MEMORY ELEMENTS HAVING CONDUCTIVE CAP LAYERS AND METHODS THEREFOR
20170279045 · 2017-09-28
Inventors
- John Ross Jameson, III (Menlo Park, CA, US)
- Jeffrey Allan Shields (Sunnyvale, CA, US)
- Kuei-Chang Tsai (Cupertino, CA, US)
Cpc classification
G11C13/0011
PHYSICS
H10N70/021
ELECTRICITY
H10N70/245
ELECTRICITY
H10N70/011
ELECTRICITY
H10N70/801
ELECTRICITY
International classification
Abstract
A memory element can include a first electrode; at least one switching layer formed over the first electrode; a second electrode layer; and at least one conductive cap layer formed over the second electrode layer having substantially no grain boundaries extending through to the second electrode layer; wherein the at least one switching layer is programmable between different impedance states by application of electric fields via that first and second electrode. Methods of forming such memory elements are also disclosed.
Claims
1. A memory element comprising: a first electrode; at least one switching layer formed over the first electrode; a second electrode layer; and at least one conductive cap layer formed over the second electrode layer having substantially no grain boundaries extending through to the second electrode layer; wherein the at least one switching layer is programmable between different impedance states by application of electric fields via that first and second electrode.
2. The memory element of claim 1, wherein the at least one conductive cap layer comprises at least one amorphous layer.
3. The memory element of claim 2, wherein the at least one amorphous layer includes a layer of an amorphous silicide.
4. The memory element of claim 2, wherein the at least one amorphous layer includes a layer of a mictamict alloy.
5. The memory element of claim 2, wherein the at least one amorphous layer has the composition M.sub.xSe.sub.yQ.sub.z where M is an early transition metal, Se is a semiconductor or semimetal, and Q is nitrogen or oxygen.
6. The memory element of claim 5, wherein the M is selected from the group of: scandium (Sc), titanium (Ti), vanadium (V), chromium (Cr), yttrium (Y), zirconium (Zr), niobium (Nb), molybdenum (Mo), hafnium (Hf), tantalum (Ta), tungsten (W) and lanthanum (La).
7. The memory element of claim 5, wherein the Se is selected from the group of: silicon (Si), germanium (Ge) and boron (B).
8. The memory element of claim 2, further including: the at least one amorphous layer is in contact with the second electrode layer, and p1 a further layer having grain boundaries is formed over the at least one amorphous layer.
9. The memory element of claim 2, further including: a lower layer having grain boundaries is in contact with the second electrode layer, and the at least one amorphous layer is formed over the lower layer.
10. The memory element of claim 9, further including an upper layer having ground boundaries formed over the at least one amorphous layer.
11. The memory element of claim 1, wherein the at least one conductive cap includes a first layer having grain boundaries in contact with a second layer having grain boundaries, and the majority of the first layer grain boundaries are not vertically aligned with the second layer grain boundaries.
12. The memory element of claim 1, wherein the second electrode is an anode that includes at least one element that can ion conduct in the at least one switching layer.
13. A method, comprising: forming a first electrode; forming at least one switching layer over the first electrode that is programmable between different impedance states by application of electric fields; forming a second electrode layer; and forming at least one conductive cap layer over the second electrode layer having substantially no grain boundaries extending through to the second electrode layer; wherein the at least one switching layer is programmable between different impedance states by application of electric fields via that first and second electrode.
14. The method of claim 13, wherein forming the at least one conductive cap layer includes forming at least one amorphous layer over the second electrode layer.
15. The method of claim 13, wherein forming at least one amorphous layer includes forming a layer of a mictamict alloy.
16. The method of claim 15, wherein the mictamict alloy has the composition M.sub.xSi.sub.yQ.sub.z where M is an early transition metal, Si is silicon, and Q is nitrogen or oxygen.
17. The method of claim 15, wherein forming the layer of the mictamict alloy includes reactive sputtering the M and Si component with a gas that includes the Q component.
18. The method of claim 13, wherein: forming the at least one conductive cap layer includes forming a layer having grain boundaries, and forming an amorphous layer.
