NON-THERMAL REFINED NITROCARBURIZED COMPONENT

Abstract

A non-thermal refined nitrocarburized component with excellent bending straightening and fatigue strength, includes a base metal steel material having a composition consisting of: (mass %), C: 0.35 to 0.50%; Si: 0.10 to 0.35%; Mn: 2.3 to 2.8%; S: 0.01% or less; N: 0.0030 to 0.0250%; Cu: 0 to 1.0%; Mo: 0 to 0.3%; Ni: 0 to 0.5%; Ti: 0 to 0.020%, the balance: Fe, impurities, and 3.10 £ (0.316 C+0.122).Math.(0.7 Si+1).Math.(5.1 Mn−1.12).Math.(0.364 Ni+1).Math.(2.16 Cr+1).Math.(3 Mo+1) £ 6.00. Impurities include P: 0.08% or less, Al: 0.05% or less, and Cr: less than 0.20%. In a stress concentrated region, an HV hardness 0.05 mm from a surface is 410 to 480, an HV hardness 1.0 mm from the surface is 200 or more, a compound-layer depth is 5 mm or less, and a base metal micro-structure is bainite.

Claims

1. A non-thermal refined nitrocarburized component, comprising a steel material of a base metal, the steel material having a chemical composition comprising: by mass %, C: 0.35 to 0.50%; Si: 0.10 to 0.35%; Mn: 2.3 to 2.8%; S: 0.01% or less; N: 0.0030 to 0.0250%; Cu: 0 to 1.0%; Mo: 0 to 0.3%; Ni: 0 to 0.5%; Ti: 0 to 0.020%; and the balance: Fe and impurities, wherein Fn1 shown by the below described Formula [1] satisfies 3.10≦Fn1≦6.00, and the impurities include P: 0.08% or less; Al: 0.05% or less; and Cr: less than 0.20%, and wherein at a stress concentrated region, an HV hardness at a position of 0.05 mm from a surface is 410 to 480, an HV hardness at a position of 1.0 mm from the surface is 200 or more, a compound-layer depth is 5 μm or less, and a metal micro-structure of the base metal is a bainite micro-structure:
Fn1=(0.316 C+0.122)×(0.7 Si+1)×(5.1 Mn−1.12)×(0.364 Ni+1)×(2.16 Cr+1)×(3 Mo+1)   [1], where an symbol of an element in Formula [1] indicates a content of the element in steel in mass %.

2. The non-thermal refined nitrocarburized component according to claim 1, wherein the chemical composition of the steel material of the base metal contains, in mass %, one or more types of elements selected from Cu: 0.05 to 1.0%, and Mo: 0.05 to 0.3%.

3. The non-thermal refined nitrocarburized component according to claim 1, wherein the chemical composition of the steel material of the base metal contains, in mass %, one or more types of elements selected from Ni: 0.05 to 0.5%, and Ti: 0.005 to 0.020%.

4. The non-thermal refined nitrocarburized component according to claim 2, wherein the chemical composition of the steel material of the base metal contains, in mass %, one or more types of elements selected from Ni: 0.05 to 0.5%, and Ti: 0.005 to 0.020%.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0065] FIG. 1 is a drawing exemplifying a part of a crankshaft as a non-thermal refined nitrocarburized component, and explaining a “pin fillet section” and a “journal fillet section” equivalent to a “stress concentrated region” of the crankshaft.

[0066] FIG. 2 is a drawing showing a shape of a grooved Ono-type rotating bending fatigue test specimen used in Example; and a unit of measurement in the drawing is “mm”.

[0067] FIG. 3 is a drawing showing a shape of a four-point bending test specimen used in Example; and a unit of measurement in the drawing is “mm”.

[0068] FIG. 4 is a drawing showing a target surface to be examined of a four-point bending test specimen used in Examples.

[0069] FIG. 5 is a drawing schematically showing measurement positions of hardness in the Vickers hardness test in a four-point bending test specimen used in Examples.

[0070] FIG. 6 is a drawing schematically showing measurement positions of compound-layer depth in a four-point bending test specimen used in Examples.

MODE FOR CARRYING OUT THE INVENTION

[0071] Each requirement of the present invention will be described in detail, hereinafter. It should be noted that “%” for a content of each element denotes “mass %”.

