be fused to the second adhesive member and the first case and into which an anode active material and a liquid electrolyte are injected. The anode has an effect of maximizing a reaction area because an electrolyte is exposed at both surfaces of the anode for a secondary battery.

The present invention relates to a rechargeable electrochemical battery cell having a housing, a positive electrode, a negative electrode, and an electrolyte, the electrolyte containing sulfur dioxide and a conductive salt of the active metal of the cell. The total quantity of oxygen-containing compounds contained in the cell that are able to react with the sulfur dioxide, reducing the sulfur dioxide, is not more than 10 mMol per Ah theoretical capacitance of the cell.

Disclosed herein are a manufacturing method of an anode for a secondary battery and an anode for a secondary battery manufactured thereby. The manufacturing method of an anode for a secondary battery includes firstly fusing a plurality of electrolytes to a first adhesive member and a second adhesive member, secondly fusing the first adhesive member and the second adhesive member to a first case and a second case, respectively, injecting an anode active material and a liquid electrolyte into the second case to which the second adhesive member is fused, and thirdly fusing the first case and the second case to each other. The anode for a secondary battery has an effect of maximizing a reaction area because an electrolyte is exposed at both surfaces of the anode for a secondary battery.

A method of manufacturing an electrochemical cell includes transferring an anode semi-solid suspension to an anode compartment defined at least in part by an anode current collector and an separator spaced apart from the anode collector. The method also includes transferring a cathode semi-solid suspension to a cathode compartment defined at least in part by a cathode current collector and the separator spaced apart from the cathode collector. The transferring of the anode semi-solid suspension to the anode compartment and the cathode semi-solid to the cathode compartment is such that a difference between a minimum distance and a maximum distance between the anode current collector and the separator is maintained within a predetermined tolerance. The method includes sealing the anode compartment and the cathode compartment.

Disclosed herein is an anode for a secondary battery manufactured thereby. The anode for a secondary battery includes a first adhesive member and a second adhesive member to which a plurality of electrolytes are fused, a first case configured to be fused to the first adhesive member, and a second case configured to be fused to the second adhesive member and the first case and into which an anode active material and a liquid electrolyte are injected. The anode has an effect of maximizing a reaction area because an electrolyte is exposed at both surfaces of the anode for a secondary battery.

A method of manufacturing an electrochemical cell includes transferring an anode semi-solid suspension to an anode compartment defined at least in part by an anode current collector and an separator spaced apart from the anode collector. The method also includes transferring a cathode semi-solid suspension to a cathode compartment defined at least in part by a cathode current collector and the separator spaced apart from the cathode collector. The transferring of the anode semi-solid suspension to the anode compartment and the cathode semi-solid to the cathode compartment is such that a difference between a minimum distance and a maximum distance between the anode current collector and the separator is maintained within a predetermined tolerance. The method includes sealing the anode compartment and the cathode compartment.

A method of manufacturing an electrochemical cell includes transferring an anode semi-solid suspension to an anode compartment defined at least in part by an anode current collector and an separator spaced apart from the anode collector. The method also includes transferring a cathode semi-solid suspension to a cathode compartment defined at least in part by a cathode current collector and the separator spaced apart from the cathode collector. The transferring of the anode semi-solid suspension to the anode compartment and the cathode semi-solid to the cathode compartment is such that a difference between a minimum distance and a maximum distance between the anode current collector and the separator is maintained within a predetermined tolerance. The method includes sealing the anode compartment and the cathode compartment.

A positive electrode active material particle includes a core that contains lithium cobalt oxide represented by the following Chemical Formula Li.sub.aCo.sub.(1-x)M.sub.xO.sub.2-yA.sub.y and a shell that is coated on the surface of the core and contains composite metal oxide of a metal with an oxidation number of +2 and a metal with an oxidation number of +3. In particular, M is at least one selected from the group consisting of Ti, Mg, Zn, Si, Al, Zr, V, Mn, Nb and Ni. A is oxygen-substitutional halogen and 1.00?a?1.05, 0?x?0.05, and 0?y?0.001.

Using the generally used coating method of an active material paste to a metal foil on a 3DF made the electrode properties instable due to residual air inside of the 3DF, and had the risk of causing micro short circuit of the battery due to metal fine powder and the like adhered to the 3DF and the 3DF exposed to the electrode surface. To solve the above-mentioned, the coating of the active material paste to the 3DF was made into a two-step coating process as shown below. Step one removes the air and fills the paste at the same time by applying the paste flow from one side of the 3DF (the first step coating process). Step two coats a new paste onto the surface of the electrode obtained by step one (the second step coating process). This electrode obtained by the two-step coating process hardly has remaining air amount, can uniformly confine metallic power dust or the 3DF itself inside the electrode (the first step coating process), and in addition to this, has the capability of Li ions freely moving between the electrode surface and the depth portion of the electrode through the opening portion formed on the tip portion of the innumerable protrusions of the 3DF, the micro short circuit of the battery due to Li dendrite was prevented even in repeated charge and discharge.

The present disclosure is directed to electrochemical cells having injection molded or 3D printed components, such as cathodes, anodes, and/or electrolytes, and methods for making such electrochemical cells. The cathodes, anodes, and/or electrolytes can be formed from a binder resin and various conductive and active materials, mixtures of which are injected into a mold under heat and pressure to form the components of the electrochemical cells. The cathode can include conductive metallic powder, flakes, ribbons, fibers, wires, and/or nanotubes. Further, electrochemical arrays can be formed from multiple electrochemical cells having injection molded or 3D printed components.