19. The method of claim 18, wherein the location of the amorphous layer is selected from: over the layer having grain boundaries and under the layer having grain boundaries.
20. The method of claim 13, wherein: forming the at least one conductive cap layer includes forming a first layer having grain boundaries over and in contact with the second electrode layer, and forming a second layer having grain boundaries over and in contact with the first layer with a processing step separate from that which forms the first layer; wherein the majority of the first layer grain boundaries are not vertically aligned with the second layer grain boundaries.
Description
BRIEF DESCRIPTION OF DRAWINGS
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DETAILED DESCRIPTION OF THE EMBODIMENTS
[0020] Embodiments can include memory elements, devices including such elements, and methods for making elements in which one or more conductive cap layers can be formed over an electrode of a memory element. The cap layers can include few, if any, grain boundaries that extend through to the underlying electrode. In some embodiments, cap layers can include at least one layer that is conductive and amorphous. Other embodiments can include combinations of layers, including one that is amorphous and one that includes grain boundaries.
[0021] In some embodiments, an amorphous layer of a conductive cap can have the composition M.sub.xSe.sub.yQ.sub.z where M is an early transition metal, Se is a semiconductor or semimetal, and Q is nitrogen or oxygen.
[0022] In other embodiments, a conductive cap layer can be, or can include, a layer of an amorphous silicide.
[0023] In further embodiments, a conductive cap layer can include a first layer having grain boundaries in contact with a second layer having grain boundaries, with the majority of the first layer grain boundaries not being vertically aligned with the second layer grain boundaries.
[0024] Other embodiments can include methods of forming such memory elements, and devices including such memory elements.
[0025] In the various figures, like items are referred to the same reference character but with the leading digit(s) corresponding to the figure number.
[0026]
[0027] A switching layer 104 can provide a change in impedance in response to the application of electric fields. In some embodiments, application of an electric field in one direction can result in a first type resistance change (e.g., a higher resistance), while an electric field in the opposite direction can result in a second type resistance change (e.g., a lower resistance). In some embodiments, a switching layer can change resistance through an oxidation-reduction reaction. Such a reaction may, or may not include ion conduction.
[0028] While a switching layer 104 can include any suitable material, embodiments, a switching layer can include a metal oxide layer and/or a chalcogenide.
[0029] It is understood that a switching layer 104 can be a compound layer, being formed of more than one layer.
[0030] In some embodiments, a second electrode layer 106 can be an anode of a CBRAM type element. Embodiments, a second electrode layer 106 can include one or more elements that are capable of ion conducting in the switching layer 104.
[0031] A cap layer 108 can include, or can be, an amorphous layer that essentially includes no grain boundaries. In some embodiments, amorphous cap layer 108 can be an amorphous silicide. In one embodiment, an amorphous cap layer 108 can be a tantalum silicide Ta.sub.xSi.sub.y. Tantalum silicide can advantageously use materials commonly present in existing fabrication processes.
[0032] In addition or alternatively, a cap layer 108 can include, or be, a conductive mictamict alloy. In some embodiments, a mictamict alloy can have the composition M.sub.xSe.sub.yQ.sub.z, where M is an early transition metal, Se is semiconductor or semimetal, and Q is nitrogen (N) or oxygen (O). Early transition metals are of groups IIIB, IVB, VB and VIB of the Periodic Table. In more particular embodiments, M can be any of: scandium (Sc), titanium (Ti), zirconium (Zr), vanadium (V), chromium (Cr), yttrium (Y), lanthanum (La), niobium (Nb), molybdenum (Mo), hafnium (Hf), tantalum (Ta) or tungsten (W). According to some embodiments, Se can be any of: silicon (Si), germanium (Ge) or boron (B). Very particular examples of mictamict alloy nitrides that may be included in a cap layer according to embodiments are: Ta.sub.xSi.sub.yN.sub.z, which in a particular example can be Ta.sub.36Si.sub.14N.sub.50, or a compound having a similar stoichiometry; Mo.sub.xSi.sub.yN.sub.z, where particular examples can include x/y/z being about 35/17/48, 36/17/47, or a compound having a similar stoichiometry; W.sub.xSi.sub.yN.sub.z, where particular examples can include x/y/z being about 24/36/40, 24/38/38, 36/14/50, 41/17/42 or a compound having a similar stoichiometry; W.sub.xB.sub.yN.sub.z, where particular examples can include x/y/z being about 42/17/41, 64/20/16 or a compound having a similar stoichiometry; or Ti.sub.xSi.sub.yN.sub.z which in a particular example can be Ti.sub.34Si.sub.23N.sub.43, or a compound having a similar stoichiometry. These or additional examples are understood from, “Amorphous Ternary Diffusion Barriers for Silicon Metallizations” by Jason S. Reid, a Thesis submitted to the California Institute of Technology, dated 1995 (herein after Reid), the contents of which are incorporated herein. It is understood however, that these particular compositions are provided by way of example only, and should not necessarily be construed as limiting.