[0072] (A) Chemical Composition of Steel Material of Base Metal:

[0073] C: 035 to 0.50%

[0074] C has an action to improve the internal hardness, and enhance the bending fatigue strength. The C content is required to be 0.35% or more in order to attain a desired bending fatigue strength. However, an excessive C content results in an excessively high surface-layer hardness, so that it is hard to attain a sufficient bending straightening property even if the compound-layer depth at the stress concentrated region is 5 μm or less. Hence, the C content is set to be 0.35 to 0.50%. The C content is preferably 0.38% or more, and preferably 0.45% or less.

[0075] Si: 0.10 to 0.35%

[0076] Si is an element necessary for deoxidation during melting the steel, and the Si content of at least 0.10% is required for obtaining the above effect. However, an excessive content of Si causes excessive deterioration of the bending straightening property even if the compound-layer depth at the stress concentrated region is 5 μm or less. Hence, the Si content is set to be 0.10 to 0.35%. The Si content is preferably 0.15% or more, and preferably 0.30% or less.

[0077] Mn: 2.3 to 2.8%

[0078] Mn is an element having a deoxidizing action similar to Si. Mn also has an action to increase a solute nitrogen content in the surface layer during the nitrocarburizing to improve the surface-layer hardness, thereby enhancing the bending fatigue strength. In order to exert this effect, the Mn content is required to be 2.3% or more. On the other hand, the Mn content of more than 2.8% causes an excessively high surface-layer hardness, which excessively deteriorates the bending straightening property even if the compound-layer depth at the stress concentrated region is 5 μm or less. Accordingly, the Mn content is set to be 2.3 to 2.8%. The Mn content is preferably 2.4% or more, and preferably 2.7% or less.

[0079] S: 0.10% or less

[0080] An effect to improve machinability can be attained by actively containing S. However, the S content of more than 0.10% significantly deteriorates the bending fatigue strength and the bending straightening property. Accordingly, the S content is set to be 0.10% or less. It is preferable to set the S content to be 0.08% or less. In order to attain the effect to improve machinability, it is preferable to set the S content to be 0.04% or more.

[0081] N: 0.0030 to 0.0250%

[0082] N is an element to improve the bending fatigue strength and the bending straightening property. In order to attain this effect, the N content is required to be 0.0030% or more. On the other hand, the N content of more than 0.0250% rather saturates this effect. Accordingly, the N content is set to be 0.0030 to 0.0250%. The N content is preferably 0.0080% or more, and preferably 0.0220% or less.

[0083] Cu: 0 to 1.0%

[0084] Cu is an element to improve the internal hardness, and enhance the bending fatigue strength. Hence, Cu may be contained as needed. However, the Cu content of more than 1.0% deteriorates hot workability. Accordingly, the amount of Cu to be contained is set to be 1.0% or less. The amount of Cu is preferably 0.4% or less, and more preferably 0.3% or less.

[0085] In order to stably attain the above effect, it is preferable to set the amount of Cu to be 0.05% or more, and more preferably 0.1% or more.

[0086] Mo: 0 to 0.3%

[0087] Mo has an action to strengthen ferrite, and improve the internal hardness to enhance the bending fatigue strength. Hence, Mo may be contained as needed. However, an excessive Mo content of more than 0.3% rather saturates the above effect, only to deteriorate economic efficiency. Accordingly, the amount of Mo to be contained is set to be 0.3% or less. The amount of Mo is preferably 0.2% or less.

[0088] In order to stably attain the above effect, the amount of Mo is preferably 0.05% or more, and more preferably 0.1% or more.

[0089] Any one type selected from Cu and Mo, or two types selected from Cu and Mo in combination may be contained. The total content when these elements are contained in combination may be 1.3%, and preferably 0.3% or less.

[0090] Ni: 0 to 0.5%

[0091] Ni is an element to improve toughness, and enhance the bending straightening property. Accordingly, Ni may be contained as needed. However, the Ni content of more than 0.5% rather saturates the above effect, only to deteriorate the economic efficiency. Hence, the amount of Ni to be contained is set to be 0.5% or less. The amount of Ni is preferably 0.3% or less, and more preferably 0.2% or less.

[0092] In order to stably attain the above effect, the amount of Ni is preferably 0.05% or more, and more preferably 0.08% or more.

[0093] In the case of containing Cu, it is likely to cause hot cracking called “Cu checking”, and in order to prevent this, it is preferable to contain Cu in combination with Ni in a manner as to satisfy Ni/Cu≧0.5.

