A heat shrinkable film shows a heat shrinkage rate in the direction perpendicular to the main shrinkage direction that is not high even at high temperature and is printable thereon. The heat shrinkable film includes a polyester resin, wherein the heat shrinkage characteristics in the direction perpendicular to the main shrinkage direction satisfy the following Relationships 1 and 2:

−15≤ΔT.sub.70-65≤0  Relationship 1

0≤ΔT.sub.100-95≤5  Relationship 2 wherein ΔT.sub.X-Y is a value obtained by subtracting heat shrinkage rate of the heat shrinkable film in the direction perpendicular to the main shrinkage direction after the heat shrinkable film is immersed in water bath for 10 seconds at Y° C. from heat shrinkage rate of the heat shrinkable film in the direction perpendicular to the main shrinkage direction after the heat shrinkable film is immersed in water bath for 10 seconds at X° C.

Methods for preparing oriented polymer tubes, such as biodegradable polymer tubes suitable for in vivo use, are provided herein. The disclosed methods provide alternatives to the typical extrusion/expansion methods by which oriented polymeric tubes for such uses are commonly produced. Advantageously, the disclosed methods can provide more homogeneous molecular orientation of crystallizable polymers within the tube walls, which can endow such polymeric tubes with enhanced strength (e.g., resistance to compression) and toughness.

To provide a biaxially-stretched polyester film that can be used as a base film for vapor deposition, has excellent barrier properties, dimensional stability, processability, bag breakage resistance, and chemical resistance, and has less transfer of an extract to contents after retorting. A biaxially-stretched polyester film having features (a), (b), (c), and (d) below and having a thickness of 10 to 30 μm: (a) the biaxially-stretched polyester film is formed from a polyester resin composition containing a polybutylene terephthalate resin (A) in a range of 60% by mass or more; (b) a thermal shrinkage of the biaxially-stretched polyester film at 150° C. for 30 minutes is −2 to +2%; (c) thickness accuracy of the biaxially-stretched polyester film is 1 to 20%; and (d) a total amount of 1,4-butanediol and tetrahydrofuran volatilized during heating at a temperature of 135° C. for 60 minutes is not more than 2000 ppb.

The invention provides a polyester sealant film having at least one of a heat sealing layer and a heat resistant layer, wherein each layer consists of a polyester component containing ethylene terephthalate. The polyester sealant film has (1) a heat sealing strength of the heat sealing layers of 8-20 N/15 mm; (2) a difference in reversible heat capacity (ΔCp) for the heat sealing layer of 0.5-1.1 J/g/K; (3) a ΔCp for the heat resistant layer of 0.1 to less than 0.6 J/g/K; (4) a fold holding angle of 20-60 degrees; (5) a smaller curvature radius of 50-300 mm in a longitudinal or widthwise direction; and (6) a heat shrinkage ratio of −5% to 5% in both longitudinal and widthwise directions. The invention also provides a laminate comprising at least one layer of the polyester sealant and a packaging bag comprising the laminate.

Embodiments relate to a heat shrinkable film, which has a heat shrinkage rate in the direction perpendicular to the main shrinkage direction that is not high even at a high temperature and which is printable thereon. The heat shrinkable film comprises a polyester resin, wherein the heat shrinkage characteristics in the direction perpendicular to the main shrinkage direction satisfy the following Relationships 1 and 2:
−15≤ΔT.sub.70−65≤0  [Relationship 1]
0≤ΔT.sub.100−95≤5  [Relationship 2] wherein ΔT.sub.X−Y is a value obtained by subtracting a heat shrinkage rate of the heat shrinkable film in the direction perpendicular to the main shrinkage direction after the heat shrinkable film is immersed in a water bath for 10 seconds at Y° C. from a heat shrinkage rate of the heat shrinkable film in the direction perpendicular to the main shrinkage direction after the heat shrinkable film is immersed in a water bath for 10 seconds at X° C.

The present invention relates to a method, to a biodegradable film and to a package for cheese ripening or preservation, in particular for ripening hard or semi-hard cheese, preferably rind cheese. This method, thanks to the peculiar transmission properties of the film, provides cheese more similar to naturally ripened cheese, with a minor loss of water, due to evaporation, with reduced mold and yeast growth, and without significant flavor, consistency and color deviations.

A sealed pharmaceutical container includes a shoulder, a neck extending from the shoulder, and a flange extending from the neck. The flange includes an inclined sealing surface defining an opening in the sealed pharmaceutical container. The sealed pharmaceutical container also includes a sealing assembly including a stopper extending over the sealing surface of the flange and a cap securing the stopper to the flange. The stopper has a glass transition temperature (T.sub.g) that is greater than or equal to 70 C. and less than or equal to 45 C. The sealing assembly maintains a helium leakage rate of the sealed pharmaceutical container of less than or equal to 1.410.sup.6 cm.sup.3/s as the sealed pharmaceutical container is cooled to a temperature of less than or equal to 45 C.

A laminated body having at least two or more different layers, wherein the laminate body is characterized by satisfying the following requirements (1) to (5): (1) the laminate body has a heat-sealing layer as at least one of the outermost layers, wherein the heat-sealing layer includes a polyester based component containing ethylene terephthalate as a main constituent component, and a sealing strength of 8 N/15 mm to 30 N/15 mm; (2) at least one layer other than the heat-sealing layer is an inorganic thin film layer; (3) a water vapor permeation rate of 0.1 g/m.sup.2.Math.d to 6 g/m.sup.2.Math.d; (4) an oxygen permeation rate of 5 ml/m.sup.2.Math.d.Math.MPa to 30 ml/m.sup.2.Math.d.Math.MPa; and (5) a heat shrinkage rate of 5% to 5%.

Coextruded, biaxially oriented multilayer films comprising a base layer comprising a polyester having an intrinsic viscosity greater than 0.75 dl/g and a heat-sealable layer directly adhered to said base layer, said heat-sealable layer comprising an amorphous polyester having a melting temperature not higher than the melting temperature of the polyester of the base layer and a thermoplastic resin characterized in that the heat-sealable layer comprises a further polyester resin are described. Also packages comprising a container, a food product and the above coextruded, biaxially oriented multilayer film are described. The packages are particularly suitable for ready-meals to be used in conventional oven at high temperatures.

A shrink film comprising a core layer comprising a glycol modified polyester, the core having an upper and lower surface; an upper skin layer disposed on the upper surface of the core layer and a lower skin layer disposed on the lower surface of the core layer, the skin layers each individually comprising (a) a resin material; and (b) an antiblocking agent.