[0033] Very particular examples of mictamict alloy oxides that may be used in a cap layer according to embodiments may include: Ti.sub.xSi.sub.yO.sub.z, where particular examples of x/y/z can be about 3/1/8, 25/8/67, or a compound having a similar stoichiometry; or Ru.sub.xSi.sub.yO.sub.z. These or additional examples are understood from, “Thermal Stability of amorphous Ti3Si1O8 thin films” by P. H. Giauque et al., Microelectronic Engineering 55 (2001) 183-188 (hereinafter Giauque et al.), the contents of which are incorporated herein. It is understood however, that these particular compositions are provided by way of example only, and should not necessarily be construed as limiting.
[0034] According to some embodiments, an amorphous cap layer 108 can remain amorphous through anneals greater than 400° C., and thus can be suitable for existing fabrication processes, including CMOS fabrication processes.
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[0037] Grain boundary containing layers 208-0 and 208-2 can be formed of any suitable conductive material, preferably those available in, or compatible with, an existing fabrication process.
[0038] In some embodiments, interrupting layer 208-1 can be a material having a different grain structure than that of layers 208-0 and 208-2. In some embodiments, interrupting layer 208-1 can be a metal formed of a single element, while layers 208-0 and 208-2 can be compound materials. In one very particular embodiment, layers 208-0 and 208-2 can be TaN and interrupting layer 208-1 can be Ta.
[0039] In other embodiments, interrupting layer 208-1 can be an amorphous layer. In such embodiments, interrupting layer 208-1 can be formed of any suitable amorphous material as described herein, or an equivalent.
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[0042] Layer 308-2 can include grain boundaries. However, layer 308-1 can limit or prevent such grain boundaries from extending to second electrode layer 306.
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[0045] Layer 408-1, formed over layer 408-0, can be an interrupting layer as described for the embodiment of
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[0048] Layer 508-1 can be formed over and in contact with layer 508-0. Layer 508-1 can also include grain boundaries, however, the majority of such grain boundaries are not vertically aligned with those of the underlying layer 508-0. Accordingly, while undesirable elements may propagate through grain boundaries of layer 508-1, due to the vertical misalignment of grain boundaries, most of the elements will not propagate through layer 508-0 on to second electrode layer 506.
[0049]
[0050] Referring to
[0051] Following the formation of first electrode 102, a switching layer 104 can be formed over the first electrode 104. In particular embodiments, switching layer 104 can be in contact with first electrode 104. A switching layer 104 can be subject to the variations noted for
[0052] Following the formation of switching layer 104, a second electrode layer 106 can be formed over the switching layer 104. In particular embodiments, second electrode layer 106 can be in contact with switching layer 104. A second electrode layer 106 be subject to the variations noted for
[0053] Referring to
[0054] A cap layer 108 can be subject to the variations noted for
[0055] In more particular embodiments, a cap layer 108 can be an amorphous compound M.sub.xSe.sub.yQ.sub.z, described with reference to
[0056] In some very particular embodiments, an amorphous cap layer 108 can be formed by reactive sputtering at a frequency of about 10-20 MHz, with a power of about 50-2000 W, and at a pressure of about 0.1 mTorr to 10 mTorr. Metal silicide or metal boride targets can be used, including but not limited to targets of: Mo.sub.3Si.sub.3, Ta.sub.5Si.sub.3, Ti.sub.5Si.sub.3, W.sub.5Si.sub.3, WSi.sub.2 or W.sub.2B. Argon (Ar) gas can flow into the chamber at about 10-80 sccm with nitrogen gas (N.sub.2).