[0094] Ti: 0 to 0.020%

[0095] Ti is an element that forms nitride, and refines grains to hinder propagation of cracking during the bending-straightening, thereby enhancing the bending straightening property. Accordingly, Ti may be contained as needed. However, the Ti content of more than 0.020% generates coarse nitride, and significantly deteriorates the bending straightening property even if the compound-layer depth at the stress concentrated region is 5 μm or less. Accordingly, the amount of Ti to be contained is set to be 0.020% or less. The amount of Ti is preferably 0.015% or less.

[0096] In order to stably attain the above effect, the amount of Ti is preferably 0.005% or more.

[0097] Any one type selected from Ni and Ti, or two types selected from Ni and Ti in combination may be contained. The total content when these elements are contained in combination may be 0.520%, and preferably 0.30% or less.

[0098] Fn1: within range of 3.10 to 6.00

[0099] In the non-thermal refined nitrocarburized component according to the present invention, Fn1 represented by the below described Formula [1] is within a range of 3.10 to 6.00:

Fn1=(0.316 C+0.122)×(0.7 Si+1)×(5.1 Mn−1.12)×(0.364 Ni+1)×(2.16 Cr+1)×(3 Mo+1)   [1],

where an symbol of an element in Formula [1] indicates a content of the element in steel in mass %.

[0100] Fn1 is an index relating to the base material micro-structure. Any of C, Si, Mn, Ni, Cr, and Mo improves hardenability of steel. If Fn1 is 3.10 or more, the hardenability of steel material becomes sufficiently high, and the base material micro-structure becomes a bainite micro-structure, which allows to impart a high endurance ratio to the base material. However, if Fn1 becomes more than 6.00, the base material micro-structure becomes a martensite micro-structure, and the hardness becomes excessively high, thus adversely affecting the bending straightening property. Hence, Fn1 is set to be 3.10≦Fn1≦6.00. Fn1 is preferably 3.50 or more, and is also preferably 5.00 or less.

[0101] The non-thermal refined nitrocarburized component according to the present invention includes a steel material of a base metal having a chemical composition consisting of each element described above, with the balance being Fe and impurities, where the impurities include P: 0.08% or less; Al: 0.05% or less; and Cr: less than 0.20%.

[0102] P: 0.08% or less

[0103] P is an impurity contained in the steel, and deteriorates the bending fatigue strength. Particularly, the P content of more than 0.08% significantly deteriorates the bending fatigue strength. Accordingly, the P content is set to be 0.08% or less. It is preferable to set the P content to be 0.04% or less.

[0104] Al: 0.05% or less

[0105] Al is an impurity contained in the steel. An excessive Al content deteriorates the bending straightening property. Particularly, the S content of more than 0.05% significantly deteriorates the bending straightening property even if the compound-layer depth at the stress concentrated region is 5 μm or less. Accordingly, the Al content is set to be 0.05% or less. The Al content is preferably 0.03% or less.

[0106] Cr: less than 0.20%

[0107] Cr is an impurity contained in the steel. Containing Cr may excessively increase the surface-layer hardness, which deteriorates the bending straightening property; thus it is preferable to set the Cr content to be as small as possible. Accordingly, the Cr content is set to be less than 0.20%. The Cr content is preferably 0.10% or less.

[0108] (B) Hardness, Compound-Layer Depth, and Micro-Structure:

[0109] In the non-thermal refined nitrocarburized component according to the present invention, (1) at a stress concentrated region, the HV hardness at a position of 0.05 mm from a surface, that is, the HV hardness in a surface layer is 410 to 480; the HV hardness at a position of 1.0 mm from the surface, that is, the HV hardness at an internal part is 200 or more; the compound-layer depth is 5 μm or less, and (2) the metal micro-structure of the base metal is a bainite micro-structure.

[0110] (B-1) Surface-Layer Hardness at Steel Concentrated Region

[0111] In order to attain a fatigue strength as high as 800 MPa or more, it is necessary that the HV hardness in the surface layer at a stress concentrated region is 410 or more. On the other hand, if the HV hardness in the surface layer at the stress concentrated region is more than 480, in the case of using a crankshaft shape to likely cause a greater bending than that of a conventional art during the nitrocarburizing, it may be hard to attain a practically sufficient bending straightening property even if the compound-layer depth at the stress concentrated region is 5 μm or less.

[0112] Accordingly, in the non-thermal refined nitrocarburized component according to the present invention, the HV hardness at a position of 0.05 mm from the surface at the stress concentrated region is set to be 410 to 480. The HV hardness at a position of 0.05 mm from the surface at the stress concentrated region is preferably 420 or more, and preferably 470 or less.

[0113] (B-2) Internal Hardness at the Stress Concentrated Region:

[0114] In the non-thermal refined nitrocarburized component, since the endurance ratio of the base metal is lower than that in the thermal refined nitrocarburized component, at the stress concentrated region, the fatigue strength of the base metal becomes lower than that in the thermal refined nitrocarburized component even if the non-thermal refined nitrocarburized component has an internal hardness equivalent to that of the thermal refined nitrocarburized component. Consequently, in the non-thermal refined nitrocarburized component, at the stress concentrated region, in the case of having an HV hardness of less than 200 at the internal part, even if the non-thermal refined nitrocarburized component has an internal hardness equivalent to that of the thermal refined nitrocarburized component, and also has a surface-layer hardness as high as 410 or more in terms of the HV hardness, fatigue fractures initiated from the internal part may be caused, which makes it hard to attain a high fatigue strength of 800 MPa or more.

[0115] Accordingly, in the non-thermal refined nitrocarburized component according to the present invention, the HV hardness at a position of 1.0 mm from the surface at the stress concentrated region is set to be 200 or more. The HV hardness at a position of 1.0 mm from the surface at the stress concentrated region is preferably 210 or more, and preferably 320 or less in the light of machinability.

[0116] (B-3) Compound-Layer Depth at the Stress Concentrated Region:

[0117] By setting the compound-layer depth at the stress concentrated region to be thinner, it is possible to improve the bending straightening property without deteriorating the bending fatigue strength. However, it is hard to expect significant improvement of the bending straightening property if the compound layer whose depth is more than 5 μm still remains.

[0118] Accordingly, in the non-thermal refined nitrocarburized component according to the present invention, the compound-layer depth at the stress concentrated region is set to be 5 μm or less. The compound-layer depth at the stress concentrated region is preferably 3 μm or less, and it is most preferable to have no compound layer, that is, have a compound-layer depth of 0 μm.

[0119] (B-4) Metal Micro-Structure of Base Metal:

[0120] As described above, the metal micro-structure (base material micro-structure) of the base metal of the non-thermal refined nitrocarburized component according to the present invention, which has a steel material of a base metal having the chemical composition described in the above section (A), is a bainite micro-structure. The bainite micro-structure as used herein refers to a metal micro-structure of the base metal of which 80% or more is bainite micro-structure.

[0121] As described above, since a non-thermal refined nitrocarburized component has a lower endurance ratio of the base material compared with a thermal refined nitrocarburized component, even if it has an internal hardness equal to that of the thermal refined nitrocarburized component at a stress concentrated region, the fatigue strength of the base material will become lower than that of a thermal refined nitrocarburized component. However, when the base material micro-structure of the non-thermal refined nitrocarburized component is a bainite micro-structure, the endurance ratio of the base material becomes higher compared with a case in which the base material micro-structure is a ferrite-pearlite micro-structure. Hence, a bainite type non-thermal refined steel can attain a higher fatigue strength compared with a ferrite-pearlite type non-thermal refined steel which has the same internal hardness at a stress concentrated region.

[0122] A component which satisfies the above described conditions (B-1) to (B-4) can be obtained in such a manner that a steel material that satisfies the chemical composition specified by the present invention is hot-forged at a temperature of 1000° C. or more into a hot forged product having a shaft diameter of 8 to 80 mm; then after being allowed to cool and machined, the product is subjected to a nitrocarburizing treatment by being retained for two hours in an atmosphere where an RX gas and ammonia gas are mixed at a mixture ratio of 1:1 at a temperature of 600° C., and then cooled in an oil having a temperature of 90° C.; and subsequently the stress concentrated region thereof is ground through machining such as lapping.

[0123] The above mentioned “RX gas” is one type of a modified gas, and represents a brand name of this gas.

[0124] Specifically, representing a crankshaft as an example of the non-thermal refined nitrocarburized component, for example, this crankshaft can be obtained in such a manner that a starting material that satisfies conditions on the chemical composition specified by the present invention is hot-forged into a crankshaft, this crankshaft is machined, and thereafter this crankshaft is subjected to the nitrocarburizing treatment to retain the crankshaft for two hours in an atmosphere where an RX gas and an ammonia gas are mixed at a mixture ratio of 1:1 at a temperature of 600° C., and then cooled in an oil having a temperature of 90° C., and subsequently, the pin fillet section and the journal fillet section are ground through machining using a lapping machine or the like.