[0057] In other very particular embodiments, an amorphous cap layer 108 can be formed by reactive sputtering with a target of Ti.sub.3Si and a gas flow of Ar and O.sub.2. Other very particular examples and variations are understood from Reid and Giauque et al., incorporated by reference above.
[0058]
[0059] Referring to
[0060] Referring to
[0061] In particular embodiments, an interrupting layer 208-1 can be a pure metal layer. In particular embodiments, interrupting layer 208-1 can be metal formed by deposition, including but not limited to: atomic layer deposition, sputtering (including reactive sputtering), or chemical vapor deposition (CVD) (including plasma enhanced CVD). In one very particular embodiment, interrupting layer 208-1 can be a layer of Ta.
[0062] As noted for
[0063] It is noted that following the formation of interrupting layer 208-1, a memory cell 200 can have the form of that shown in
[0064] Referring to
[0065] In some embodiments, layers 208-0 and 208-2 can be a same material formed with same conditions, but a separate fabrication step. However, in other embodiments, layers 208-0 and 208-2 can be a same material formed with different process conditions or different materials entirely.
[0066]
[0067] Referring to
[0068] Referring to
[0069]
[0070] Referring to
[0071] Referring to
[0072]
[0073] In this way, an IC device 1020 fabricated with a CMOS process can advantageously include elements (such as CBRAM or other RRAM) elements that have increased protection from undesired elements.
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[0075] Access circuits 1134 can enable access to memory cells according to address values. In some embodiments, access circuits 1134 can include decoder circuits, including row and/or column decoders. In some embodiments, access circuits 1134 can also provide limited access to some memory cells (e.g., boot blocks or the like).
[0076] Program/erase circuits 1136 can set an impedance of elements (e.g., 1100) of memory cells by application of an electric field through access circuits 1134. In some embodiments, memory cells within array(s) 1132 can be erased to a high resistance than selectively programmed to one or more lower resistances according to a data value to be stored. However, in other embodiments, memory cells can be erased to a low resistance and selectively programmed to a high resistance. In the embodiment shown, program and erase operations can be controlled according to control inputs Ctrl.
[0077] A controller 1138 can control program and erase operations. In particular, controller 1138 can provide control inputs Ctrl to program/erase circuits 1136.
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[0079] A first terminal of element 1200 can be connected to an access line 1242 (e.g., a bit line) via access device 1246. A second terminal of element 1200 can be connected to a node 1250. In some embodiments, a second terminal of element 1200 can be an anode, and node 1250 can be a plate common to many anodes of other elements.
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[0081] It should be appreciated that reference throughout this description to “one embodiment” or “an embodiment” means that a particular feature, structure or characteristic described in connection with the embodiment is included in at least one embodiment of an invention. Therefore, it is emphasized and should be appreciated that two or more references to “an embodiment” or “one embodiment” or “an alternative embodiment” in various portions of this specification are not necessarily all referring to the same embodiment. Furthermore, the particular features, structures or characteristics may be combined as suitable in one or more embodiments of the invention.
[0082] It is also understood that other embodiments of this invention may be practiced in the absence of an element/step not specifically disclosed herein.
[0083] Similarly, it should be appreciated that in the foregoing description of exemplary embodiments of the invention, various features of the invention are sometimes grouped together in a single embodiment, figure, or description thereof for the purpose of streamlining the disclosure aiding in the understanding of one or more of the various inventive aspects. This method of disclosure, however, is not to be interpreted as reflecting an intention that the claims require more features than are expressly recited in each claim. Rather, inventive aspects lie in less than all features of a single foregoing disclosed embodiment. Thus, the claims following the detailed description are hereby expressly incorporated into this detailed description, with each claim standing on its own as a separate embodiment of this invention.