[0125] Hereinafter, although the present invention will be described in detail by way of Examples, the present invention will not be limited to those Examples.

EXAMPLE

[0126] Each of Steels A to N having respective chemical compositions shown in Table 1 was melt in a 70 t convertor, subjected to continuous casting, and further subjected to blooming into a cast piece having a cross sectional dimension of 180 mm×180 mm.

[0127] Subsequently, each cast piece was hot-forged under the conditions that a heating temperature was 1200° C., and a finishing temperature was 1000 to 1050° C. into a steel bar having a diameter of 90 mm. Each steel bar after the hot-forging was cooled in the atmosphere down to a room temperature through allowing cooling.

[0128] In Table 1, each of Steels A to H is a steel having chemical composition within the range specified by the present invention, and each of Steels I to N is a steel having chemical composition out of the range specified by the present invention.

TABLE-US-00001 TABLE 1 Chemical composition (mass %) Balance: Fe and impurities Steel C Si Mn S N Cu Mo Ni Ti P Al Cr Fn1 A 0.36 0.21 2.72 0.070 0.0135 — — — — 0.017 0.007 0.04 3.75 B 0.48 0.14 2.42 0.042 0.0170 — — — — 0.020 0.022 0.09 4.03 C 0.41 0.32 2.32 0.066 0.0180 — — — — 0.018 0.014 0.14 4.30 D 0.43 0.20 2.48 0.062 0.0175 — — — 0.012 0.018 0.012 0.06 3.83 E 0.40 0.15 2.44 0.075 0.0150 0.20 — — — 0.010 0.011 0.10 3.78 F 0.41 0.22 2.42 0.066 0.0160 — — 0.10 — 0.016 0.010 0.09 4.03 G 0.37 0.17 2.40 0.050 0.0165 0.19 — 0.09 — 0.011 0.014 0.11 3.80 H 0.36 0.15 2.35 0.055 0.0180 — 0.11 — — 0.022 0.010 0.04 4.09 I *0.19 0.11 2.50 0.065 0.0185 — — — — 0.010 0.011 0.19 3.22 J 0.37 0.20 *2.25 0.068 0.0170 — — — — 0.015 0.012 0.13 3.61 K 0.36 0.18 *3.10 0.060 0.0175 — — — — 0.014 0.020 0.10 4.74 L 0.36 0.22 2.45 0.060 0.0190 — — — — 0.012 0.015 *0.28 4.97 M 0.36 0.14 2.30 0.066 0.0185 — — — — 0.021 0.015 0.03 *2.92 N 0.49 0.30 2.77 0.062 0.0175 — — — — 0.018 0.018 0.18 *6.05 Fn1 = (0.316C + 0.122) × (0.7Si + 1) × (5.1Mn − 1.12) × (0.364Ni + 1) × (2.16Cr + 1) × (3Mo + 1) A mark (*) represents deviation from the chemical composition specified by the present invention.

[0129] Each steel bar having a diameter of 90 mm obtained in this manner was heated up to a temperature of 1200° C., and then hot-forged at a finishing temperature of 1000 to 1050° C. into a steel bar having a diameter of 50 mm. Each finished steel bar was cooled down to a room temperature through allowing cooling in the atmosphere.

[0130] In each of Steels A to N, a grooved Ono-type rotating bending fatigue test specimen having a shape shown in FIG. 2 was cut out in parallel to the forging axis from an D/4 part (“D” represents a diameter of a steel bar) of each steel bar as hot-forged having a diameter of 50 mm, and a four-point bending test specimen having a shape shown in FIG. 3 was also cut out in the same manner as this grooved Ono-type rotating bending fatigue test specimen.

[0131] In the test specimen in FIG. 2, the groove bottom of the R3 is equivalent to the stress concentrated region. Similarly, in the test specimen in FIG. 3, the notch bottom of the R3 is equivalent to the stress concentrated region.

[0132] Each grooved Ono-type rotating bending fatigue test specimen and each four-point bending test specimen, which were obtained in the above manner, were respectively subjected to the nitrocarburizing treatment to retain each test specimen for two hours in an atmosphere where the RX gas and the ammonia gas are mixed at a mixture ratio of 1:1 at a temperature of 600° C.; and thereafter, was cooled in the oil having a temperature of 90° C.

[0133] In Test No. 1 to Test No. 14, subsequent to the nitrocarburizing treatment, electrolytic grinding was further carried out at the groove bottom of each grooved Ono-type rotating bending fatigue test specimen, and at the notch bottom of each four-point bending test specimen, with a target grinding depth of 0.03 mm under the following conditions.

[0134] Electrolytic solution: perchloric acid (HClO.sub.4):acetic acid (CH.sub.3COOH)=1:9

[0135] Current value: 0.14 A

[0136] Grinding area: [0137] Ono-type rotating bending fatigue test specimen: 160 mm.sup.2 [0138] Four-point bending test specimen: 96 mm.sup.2

[0139] Grinding time period: [0140] Ono-type rotating bending fatigue test specimen: 970 seconds [0141] Four-point bending test specimen: 590 seconds

[0142] In Test No. 15 and Test No. 16, subsequent to the nitrocarburizing treatment, electrolytic grinding was further carried out at the groove bottom of each grooved Ono-type rotating bending fatigue test specimen, and the notch bottom of each four-point bending test specimen, with a target grinding depth of 0.015 mm under the following conditions.

[0143] Electrolytic solution: perchloric acid (HClO.sub.4):acetic acid (CH.sub.3COOH)=1:9

[0144] Current value: 0.14 A

[0145] Grinding area: [0146] Ono-type rotating bending fatigue test specimen: 160 mm.sup.2 [0147] Four-point bending test specimen: 96 mm.sup.2

[0148] Grinding time period: [0149] Ono-type rotating bending fatigue test specimen: 490 seconds [0150] Four-point bending test specimen: 300 seconds

[0151] Using the specimens as nitrocarburized (Test No. 17) and the specimens further subjected to the electrolytic grinding after the nitrocarburizing treatment (Test No. 1 to Test No. 16) obtained in the above manner, a study of the bending fatigue strength by the Ono-type rotating bending fatigue test, and a study of the bending straightening property by the four-point bending test were respectively carried out.

[0152] Further, using the Ono-type rotating bending fatigue test specimens and the four-point bending test specimens, which were as nitrocarburized (Test No. 17) or subjected to electrolytic grinding after the nitrocarburizing treatment (Test No. 1 to Test No. 16), the surface-layer hardness (i.e., hardness at a position of 0.05 mm from the surface of each specimen), the internal hardness (i.e., hardness at a position of 1.0 mm from the surface of each specimen), and the compound-layer depth at the groove bottom and the notch bottom, which were stress-concentrated regions, were studied. Further, the base material micro-structure was studied as well.

[0153] The details of each study will be described, hereinafter.

[0154] (1) Study of Bending Fatigue Strength:

[0155] The Ono-type rotating bending fatigue test was carried out at a room temperature, in the atmosphere, under completely reversed bending at a rotational rate of 3000 rpm so as to study the bending fatigue strength (referred to as “σw”, hereinafter).

[0156] The target σw was set to be 800 MPa or more.

[0157] (2) Study of Bending Straightening Property:

[0158] A strain gauge of 2 mm was adhesively bonded to the notch bottom of each four-point bending test specimen, and bending-straightening strain was applied to this specimen until the gauge was broken. A read value of the gauge at the moment when the gauge was broken was evaluated as the bending straightening property.

[0159] The target value of the bending straightening property was set to be 22000μ (equivalent to the bending-straightening strain of 2.2%) or more.

[0160] (3) Surface-Layer Hardness and Internal Hardness at Stress Concentrated Region

[0161] The Ono-type rotating bending fatigue test specimen was cut such that a cross section that passes through the central portion of the specimen and is parallel with the longitudinal direction of the specimen appears. Further, the four-point bending test specimen was cut such that a cross section that is parallel with the longitudinal direction of the specimen and is perpendicular to the direction of the groove appears. Then, to employ each cut surface as a target surface to be examined, after the vicinity of the groove of the R3 of the Ono-type rotating bending fatigue test specimen and the vicinity of the notch of the R3 of the four-point bending test specimen were embedded in resin, the aforementioned surface was polished to be mirror-finished; and subsequently the surface-layer hardness at the stress concentrated region (hereinafter, simply referred to as the “surface-layer hardness) and the internal hardness at the stress concentrated region (hereinafter, simply referred to as the “internal hardness”) were studied using a Vickers hardness meter. The target surface to be examined of the four-point bending test specimen is shown in FIG. 4. The target surface to be examined is similar for the case of the Ono-type rotating bending fatigue test specimen (not shown).

[0162] As for hardness, in conformity to the “Vickers hardness test—Test method” described in JIS Z 2244:2009, the HV hardness at any six points respectively at a position of 0.05 mm and a position of 1.0 mm from the groove bottom of the R3 and the notch bottom of the R3 were measured with a test force of 2.94N using a Vickers hardness meter, and the measured values were arithmetically averaged to evaluate the surface-layer hardness and the internal hardness. FIG. 5 schematically shows the measurement positions of hardness in the four-point bending test specimen. The measurement positions are similar for the target surface to be examined of the Ono-type rotating bending fatigue test specimen (not shown).

[0163] (4) Compound-Layer Depth at the Stress Concentrated Region:

[0164] The compound-layer depth at the stress concentrated region (hereinafter, simply referred to as “compound-layer depth”) was studied using each of the test specimens embedded in the resin that were used in the above (3).

[0165] Specifically, each test specimen embedded in the resin was polished once again, etched with nital, and then any five visual fields at the groove bottom of the R3 and any five visual fields at the notch bottom of the R3 were respectively observed with an optical microscope with magnification of 400×; and portions observed to be white were determined as the “compound layers”, and the depths of these layers were measured, and arithmetically averaged as the compound-layer depth. The measurement positions of the compound-layer depth in the four-point bending test specimen are schematically shown in FIG. 6. The measurement positions are similar for the target surface to be examined of the Ono-type rotating bending fatigue test specimen (not shown).

[0166] (5) Base Material Micro-Structure:

[0167] The base material micro-structure was studied using each of the test specimens embedded in resin that were used in the studies described in (3).

[0168] Specifically, the base material micro-structure was observed by an optical microscope at a magnification of 400 times by using a test specimen which was etched with nital as described above.

[0169] Table 2 shows, in summary, results of each study described above. In Table 2, in a base material micro-structure described as “bainite”, a bainite micro-structure accounts for 80% or more of the base material micro-structure; in one described as “ferrite-pearlite”, a ferrite-pearlite micro-structure accounts for 80% or more of it, and in one described as “martensite”, a martensite micro-structure accounts for 80% or more of it.

TABLE-US-00002 TABLE 2 Grooved Ono-type rotating bending fatigue test specimen Four-point bending test specimen Surface Surface Compound Layer Internal base Compound Layer Internal base Bending Layer hardness hardness material Layer hardness hardness material Straightening Test depth (HV (HV micro- σw Depth (HV (HV micro- property No. Steel (μm) hardness) hardness) structure (MPa) (μm) hardness) hardness) structure (μ) 1 A 2 433 244 bainite 840 2 431 243 bainite 29800 2 B 1 435 260 bainite 880 1 434 261 bainite 29500 3 C 3 415 235 bainite 810 3 416 234 bainite 27200 4 D 0 440 265 bainite 890 0 436 264 bainite 30200 5 E 2 445 270 bainite 880 2 444 271 bainite 26000 6 F 3 461 280 bainite 900 3 465 280 bainite 24500 7 G 0 451 290 bainite 880 0 452 291 bainite 27000 8 H 1 440 235 bainite 860 1 440 233 bainite 28000 9 *I 1 435 *195 bainite #780 1 433 *198 bainite 29500 10 *J 0 *405 240 bainite #79 0 *406 242 bainite 33500 11 *K 2 *510 285 bainite 920 3 *512 282 bainite #16500 12 *L 2 *505 275 bainite 900 2 *505 277 bainite #16000 13 *M 2 412 210 *ferrite- #770 1 413 210 *ferrite- 32400 pearlite pearlite 14 *N 1 *540 295 *martensite 920 1 *542 299 *martensite #13500 15 A *11 440 245 bainite 840 *12 441 244 bainite #14000 16 B *10 445 260 bainite 870 *9 444 260 bainite #13500 17 C *21 425 238 bainite 810 *20 428 235 bainite #15000 A mark (*) represents deviation from the requirement specified by the present invention. A mark (#) represents that the value does not satisfy the target value.

[0170] As shown in Table 2, in the cases of Test No. 1 to Test No. 8 that satisfy the conditions specified by the present invention in the chemical composition of the steel material of the base metal, the surface-layer hardness, the internal hardness, and the compound-layer depth as well as the base material micro-structure, it is apparent that the target values of the σw and the bending straightening property were both satisfied, and these cases are excellent in bending fatigue characteristics and bending straightening property.

[0171] To the contrary, in the cases of Test No. 9 to Test No. 14, the respective chemical compositions of Steel I to Steel N deviate from the conditions specified by the present invention, and thus these cases are poorer in bending fatigue characteristics or bending straightening property.

[0172] Specifically, in the case of Test No. 9, the C content of Steel I that is the steel material of the base metal is less than the range specified by the present invention. Consequently, the internal hardness of the Ono-type rotating bending fatigue test specimen is as low as 195 in terms of the HV hardness, and the σw does not satisfy the target value of 800 MPa or more; thus this case is poor in bending fatigue characteristics.

[0173] In the case of Test No. 10, the Mn content of Steel J that is the steel material of the base metal is less than the range specified by the present invention. Consequently, the surface-layer hardness of the Ono-type rotating bending fatigue test specimen is as low as 405 in terms of the HV hardness, and the σw does not satisfy the target value of 800 MPa or more; thus this case is poor in bending fatigue characteristics.

[0174] In the case of Test No. 11, the Mn content of Steel K that is the steel material of the base metal is more than the range specified by the present invention. Consequently, although the compound-layer depth is as small as 3 μm, the surface-layer hardness of the four-point bending test specimen is as high as 512 in terms of the HV hardness, and the bending straightening property does not satisfy the target value of 22000μ or more in terms of the read value of the gauge; thus this case is poor in bending straightening property.

[0175] In the case of Test No. 12, the Cr content of Steel L that is the steel material of the base metal is more than the range specified by the present invention. Consequently, although the compound-layer depth is as small as 2 μm, the surface-layer hardness of the four-point bending test specimen is as high as 505 in terms of the HV hardness, and the bending straightening property does not satisfy the target value of 22000μ or more in terms of the read value of the gauge; thus this case is poor in bending straightening property.

[0176] In the case of Test No. 13, Fn1 of Steel M, which is the steel material of the base metal, is less than the range specified by the present invention. Consequently, the base material micro-structure becomes a ferrite-pearlite micro-structure, and although the surface-layer hardness in the Ono-type rotating bending fatigue test specimen is as high as 412 in HV hardness, and the internal harness is 210 in HV hardness, the bending fatigue strength σw does not satisfy the target value of 800 MPa or more, thus exhibiting poor bending fatigue characteristics.

[0177] In the case of Test No. 14, Fn1 of Steel N, which is the steel material of the base metal, is more than the range specified by the present invention. Consequently, the base material micro-structure becomes a martensite micro-structure, and although the compound layer depth is as low as 1 μm, the surface-layer hardness of the four-point bending test specimen is as high as 542 in terms of HV hardness, and the bending straightening property does not satisfy the target value of 22000μ or more in terms of the read value of the gauge, thus exhibiting poor bending straightening property.

[0178] In the cases of Test No. 15 to Test No. 17, the compound-layer depth of the four-point bending test deviates from the condition specified by the present invention; thus these cases are poor in bending straightening property.

[0179] In the case of Test No. 15, although Steel A that is the steel material of the base metal has chemical composition within the range specified by the present invention, the compound-layer depth of the four-point bending test specimen is as high as 12 μm, and the bending straightening property does not satisfy the target value of 22000μ or more in terms of the read value of the gauge; thus this case is poor in bending straightening property.

[0180] In the case of Test No. 16, although Steel B that is the steel material of the base metal has chemical composition within the range specified by the present invention, the compound-layer depth of the four-point bending test specimen is as high as 9 μm, and the bending straightening property does not satisfy the target value of 22000μ or more in terms of the read value of the gauge; thus this case is poor in bending straightening property.

[0181] In the case of Test No. 17, although Steel C that is the steel material of the base metal has chemical composition within the range specified by the present invention, the compound-layer depth of the four-point bending test specimen is as high as 20 μm, and the bending straightening property does not satisfy the target value of 22000μ or more in terms of the read value of the gauge; thus this case is poor in bending straightening property.

INDUSTRIAL APPLICABILITY

[0182] The non-thermal refined nitrocarburized component of the present invention is excellent in bending straightening property after the nitrocarburizing treatment, and has a bending fatigue strength as high as 800 MPa or more in the bending fatigue test; therefore, this non-thermal refined nitrocarburized component is usable as a component, such as a crankshaft, in automobiles, industrial machines, or construction machinery, and this component is capable of attaining reduction in weight and size.